Unit 1 Glossary Flashcards

1
Q

Definition of absorption spectrum

A

A spectrum consisting of dark absorption lines superimposed on a bright continuous spectrum it shows the absorption of radiation by a material over a range of wavelengths

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2
Q

Definition of Aufbau principal

A

This states that the orbitals are filled in order of increasing energy

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3
Q

Define bidentate

A

A ligand that contains two atoms with lone pairs of electrons capable of bonding to a metal atom or ion

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4
Q

Define a complex

A

The complex consists of a central metal atom or ion surrounded by Ligands

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5
Q

Define a coordinate bond

A

A covalent bond in which one of the atom supplies both of the electrons to the shared pair

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6
Q

Define a coordinate compound

A

Compounds in which a central metal atom or ion is attached to a group of surrounding molecules or ions by dative covalent bonds

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7
Q

Define coordination number

A

The coordination number is the number of nearest neighbours by which an atom or ion is surrounded in a structure

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8
Q

Define a dative covalent bond

A

Is a type of covalent bond both the shared electrons originally came from the same atom

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9
Q

Define degenerate

A

I said of atomic orbitals that are equal to each other in energy

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10
Q

Define the electromagnetic spectrum

A

Is the range of frequencies or wavelength of electromagnetic radiation

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11
Q

Define electronegativity

A

Electronegativity is a measure of the attraction of an atom involved in a bond has for the electrons of the bond

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12
Q

Define emission spectroscopy

A

The study of emission spectra produced by excited substances

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13
Q

Define excitation energy

A

The minimum energy required to change the system from its ground state to a particular excited state

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14
Q

Define frequency

A

This is the number of wavelengths that pass a fixed point in one unit of time

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15
Q

Define ground state

A

This is the lowest possible electronic configuration the electrons in the atom can adopt

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16
Q

What is Hinesburg’s uncertainty principle

A

This states that it is impossible to state precisely the position of the momentum of an electron at the same instant

17
Q

Define haxadentate

A

A legend that buttons to a metal iron using electron pairs on six donor atoms

18
Q

What is Hund’s rule

A

When degenerate orbitals are available electrons fill each single keeping their spins parallel before pairing starts

19
Q

Define ionisation

A

The addition of removal of an electron to create an ion

20
Q

Define ionisation energy

A

The energy involved in removing one mole of electrons from one mole of atoms in the gaseous state

21
Q

Define a ligand 

A

Molecules or ions that bond to the central metal atom or ion in a complex

22
Q

What is a lone pair

A

Alone or non-bonding pair of electrons as a pair of outer core valence shell electrons which are not used to form a covalent bond within the molecule

23
Q

Define mono dentate

A

I like and that bonds to a metal atom or ion using the electron pair of a single donor atom

24
Q

Define oxidation

A

This is the loss of electrons from a substance it can also be described as an increase in oxidation number

25
Q

Define oxidation number

A

The formal change assigned to each atom in a compound according to a certain rule

26
Q

Define the Pauli exclusion principle

A

This states that an orbital holds a maximum of two electrons

27
Q

Define Quanta

A

The smallest possible discreet unit of any physical property such as energy or matter

28
Q

Define reduction

A

The gain of electrons by a substance it can also be described as a decrease in oxidation number

29
Q

What is the spectrochemical series

A

A list of lagoons in order of size of the crystal fields fitting cost in the D orbitals

30
Q

Define wavelength

A

The distance between adjacent crests or tufts of a wave

31
Q

Define wave number

A

Wave number is the reciprocal of wavelength and has the unit of cm-1