Unit 2: Ethanlpy Changes Flashcards
Describe the importance of oxidation
- exothermic reaction
- oxidation of fuels by combustion is our most exploited exothermic reaction
- we rely on combustion if petrol and diesel in cars and public transport.
- concern about how much fuel is burned and how much CO2 is produced.
What do endothermic processes require?
An input of heat energy
Eg. Thermal decomposition of calcium carbonate
Definition of standard conditions
A pressure of 100kPa
A temperature of 298K
A concentration of 1mol/dm^3
Definition of enthalpy change of reaction
The enthalpy change that accompanies a reaction in the molar quantities expressed in a chemical equation under standard conditions, all reactants and products being in their standard styles.
Definition of enthalpy change of formation
The enthalpy change that takes place when one mole of a compound is formed from its constituent elements in their standard states under standard conditions.
Definition of enthalpy change of combustion
The enthalpy change that takes place when:
- one mole of a substance reacts
- completely with oxygen
- under standard conditions, all reactants and products being in their standard states.
Equation for energy change
Q=mc
Definition of average bond enthalpy
The average enthalpy change that takes place when breaking by homolytic fission, 1 mol of a given type of bond in the molecules of a gaseous species.
What is an exothermic reaction?
- Bond making, it releases energy.
- The bonds that are formed are stronger than the bonds that are broken
What is an endothermic reaction?
- Bond breaking, it requires energy
- the bonds formed are weaker than the bonds that are broken.