Unit 1 Flashcards
Structural Isomer
or constitutional isomerism (perIUPAC), is a form of isomerism in which molecules with the same molecular formula have bonded together in different orders, as opposed to stereoisomerism
Geometric Isomer
Form of stereo isomerism
Enantiomer
Chiral molecules that are mirror images of one another. Furthermore, the molecules are non-superimposable on one another. This means that the molecules cannot be placed on top of one another and give the same molecule.
Hydroxyl-polar
is a chemical functional group containing an oxygen atom connected by a covalent bond to a hydrogen atom.Acceptor or donor.
Carbonyl-polar
Composed of a carbon atom double-bonded to an oxygen atom: C=O
Aldehyde
C=O at the end of a R group.
Ketone
C=O in the middle of a R group
Carboxyl-charged
the acid radical —COOH. Ionizes to release H+. at pH 7 called “carboxylic acid.”
Amino-charged
Basic. Accepts H+ to form +NH3
Phosphate-charged
Ionizes to release H—acidic. Ionizes at pH 7. Hydrophilic, phosphate transfer through hydrolysis.
Methyl-non-polar
R-CH3. “Methylation”- regulates molecular function.
Sulfhydryl-Polar
Found in proteins. *disulfide bridge-one way to sustain protein bridge.
Dehydration Synthesis
Monomers combine with each other via covalent bonds to form larger molecules known as polymers. In doing so, monomers release water molecules as byproducts.
Hydrolysis
A reaction involving the breaking of a bond in a molecule using water. The reaction mainly occurs between an ion and water molecules and often changes the pH of a solution.
Monosaccharide
The most basic units of carbohydrates. They are the simplest form of sugar and are usually colorless, water-soluble, crystalline solids
Disaccharide
The carbohydrate which is formed when two monosaccharides (simple sugars) undergo a condensation reaction which involves the elimination of a small molecule, such as water, from the functional groups only.
Polysaccharide
Are polymeric carbohydrate molecules composed of long chains of monosaccharide units bound together by glycosidic linkages and on hydrolysis give the constituent monosaccharides oroligosaccharides
Amylose/Amylopectin
A helical polymer made of α-D-glucose units, bound to each other through α glycosidic bonds. This polysaccharide is one of the two components of starch, making up approximately 20-30% of the structure. Amylopectin is a soluble polysaccharide and highly branched polymer of glucose found in plants.
Glycosidic Bond
A covalent bond that joins a carbohydrate (sugar) molecule to another group, which may or may not be another carbohydrate. Formation of ethyl glucoside: Glucose and ethanol combine to form ethyl glucoside and water.
Cellulose
An organic compound polysaccharide consisting of a linear chain of several hundred to many thousands of β linked D-glucose units. important structural component of the primary cell wall of green plants,.
Chitin
A long-chain polymer of a N-acetylglucosamine, a derivative of glucose. There is a different functional group on 2nd carbon.
Glycosaminoglycans
Mucopolysaccharides are long unbranched polysaccharides consisting of a repeating disaccharide unit. The repeating unit (except for keratan) consists of an amino sugar (N-acetylglucosamine or N-acetylgalactosamine) along with a uronic sugar (glucuronic acid or iduronic acid) or galactose
Glucose
A sugar with the molecular formula C6H12O6. Glucose is made during photosynthesis from water and carbon dioxide, using energy from sunlight. The reverse of the photosynthesis reaction, which releases this energy, is a very important source of power for cellular respiration. Glucose is stored as a polymer, in plants as starch and in animals as glycogen.
Hexose
Monosaccharide with six carbon atoms, having the chemical formula C6H12O6