UNIT#03 GASES Flashcards
At constant temperature when the pressure of a gas is increased three times then its volume becomes:
V/3
(P ∝ 1/V)
Under what conditions the density of an ideal gas will be maximum at:
➡Low temperature
➡High Pressure
(d= PV/RT)
If 1/V is plotted on x-axis and pressure on Y-axis at constant temperature, what should appear:
Straight line passing thorugh origin
The general gas equation to know the volumes of the gas at various temperatures is:
Vt = V° (1+t/273)
A mono-atomic substance can store energy only in the form of:
Translational Motion
A graph between pressure and product of pressure and volume at constant temperature and number of moles is:
Straight line parallel to x-axis
If both temperature and volme of a gas are doubled, the pressure
Remain unchanged
WHich one is the form of general gas equation:
➡PV=nRT
➡PV=RT
➡P1V1/T1 = P2V2/T2
Volume of a gas at S.T.P is 10dm3 at what temperature its volume will become 30dm3, keeping pressure constant
819K
(V1T1 = V2T2)
Which of the follwoing pairs of gases possess equal volume at S.T.P
0.5 mole of NO and 16g of O2
(Equal volume of all ideal gas at same temperature and pressure contain equal number of molecules and moles)
Which is incorrect about ideal gas
➡No force of attraction between molecules❌
➡No example in nature❌
➡Can be liquified easily✅
➡Obey gas laws at all conditions of temperature and pressure❌
A gas initially at 27 °C is heated up to 327 °C, its average kinetic energy will be:
Double
The coorect value for geenral gas constant is:
8.314 x 10^7 erg mol-1 K-1
In gases and liquids, temperature is the measure of _____ kinetic energies of molecules.
Average translational
The molar volume of nitrogen gas is maximum at:
130 °C and 1 atm
8g of methane and 2g of hydrogen are mixed and kept at 760 mm pressure at 273K, the total volume occupied by the mixture will be:
33.6 dm3
What is NOT true about gases:
➡They are highly compressible❌
➡They have only vibrational motion✅
➡Sudden expansion of gases cause cooling❌
➡They exert pressure on the walls of the vessel❌
For a definite mass of ideal gas at constant temperature, the plot of which pair of species will give a curved graph.
P vs V
A pressure of 0.101325 bar when expressed in atmosphere represents:
0.1 atm
(1 atm = 1.10325 bar)
Dimensons of the pressure are the same as that of:
Force per unit volume
Gases deviate from ideal behaviour at high pressure. Which of the following is correct for non-ideality?
At high pressure, the volume of the gas becomes insignificant
Under high pressure which of the following gas show more ideality in character:
N2
Ideality of gas will be more:
➡Less Intermolcular Force
➡Smaller Size
➡Non-Polar
➡Smaller mass
When 200cm3 of a gas at constant pressure is heated, its volume:
Increases
(V ∝ T)
The product of PV of a gas has unit of:
Work
(Joule)
Under what condition if temperature and pressure will a real gas behave most like an ideal gas?
➡High Temperature
➡Low Pressure
Absolute temperature of a gas is direclty proportional to average ___.
Translational Kinetic Energy
An ideal gas cant be liquefied because:
Forces between its molecuels are negligible
The compressibility factor ‘Z’ for an ideal gas is:
Equal to one
In dm3 atm K-1 mol-1, 2.0 g of hydrogen gas is heated from 27 °C to 327 °C. Which of the following is incorrect
The number of moles of the gas increases
(closed container)
A pressure of a gas is due to:
Molecular impacts against the walls of vessel
The compressiiblity actor, Z i.e the extent to which a real gas deviated from ideal behaviour is given by:
Z= PV/RT
Which of the following gases has the lowest r.m.s velocity at 25 °C
Cl2
Value of a ideal gas constant R does not depend upon:
Units of Temperature
“a” is called co-efficient of attraction in Van der Waal’s equation for real gases the unit of “a” is:
Nm+4/mol2
What will be the new volume if temperature and pressure both are reduced to half
Remains same
Very small values of Van der Waal’s constant in his equation for a particular gas shows that:
Least attractive forces are present among the molecules of the gas
Excluded volume is ____ times the actual volume of gas molecules
Four
(b=4Vm)
The constant ‘a’ in Van Der Waal’s equation is maximum for:
(a=attraction per unit volume)
Ammonia
(Ammonia has hydrogen bonding, Strong intermolecular force)
The average kinetic energy of the gas molecules is:
Directly proprotional to its absolute temperature
All the collisions between the particles o gases are elastic in nature. What is meant by “elastic collision”
No change in the kinetic energy
Which one of the following expression represent the Avogadro law?
V=RnT/P
(When T and P are constant)
The root mean square velocity of gases is inversely proportional to square root of their:
Molar mass
c (r.m.s) = √3RT/M
The number of molecules in 22.4 dm3 of H2 gas at 0 °C and 1 atm are:
6.02 x 10^23
There are four gases H2, N2, He, and CO2 at 0°C. Which gas shown greater non-ideal.
CO2
(Mass ∝ Intermolecular Force ∝ Non-Ideal Behaviour)
Identify the value of R at STP:
0.0821 atm dm3 K-1 mole-1
In the Van Der Waals equation, “b” represents that:
Excluded volume per mole
Gas is enclosed in a container of 20cm3 with the moving piston. According to kinetic theory o gases, what is the effect on freely moving molecules of the gas if temperature is increased from 20°C to 100°C?
Volume will be increased
(At constant pressure, by increasing temperature volume of a gas molecules)
Which of the following is the correct equation to calculate relative molecular mass of a gas:
M = mRT/PV
Which of the statmeent is applicable for both ideal and real gases molecules?
➡Have no forces of attraction❌
➡Collisions between the molecules is elastic❌
➡Molecules are in random motion✅
➡The actual volume of gas is negligible as compared to the volume of the gas❌
At absolute zero the molecules of hydrogen gas will have:
All the motion are ceased
According to the general gas euation, density of an ideal gas depends upon:
➡Pressure
➡Temperature
➡Molar mass of the gas
➡All of the above✅
The actual volume of gas molecules is considered neglegibile at following pressures.
2 atm
The unit is ___ commonly used by meterologist
Millibar
Plasma is difficult to maintain at:
Low Temperature
Effusion is the movement of a gas through extremely small opening of molecular size into region of ____ pressure.
Low
PV/nRT for an ideal gas is called
Compressibility Factor
The sum of moel fraction of the gases in a mixture of gases is:
Always 1
According to Avogadro’s law, .889 g of 1dm3 H2 and 1.4384g of 1 dm3 O2 have number of molecules
Same
Calculate the mass of 1dm3 of NH3 gas at 3°C and 1mm Hg pressure, considering that NH3 is ideally behaving
0.99 g
212-degree Farhenheit is expressed Kelvin as:
373
For non-ideal gas:
PV/NRT is not equal to Z
R does not depend upon:
Pressure
Which law is applicable while respiration:
Dalton’s Law
Which has the highest rate of diffusion:
NH3SO2
Effusions are:
Inversely to the square root of mass
KMT is discovered by:
Bernoulli
Which of these gases cannot liquify:
➡H2
➡He
The general gas equation is also known as:
Ideal
When temperature increases, the isotherm moves:
Away from both axis
Volume in an ideal gas is directly related to;
➡n
➡T
➡P
According to kinetic molecular theory absolute temperature is directly proportional to ___ of molecules.
Average translational kinetic Energy
Calculate the density of methane in g/L at -450°C and 300 torr pressure.
0.338
The general gas equation is also known as;
Ideal gas equation
The general gas equation is used for;
Ideal gas
General Gas Equation
PV=nRT
Liquids have no definite shape it is because
The molecules of liquid are in constant motion by sliding over each other
A class of materials with highly variable mechanical and optical properties that solidify from the molten state without crystallization are called
Amorphous solids
Gases deviate from Ideal behaviour at high pressure. Which of the following is correct for non idealty
At high pressure, the intermolecular attractions become significant
Under high pressure which of the following gas show more ideality in character
N2
CO2
NH3
SO2
N2
Absolute zero is
-459.67°F
The correct value of general gas constant is
8.314×10⁷ erg/mol.K
An ideal gas can’t be liquefied because
Forces between its molecules are negligible
A fire extinguisher delivers 2.2 kg of CO2. volume of CO2 at STP is
1120 dm3
When 200 ml of a gas at constant pressure is hated its volume
Increases
The product of PV of a gas is a unit of
Work
Gases exert pressure on the walls of the container because the gas molecules
Collide with walls of container
Which one of the following is absolute zero
Zero kelvin
The number of molecules in 0.0112m3 of Methane at 0°C and pressure of 760 mm Hg is
3.01×10^23
Which of the following will have same number of molecules at STP
280 cm3 of CO2 and 280 cm3 of N2O
The graph between pressure and inverse of volume at constant pressure and number of moles
Straight line passing through the origin
In a closed vessel of 1000 cm3, H2 gas is heated from 27°C to 127°C. Which statement is not correct
The number of moles of gas increases