Brainscape's Knowledge GenomeTM

Browse over 1 million classes created by top students, professors, publishers, and experts.


See full index

B19OC > Umpolung Chemistry > Flashcards

Umpolung Chemistry Flashcards

1
Q

Umpolung meaning

A

Inverse polarity

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Acyl anion equivalent

A

CN-

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

How to remove CN-

A

H+/H2O gives alcohol
H+/Alcohol gives corresponding ester

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Nitro alkene

A

Soft nucleophile, acyl anion equivalent used for conjugated additions, unmasked to C=O using Nef Reaction = TiCL3 with water

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Thioacetal

A

acyl anion eqivalent used for direct nucleophilic attack, added using LA catalysis and SHCH2CH2CH2SH and nBuLi converts to corresponding lithium reagent to be used

How well did you know this?
1
Not at all
2
3
4
5
Perfectly

B19OC (15 decks)

Brainscape helps you reach your goals faster, through stronger study habits.
© 2024 Bold Learning Solutions. Terms and Conditions