u2: titration Flashcards
titrant
solution in burette
sample
solution analyzed in flask
equivalence point/stoichiometric point
- amnt. of titrant recorded when chemically equivalent amounts have reacted
- when n H3O = n OH
endpoint
point where a sharp change in a measurable/characteristic property occurs (colour, pH)
titration curves: strong acid nd strong base
equivalence point at pH=7
what does midpoint/equivalence point look like on graphs?
sharp increase in pH
conjugate acid of a strong base is…
weak
conjugate base of a strong acid is…
weak
titration curves: strong base nd weak acid
equivalence point at pH above 7
titration curves: weak base nd strong acid
equivalence point at pH below 7
what are titrations not done with?
weak acids and weak bases
titration curves: polyprotic acids
- each proton has a diff. equivalence point, so multiple vertical lines exist
how do we solve the long III question?
- make ICE table for chemical equation resulting in water+salt
- find moles of weak acid/base and apply it to the salt based on ratio
- find concentration of that salt in total volume of sol’n
- make new ICE table with salt + water and determine products (where intial conc. is 0)
- convert Ka or Kb to whtever’s needed using Kw
- make constant expression and plug in all concentrations, apply 100 rule. Isolate for x
- solve for pH or pOH
- solve for pH or pOH