u2: titration Flashcards

1
Q

titrant

A

solution in burette

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2
Q

sample

A

solution analyzed in flask

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3
Q

equivalence point/stoichiometric point

A
  • amnt. of titrant recorded when chemically equivalent amounts have reacted
  • when n H3O = n OH
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4
Q

endpoint

A

point where a sharp change in a measurable/characteristic property occurs (colour, pH)

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5
Q

titration curves: strong acid nd strong base

A

equivalence point at pH=7

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6
Q

what does midpoint/equivalence point look like on graphs?

A

sharp increase in pH

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7
Q

conjugate acid of a strong base is…

A

weak

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8
Q

conjugate base of a strong acid is…

A

weak

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9
Q

titration curves: strong base nd weak acid

A

equivalence point at pH above 7

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10
Q

titration curves: weak base nd strong acid

A

equivalence point at pH below 7

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11
Q

what are titrations not done with?

A

weak acids and weak bases

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12
Q

titration curves: polyprotic acids

A
  • each proton has a diff. equivalence point, so multiple vertical lines exist
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13
Q

how do we solve the long III question?

A
  1. make ICE table for chemical equation resulting in water+salt
  2. find moles of weak acid/base and apply it to the salt based on ratio
  3. find concentration of that salt in total volume of sol’n
  4. make new ICE table with salt + water and determine products (where intial conc. is 0)
  5. convert Ka or Kb to whtever’s needed using Kw
  6. make constant expression and plug in all concentrations, apply 100 rule. Isolate for x
  7. solve for pH or pOH
  8. solve for pH or pOH
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