U2 AOS 1 Chapter 10 C, D & E Flashcards
acidic solution
greater concentration of hydronium ions than hydroxide ions
basic solution
greater concentration of hydroxide ions than hydronium ions
ionic product of water definition
Kw, concentration of ions present in water at 25degrees celcius
autoionisation
process where an atom or molecule spontaneously forms ions
neutral solution
equal concentration of hydroxide and hydronium ions
pH
concentration of hydronium ions in a solution
What happens if the temp and Kw value increases?
The concentration of hydronium ions would increase, pH decreases
ionic product (kw) of water value
Kw = 1.00 x 10^-14M^2 (found by multiplying [H3O+] & [OH-]
calculating pH (formula)
pH=-log[H3O+] OR [H3O+] = 10^-pH
limitations of the pH scale
only works for aqueous solutions
Values only valid at 25oC (298 K)
goes beyond typical range of 0 - 14
can only be readily calculated with strong acids/bases
natural indicator
an indicator made from naturally sourced substances eg. litmus paper
ph meter
instrument used to measure the pH of a solution through quantitative, specific measurement of difference of electrical potential
Why can we calculate the pH of 1.00M HCl but not 1.00M CH3COOH?
HCl = strong acid, CH3COOH = weak acid, only in HCl [H3O+] = [HCl], in CH3COOH, concentration of hydronium cannot be determined from this info alone as it does not completely ionise.
meters vs indicators
meter: quantitative, specific and highly accuracy, reproducible - no change between measurements
indicator: qualitatitive, approximated range of values - low accuracy, if true pH is on border if colour range, pH may differ greatly between trials
indicator
a substance that changes colour to indicate pH range