transition metals Flashcards
How does a catalyst provide an alternative route with a lower activation energy?
Reactants aDsorbed on surface, catalyst provides an active site
Reaction occurs on surface - bond breaking or making. Catalyst aids bonds weakening.
Desorption of the product.
How does Vanadium oxide act as a catalyst in the manufacture of sulfur trioxide? (2 eq.)
How does Fe2+ catalyse the reaction between S2O82- and I- ?
How does Mn2+ autocatalyse ?
Why do complexes form coloured ions?
- Certain frequencies of visible light are absorbed
- To excite electrons in D orbital
- Remaining wavelengths of light are REFLECTED
Reactions of ions you need to know in aqueous solution with NaOH ( a base) and colours.
Fe 3 brown not purple
Reactions of Al complex ions in aqueous solution as acid and base
Reactions with NH3 and the known ions in aq sol. Cu2+ Fe2+ Fe3+ Al3+
What is the exception when aq. ions react with NH3 and the colour change
Light blue to dark blue
How do the M2+ ions react with carbonates in soloution
CuCO3 blue green
How do the M3+ ions react with carbonates in soloution
Reactions with Cl- and colour changes