TRANSITION METAL COLOURS Flashcards

IMPORTANT TO MEMORISE !!!

1
Q

COLOUR OF:

Cu(OH)2(s)

EXTRA: How is it made?

A

PALE BLUE PPT

adding dropwise NaOH/OH- or NH3 to Cu 2+(aq)

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2
Q

COLOUR OF:

[Cu(H2O)6] 2+

EXTRA: How is it made?

A

PALE BLUE

reacting Cu(II)SO4 with water ( dissolving in water)

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3
Q

COLOUR OF:

[Cu(NH3)4(H2O)2 ] 2+

EXTRA: How is it made?

A

DARK BLUE

adding excess NH3 to Cu 2+

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4
Q

COLOUR OF:

CuCl4 2-

EXTRA: How is it made?

A

YELLOW

adding HCl to Cu 2+

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5
Q

COLOUR OF:

Cu +

A

WHITE PRECIPITATE (CuI)
BROWN I2 SOLUTION

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6
Q

COLOUR OF:

Cu2+ / Cu

A

BROWN SOLID
BLUE SOLUTION

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6
Q

COLOUR OF:

CoCl4 2–

A

BLUE SOLUTION

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7
Q

COLOUR OF:

[Cr(H2O)6] 3+

EXTRA: How is it made?

A

PALE PURPLE

Cr(H2O)3(OH)3 (s) + 3H + (aq ) —–> [Cr(H2O)6] 3+ (aq)

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8
Q

WHAT IS SPECIAL ABOUT: Cr(H2O)3(OH)3 (s)

A

This hydroxide is classed as amphoteric because it can react with alkali to give a solution and react with acid to form the aqueous salt.

Cr(H2O)3(OH)3 (s) + 3OH- (aq ) -> [Cr(OH)6]3- (aq) + 3H2O(l)

Cr(H2O)3(OH)3 (s) + 3H+ (aq ) -> [Cr(H2O)6]3+(aq)

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8
Q

COLOUR OF:

Cr(OH)3 (s)

EXTRA: How is it made?

A

DARK GREEN PPT

adding dropwise NH3 or NaOH/OH- to Cr 3+(aq)

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9
Q

COLOUR OF:

[Cr(NH3)6] 3+

EXTRA: How is it made?

A

PURPLE

Adding excess NH3 to Cr 2+

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10
Q

COLOUR OF:

[Cr(OH)6] 3–

EXTRA: How is it made?

A

DARK GREEN

adding excess NaOH/OH- to Cr(OH)3 (s)

Cr(H2O)3(OH)3 (s) + 3OH - (aq ) -> [Cr(OH)6] 3- (aq) + 3H2O(l)

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11
Q

COLOUR OF:

Cr2O7 2–

A

ORANGE

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12
Q

COLOUR OF:

CrO4 2–

A

YELLOW

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13
Q

COLOUR OF:

[Mn(H2O)6] 2+

A

PALE PINK

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14
Q

COLOUR OF:

Mn(OH)2(s)

EXTRA: How is it made?

A

PALE BROWN PPT

adding dropwise NaOH/OH- or NH3 to Mn 2+

15
Q

COLOUR OF:

[Fe(H2O)6] 2+

A

PALE GREEN

16
Q

COLOUR OF:

Fe(OH)2 (s)

EXTRA: How is it made?

A

DARK GREEN PPT

adding dropwise NaOH/OH- or NH3 to Fe 2+

17
Q

COLOUR OF:

[Fe(H2O)6] 3+

A

YELLOW

18
Q

COLOUR OF:

Fe(OH)3 (s)

EXTRA: How is it made?

A

ORANGE-BROWN PPT

adding dropwise NaOH/OH- or NH3 to Fe 3+

19
Q

COLOUR OF:

MnO 4– /Fe 2+ –> Mn 2+ /Fe 3+

A

purple (MnO4 –) to pale pink (Mn 2+)

20
Q

COLOUR OF:

I /Fe 3+ —> I2/Fe 2+

A

orange brown (Fe3+) to brown (I2)

21
Q

what is a :
purple solution

WRITE THE EQUATION FOR IT

A

[Cr(NH3)6] 3+

Cr(OH)3(H2O)3(s) + 6NH3 (aq) –> [Cr(NH3)6]3+(aq) + 3H2O(l) + 3OH- (aq)

22
Q

what is a :
dark green/grey green precipitate

how is it made?

A

Cr(OH)3 (s)

Cr3+ (aq) + 3OH- (aq) –> Cr(OH)3 (s)

23
Q

evaluate all cells

A
24
Q

what are the monodentate ligands

A
25
Q

what are all the bidentate ligands

A
26
Q

hexadentate ligand ?

A
27
Q

how does cis platin work

A
28
Q

what is the relationship between arrhenius and y=mx+c

A

lnk= (-ea/R) (1/T) +lnA

28
Q

draw the enthalpy + entropy temp table

A
29
Q

what is relationship between gibbs and the y = mx +c

A
30
Q

relative mass of electron

A

The relative mass of an electron is 1/1836.

31
Q

Relative Atomic Mass:

A

​the weighted mean mass of an atom compared with 1/12th mass of

32
Q

Relative Isotopic Mass:

A

the mass of an atom of an isotope compared with 1/12th mass of an atom of carbon-12.

33
Q

Relative Formula Mass:

A

*the mass of the formula unit of a compound with a giant structure.

34
Q

RelativeMolecularMass(M​r)

A

:​the mass of a simple molecule.

35
Q

percentage yeild

A

actual/theoretical MASS

36
Q

atom economy

A

mr desired / mr of all reactants