transition metal Flashcards

1
Q

What are transition metals

A

elements in the d-block of the periodic table with a partially filled d-orbital. they lose electrons to form positive ions with the s-orbital electrons being removed first

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2
Q

physical properties of transition metals

A
  • atomic radius
  • high densities
  • high melting and boiling point
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3
Q

chemical properties of transition metals

A
  • can form different ions/complexes
  • form coloured compounds and solutions
  • used as catalysts in industrial processes
  • typically harder/ more dense than other metals
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4
Q

what are complexes

A

These form from transition metals, consisting of a central metal ion or atom surrounded by ligands
they are represented in formulas using []

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5
Q

what are ligands

A

molecules or inos with a lone electron pair that can form a cooridante bond to the central metal ions by donating this electron pair

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6
Q

common ligands include

A
  • Cl-
  • H2O
  • NH3
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7
Q

What is the coordination number equal to

A

equal to the number of coordinate bonds formed around the central metal ino

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8
Q

how are colours produced in complexes

A
  • when a transition metal ion forms a “complex” (e.g. in water) the d orbitals split in energy.
  • particular wavelengths of visible light are absorbed to “excite” to the higher energy level.
  • light that is not absorbed determines the colour we observe
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9
Q

energy equation

A

E = h f

E = energy (J)
f = frequency (Hz)
h = planck’s constant - 6.63 x 10-34 Js

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10
Q

frequency equation

A

f = c / w

f = frequecny (Hz)
c = speed of light - 3 x108 ms-1
w = wavlength (m)

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11
Q

energy and frequency equatio n mixed

A

E = h c / w

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