transition metal Flashcards
What are transition metals
elements in the d-block of the periodic table with a partially filled d-orbital. they lose electrons to form positive ions with the s-orbital electrons being removed first
physical properties of transition metals
- atomic radius
- high densities
- high melting and boiling point
chemical properties of transition metals
- can form different ions/complexes
- form coloured compounds and solutions
- used as catalysts in industrial processes
- typically harder/ more dense than other metals
what are complexes
These form from transition metals, consisting of a central metal ion or atom surrounded by ligands
they are represented in formulas using []
what are ligands
molecules or inos with a lone electron pair that can form a cooridante bond to the central metal ions by donating this electron pair
common ligands include
- Cl-
- H2O
- NH3
What is the coordination number equal to
equal to the number of coordinate bonds formed around the central metal ino
how are colours produced in complexes
- when a transition metal ion forms a “complex” (e.g. in water) the d orbitals split in energy.
- particular wavelengths of visible light are absorbed to “excite” to the higher energy level.
- light that is not absorbed determines the colour we observe
energy equation
E = h f
E = energy (J)
f = frequency (Hz)
h = planck’s constant - 6.63 x 10-34 Js
frequency equation
f = c / w
f = frequecny (Hz)
c = speed of light - 3 x108 ms-1
w = wavlength (m)
energy and frequency equatio n mixed
E = h c / w