Thermodynamic Flashcards

1
Q

what is enthalpy change

A

heat change at constant pressure

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2
Q

what reaction is the first ionisation energy

A

endothermic

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3
Q

first electron affinity

A

energy change when 1 mole of gaseous atoms gain an electron to form 1 mole of gaseous 1- ions

N (g) + e- -> N-(g)

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4
Q

what reaction is the first electron affinity

A

exothermic

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5
Q

second electron affinity

A

energy change when 1 mole of gaseous 1- ions gain an electron to form 1 mole of gaseous 2- ions

V- (g) + e- -> V2- (g)

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6
Q

what reaction is the second electron affinity

A

endothermic

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7
Q

enthalpy of atomisation

A

enthalpy change when 1 mole of gaseous atoms are formed from an element in its standard state

Na(s) -> Na(g)
1/2 F2(g) -> F (g)

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8
Q

what reaction is the enthalpy of atomisation

A

endothermic

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9
Q

lattice enthalpy

A

enthalpy change when 1 mole of an ionic compound is formed from its constituent gaseous ions

Na+(g) + CL-(g) -> NaCl (s)
Zn2+(g) + 2Br-(g) -> ZnBr2

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10
Q

what reaction is the lattice enthalpy

A

exothermic

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11
Q

lattice dissociation enthalpy

A

enthalpy change when 1 mole of an ionic compound is broken into its constituent gaseous ions

NaCl(s) -> Na+(g) + Cl-(g)

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12
Q

what reaction is the lattice disassociation enthalpy

A

endothermic

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13
Q

bond dissociation enthalpy

A

enthalpy change when 1 mole of covalent bonds is broken in the gaseous state

Cl2 (g) -> 2Cl (g)

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14
Q

what reaction is the bond dissociation enthalpy

A

endothermic

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