trace (minor) elements Flashcards
what is a trace (minor) element
<0.1wt% of rocks composition
Reported at ppm or ppb
commonly reported as oxide
trace element examples
TiO2
MnO
P2O5
CO2
why analyze trace elements
sensitive to processes of magma genesis and differentiation
partition coeffiecient
behaviour of trace elements in igneous processes
whether they prefer to enter a crystallizing mineral or remain in melt
concentration of a particular element in a solid/concentration of a particular element in a melt
incompatible trace elements
trace elements concentrated in melt during crystallisation or partial melting
Kd < 1
compatible trace elements
trace elements concentrated in solid during crystallisation or partial melting
Kd > 1
incompatible trace elements examples
large ion lithophile elements (LILE)
high field strength elements (hfse)
rare earth elements (ree)
compatible trace elements examples
Ni
V
Cr
Co
Sc
large ion lithophile elements (LILE) behaviour
fluid-mobile, like to get transported in aqueous fluids
subducting oceanic lithosphere dewaters in subduction zone, carrying LILE. goes up mantle wedge
high field strength elements (hfse) behaviour
not fluid mobile, staying in rocks but when melted, staying in melt
rayleigh fractionation
using trace elements to model perfect fractional crystallization
what are REE atoms
lanthanides
form cations with 3+ charge
ionic radius decreases from la to lu
light and heavy REE compatibility
light REE more incompatible