Topic 8 - Chemical Analysis Flashcards

1
Q

What is a pure substance?

A

A single element or compound, not mixed with any other substance

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2
Q

What is significant about the melting and boiling point of pure elements?

A

They melt and boil at specific temperatures so can be distinguished by this data

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3
Q

What is a formulation?

A

A mixture that has been designed as a useful product

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4
Q

How are formulations made?

A

By mixing the components in carefully measured quantities to insure that the product has its required properties

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5
Q

Give examples of formulations

A

Fuel, cleaning agents, paint, medicines, alloys, fertilisers, foods

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6
Q

What are complex mixtures?

A

Many products are complex mixtures in which each chemical has a particular purpose

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7
Q

What is chromatography used for?

A

To separate mixtures and give information to help identify substances

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8
Q

What are the phases involved in chromatography?

A

The stationary phase and a mobile phase

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9
Q

What does separation by chromatography depend on?

A

The distribution of substances between the phases

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10
Q

What is a compounds Rf value?

A

The ratio of the distance moved by a compound to the distance moved by the solvent

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11
Q

Why can you identify a compound from its RF value?

A

Different compounds have different Rf values in different solvents

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12
Q

What happens to the compounds in a mixture during chromatography?

A

They may separate into different spots depending on the solvent

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13
Q

What happens to a pure compound during chromatography?

A

It will produce a single spot in all solvents

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14
Q

What is the test for hydrogen?

A

Hold a burning splint at the end of an open test tube - hydrogen burns rapidly with a pop sound

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15
Q

What is the test for oxygen?

A

Insert a glowing splint into a test tube – the splint relights in oxygen

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16
Q

What is the test for carbon dioxide?

A

Use an aqueous solution of calcium hydroxide (lime water) – when carbon dioxide is shaken with or bubbled through limewater it turns cloudy

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17
Q

What is the test for chlorine?

A

When damp litmus paper is put into chlorine gas the litmus paper is bleached and turns white

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18
Q

What can flame tests be used for?

A

To identify some metal ions (Cations)

19
Q

What colour does lithium compounds go during a flame test?

20
Q

What colour does sodium compounds go in a flame test?

A

Yellow flame

21
Q

What colour do potassium compounds go in flame tests?

22
Q

What colour do calcium compounds go in flame tests?

A

Orange – red flame

23
Q

What colour do copper compounds go in a flame test?

24
Q

What happens if a sample containing a mixture of ions is used for a flame test?

A

Some flame colours can be masked

25
What can sodium hydroxide solution be used for?
To identify some metal ions (cations)
26
What solutions form white precipitate when sodium is hydroxide solution is added?
Aluminium, calcium and magnesium
27
What happens to the aluminium hydroxide precipitate in excess sodium hydroxide solution?
It dissolves
28
What solutions from coloured precipitate when sodium hydroxide solution is added?
Copper II, iron II, iron III
29
What colour does copper II form when added to sodium hydroxide solution?
Blue
30
What colour does iron II form when added to sodium hydroxide solution?
Green
31
What colour does iron III form when added to sodium hydroxide solution?
Brown
32
What is formed when carbonates react with dilutes acid?
Carbon dioxide gas
33
How can Carbon dioxide gas be identified?
With lime water
34
What do halide ions and silver nitrate solution form in the presence of dilute nitric acid?
Precipitates
35
What colour does silver chloride go when reacted with silver nitrate solution in the presence of dilute nitric acid?
White
36
What colour does silver bromide go when reacted with silver nitrate solution in the presence of dilute nitric acid?
Cream
37
What colour does silver iodide go when reacted with silver nitrate solution in the presence of dilute nitric acid?
Yellow
38
How do you test for sulphate?
React sulphate ions with barium chloride solution in the presence of dilutes hydrochloric acid to produce a white precipitate
39
How else can elements and compounds be detected?
Using instrumental methods
40
What are the advantages for instrumental methods?
Accurate, sensitive and rapid
41
What is flame emission spectroscopy?
And instrumental methods used to analyse metal ions in solutions
42
How do you do flame emission spectroscopy?
The sample is put into a flame and the light given out is passed through a spectroscope
43
What is the output of a flame emission spectroscope?
A line spectrum that can be analysed to identify the metal ions in the solution and measure their concentrations