Topic 7Organic Chem Flashcards

1
Q

Alkane formula

A

CnH2n+2

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2
Q

What series are alkanes in

A

Homologous

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3
Q

What are the four main alkanes and what are their formulas

A

Methane CH4
Ethane C2H6
Propane C3H8
Butane C4H10

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4
Q

Do hydrocarbons properties change as they get longer

A

True
When they are shorter hydrocarbons are runny less viscous more volatile and have lower boiling point more flammable.

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5
Q

What does there need to be a lot of for complete combustion to take place

A

Oxygen

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6
Q

Waste products of complete combustion

A

Carbon dioxide and water

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7
Q

Equation for compete combustion

A

Hydrocarbon + oxygen— carbon dioxide + water

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8
Q

Is crude oil renewable

A

No as it takes millions of years to form and its is a fossil fuel as it is a finite resource

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9
Q

What is the temp gradient in heating columns

A

Hot at bottom cool at top

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10
Q

What is formed in fractional distillation columns

A

Petrol
Kerosene (jet fuel)
Diesel
Heavy fuel oils

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11
Q

Where are shorter chains found in fractional distillation columns

A

At the top

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12
Q

What is the purpose of cracking

A

Process of breaking down long hydrocarbon into shorter more useful hydrocarbons

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13
Q

What is the formula for alkene

A

alkene CnH2n

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14
Q

What is the difference between Alkanes and Alkenes

A

Alkanes carbon carbon single bond C-C
Alkenes carbon carbon double bond C=C

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15
Q

How do you test for an alkene

A

Add bromine water if it is present it turn from orange to colourless

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16
Q

How is cracking preformed

A

Cracking is a thermal decomposition reaction (breaking moleculs with heat)
1) Heat hydrocarbons so they vapourise
2) Vapour is passed over hot aluminum oxide catalyst
3) Long chain molecules split apart on surface

17
Q

What are the four main alkene and what are the formulas for them

A

Ethene C2H4
Propene C3H6
Butene C4H8
Pentene C5H10

18
Q

What type of flame do Alkenes burn with

A

A smokey flame

19
Q

Equation for incomplete combustion

A

Alkene + oxygen– carbon + carbon monoxide + carbon dioxide + water

20
Q

What is a polymer

A

Are long molecules made of small molecules called monomers joined together

21
Q

What is addition polymerisation

A

It happens when alkene monomers join together by breaking there C=C double bond to form a long chain polymer with only one product

22
Q

What is a repeating unit for a addition polymer

A

it is where the smallest section of a polymer is repeated to form a new polymer.
Eg Poly(ethene) (-CH2-CH2-)n

23
Q

How do you make a monomer from a polymer

A

Add the C=C double bond back
Remove the poly from the start
Polypropene - propene

24
Q

What is the general formula for alcohols

25
What are the 4 first alcohols and what re there formulas
Methonal CH3OH Ethanol C2H5OH PropanolC3H7OH Butanol C4H9OH
26
What are the main reactions of Alcohols
They are flammable Burns in oxygen for complete combustion to produce Carbon Dioxide and Water Soluble in water reacts with sodium react with carboxylic acids to form esters
27
How is ethanol made and what are its uses
Made in fermentation equation Glucose -- ethanol + carbon dioxide happens fastest at 37 C
28
General formula for Carboxylic acids and what are the main ones
CnH2n+1COOH Methanoic acid HCOOH Ethanoic acid CH3COOH Propanoic acid C2H5COOH Butanoic acid C3H7COOH
29
What do carboxylic acids produce
Salt, water, carbon dioxide
30
When salts are formed what does it end in
anoate eg methanoate
31
What do carboxylic acids release when they dissolve in water and do they completely ionise
Release H+ don't completely ionise and form weak acids
32
What are esters functional group
COO
33
What is condensation polymerization
Involves monomers with two functional groups forming a polymer and a small molecule. An example is a Polyester
34
Compare addition and condensation polymerization
Addition Condensation Monomers Alkenes monomers with 2 functional groups Bonds Form C-C single bonds Ester/Amide bonds Products The polymer Polymer+ small molecule
35
What are 3 naturally occurring polymers
Proteins made from amino acids (Polypeptides Carbohydrates made from sugar monomers DNA made from nucleotide monomers
36
What are the monomers of DNA
Nucleotide monomers
37
What type of polymerization forms proteins
condensation polymerization of proteins creating peptide bonds which release water