Topic 7- rates of reactions Flashcards

1
Q

Describe the core practical in which we observe a colour change

A

Put 50cm3 of sodium thiosulfate solution in a flask.
Measure 5cm3 of dilute hydrochloric acid in a small measuring cylinder.
Add the acid to the flask and immediately start timer. Swirl the flask to the mix the solutions and place it on a piece of paper marked with a cross. When the cross disappears stop the clock and note time
Repeat using different concentrations of sodium thiosulfate,

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2
Q

How can the rate of a reaction be measured

A

By the rate at which a reactant is used up, or the rate at which a product is formed.
Measure the rate at which a reactant is used up and measure the rate at which a product is formed.

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3
Q

What 2 things do we measure when measuring rates of reactions

A

The mass of a substance- solid, liquid or gas- is measured with a balance.
The volume of a gas is usually measured with a gas syringe, or sometimes an upside down measuring cylinder or burette

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4
Q

Rate of reaction equation

A

Amount of reactant used or product formed DIVIDED by time taken

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5
Q

How do reactions occur and how can they be increased

A

Particles colliding and the rate if reaction is increased when the the frequency and/or energy of collisions is increased

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6
Q

How can temperature effect rate of reaction

A

A higher temperature means particles have more kinetic energy and therefore means more frequent collisions

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7
Q

How can concentration increase rate of reaction

A

An increased concentration increases rate of reaction because the particles are closer together and there are more of them

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8
Q

How can surface area to volume ratio effect rate of reaction

A

An increased surface area increases rate of reaction

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9
Q

What is a catalsyt

A

A substance that speeds up the rate of a reaction without altering the products of a reaction, being itself unchanged chemically and in mass at the end of a reaction

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10
Q

What effect does a catalyst have on energy

A

Increases rate of reaction by lowering activation energy

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11
Q

What are enzymes

A

biological catalysts which are used in the production of alcoholic drinks

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12
Q

What are the advantages of catalysts

A

Speeds up rate
Reusable, initial expense is repaid
Lower activation energy means less money spent on energy

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13
Q

List examples of where heat energy accompanies changes

A

-Salts dissolving in water
-Neutralisation reactions
-Displacement reactions
-Precipitation reactions
When these reactions take place in solution, temperature changes can be measured to reflect the heat changes

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14
Q

What is an exothermic reaction

A

a reaction/change in which heat energy is given out

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15
Q

What is an endothermic reaction

A

a reaction/change in which heat energy is taken in

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16
Q

What type of reaction is making bonds

A

Exothermic

17
Q

What type of reaction is breaking bonds

A

Endothermic

18
Q

How do we know when the overall heat energy change for a reaction is exothermic

A

Exothermic if more heat energy is released in forming bonds in the products than is required in breaking bonds in the reactants

19
Q

How do we know when the overall heat energy change for a reaction is endothermic

A

If less heat energy is released in forming bonds in the products than is required in breaking bonds in the reactants

20
Q

What is the calculation energy change measured in

A

kJ mol -1

21
Q

Explain the term activation energy

A

The energy curve goes up from the reactants energy level to begin with and then drops to the products energy level. This is because many reactions need an input of energy to start reaction off= activation energy

22
Q

General formula for carboxylic acids

A

C(n-1) H(2n-1) COOH

23
Q

What can alcohols be oxidised to form

A

Carboxylic acids

24
Q

What’s the general formula for an alcohol

A

Cn H(2n-1) OH