Topic 7- organic chemistry: Flashcards
What are hydrocarbons?
Any compound that is formed form hydrogen and carbon atoms only.
Alkanes:
- The simplest type of hydrocarboon you can get
- General formula- C(n)H(2n+2)
- They are a homoglous series- group of organic compounds that work in similar ways
- They are saturated compunds- each carbon atom forms 4 bonds
- First 4- Methane, Ethane, Propane, Butane. (Monkeys Eat Peanut Butter)
Properties of hydrocarbons:
- Properties of hydrocarbons change as the carbon chain gets longer
- The shorter the carbon chain, the more runny and less viscous (gloopy) it is
- The shorter the carbon chain, the more voaltile the hydrocarbon is- lower it’s boiling point
- The shorter the hydrocarbon, the more flammable it is
- They are burnt so they can be used as fuel as the reaction produces energy
Complete combustion:
- Occurs when there is a lot of oxygen
- Complete combustion of any hydrocarbon releases lots of enegy- waste products are CO2 and water
- Hydrocarbon + oxygen 🡒 carbon dioxide + water (+energy)
- During combustion, both the hydrogen and carbon from the hydrocarbon are oxidised
Crude oil:
- A finite resource found in rocks
- A fossil fuel form the remains of ancient biomass- mainly of plankton buried in mud
- Turned to crude oil due to high temperature and high pressure
- A mixture of lots of different hydrocarbons (mostly alkanes)
- Different compounds can be seperated using farctional distillation
Fractional distillation:
- The oil is heated until most of it turns into gas, the gases enter the fractionating collumn
- In the colllumn, the temperature is hotter at the bottom and cooler at the top
- Longer hydrocarbons have higher boiling points. Shorter hydrocarbons have lower boiling points
- So they will condense at different levels in the tower
What are the uses of crude oil?
- Provides the fuel for modern transport
- The petrochemical industry uses some hydrocarbbons from crude oil as feedstock to make new compounds for use in polymers, solvents, lubricants and detergenets
- All products from crude oil are an example of organic compund (they contain carbon atoms)
Cracking:
Cracking means splitting up long-chain hydrocarbons
* This is because short-chain hydrocarbons are flammable so make good fuels and are high in demand
* As a result, the longer alkane molecules produced by fractional distillation are turned into smaller, more useful ones by cracking.
Processes of cracking:
Cracking is a thermal decomposition reaction-breaks molecules diwn by heating them
* The long-chain hydrocarbons must be heated to vaporise them
* Then either catalytic cracking or steam cracking take place.
Process of catalytic cracking:
Pass them over a hot catalyst and the long-chain molecules split apart on the surface
Process of steam cracking:
Mix them with steam and heat them to a very high temperature so that thermal decomposition reactions can occur
General equation for cracking:
Long chain hydrocarbon molecule → shorter alkane molecule + alkene