Topic 6B Flashcards

1
Q

general formula for alkanes

A

CnH2n+2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

cracking

A

conversion of large hydrocarbons to smaller molecules by breakage of C-C bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

fractional distillation

A
  • oil is pre-heated then passed into a column
  • fractions condense at different heights
  • temperature of column decreases as you go up
  • separation depends on boiling point
  • small molecules condense at top (low temp) and large molecules condense at bottom (high temp)
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

economic reasons for catalytic cracking

A
  • shorter C chains are more in demand than larger fractions
  • large hydrocarbons are cracked to produce shorter ones
  • the products are more useful and valuable
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

reforming

A

turning straight chain alkanes into branched and cyclic alkanes and aromatic hydrocarbons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

complete combustion products

A
  • CO2 and H2O
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

incomplete combustion products

A
  • carbon monoxide
  • carbon
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

cons of carbon monoxide production

A
  • highly toxic
  • can form a strong bond with haemoglobin in RBC
  • prevents oxygen attaching to the haemoglobin as the bond is stronger between the CO and haemoglobin
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

cons of carbon

A
  • soot particles can cause global dimming
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

where are nitrogen oxides formed

A
  • nitrogen oxides form in the reaction between N2 and O2 inside the car engine
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

how are nitrogen oxides formed

A
  • the high temperature and spark in the engine provide sufficient energy to break a strong N2 bond
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

cons of nitrogen oxides

A
  • NO is toxic and can form smog
  • NO2 is toxic and acidic and forms acid rain
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

cons of unburn hydrocarbons

A

contribute towards formation of smog

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

catalytic converters

A

remove CO, NOx and unburned hydrocarbons from the exhaust gases and turn them into harmless CO2, N2 & H2O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

what do catalytic converted have

A
  • they have a ceramic honeycomb coated with a thin layer of catalyst metals, platinum, palladium, rhodium to give a large surface area
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

advantages of using biofuels

A
  • reduction of use of fossil fuels which are finite resources
  • biofuels are renewable
  • use of biodiesel is more carbon-neutral
  • allows fossil fuels to be used as a feedstock for organic compounds
  • no risk of large scale pollution from exploitation of fossil fuels
17
Q

disadvantages of biofuels

A
  • less food crops may be grown
  • land not used to grow food crops
  • rain forests have to be cut down to provide land
  • shortage of fertile soils
18
Q

what is a free radical

A
  • a species which possess an unpaired electron
19
Q

how is a radical formed

A
  • via homolytic fission of a covalent bond
  • each atom gets one electron from the covalent bond
20
Q

reactions of alkanes with halogens

A
  • free radical substitution
21
Q

what is the essential condition for free radical substitution

A

UV light

22
Q

limitations of free radical substitution

A
  • collisions are uncontrollable so you can’t make one specific product
  • hence further substitutions occur creating a mixture of products