Topic 6B Flashcards
general formula for alkanes
CnH2n+2
cracking
conversion of large hydrocarbons to smaller molecules by breakage of C-C bonds
fractional distillation
- oil is pre-heated then passed into a column
- fractions condense at different heights
- temperature of column decreases as you go up
- separation depends on boiling point
- small molecules condense at top (low temp) and large molecules condense at bottom (high temp)
economic reasons for catalytic cracking
- shorter C chains are more in demand than larger fractions
- large hydrocarbons are cracked to produce shorter ones
- the products are more useful and valuable
reforming
turning straight chain alkanes into branched and cyclic alkanes and aromatic hydrocarbons
complete combustion products
- CO2 and H2O
incomplete combustion products
- carbon monoxide
- carbon
cons of carbon monoxide production
- highly toxic
- can form a strong bond with haemoglobin in RBC
- prevents oxygen attaching to the haemoglobin as the bond is stronger between the CO and haemoglobin
cons of carbon
- soot particles can cause global dimming
where are nitrogen oxides formed
- nitrogen oxides form in the reaction between N2 and O2 inside the car engine
how are nitrogen oxides formed
- the high temperature and spark in the engine provide sufficient energy to break a strong N2 bond
cons of nitrogen oxides
- NO is toxic and can form smog
- NO2 is toxic and acidic and forms acid rain
cons of unburn hydrocarbons
contribute towards formation of smog
catalytic converters
remove CO, NOx and unburned hydrocarbons from the exhaust gases and turn them into harmless CO2, N2 & H2O
what do catalytic converted have
- they have a ceramic honeycomb coated with a thin layer of catalyst metals, platinum, palladium, rhodium to give a large surface area