TOPIC 6 Flashcards

1
Q

What is Entropy?

A

The ENTROPY of a system can in fact be shown to be a measure of its disorder and of the UNAVAILABILITY OF ENERGY TO DO WORK.

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2
Q

simple definition of energy

A

the ability to do work

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3
Q

is a measure of how much energy is not available to do work.

A

entropy

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4
Q

That unavailable energy is of interest in thermodynamics, because

A

the field of thermodynamics arose from efforts to convert heat to work.

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5
Q

Unit of Entropy

A

J/K

KJ/K

Btu/°R

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6
Q

Unit for Specific Entropy

A

KJ/kg K (for s)

KJ/kmol K (for s line)

Btu/lb °R (for s)

Btu/lbmol °R (for s line)

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7
Q

Btu/°R to J/K

A

1899.1 J/K

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8
Q

Btu to J

A

1055.06 J

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9
Q

lb to kg

A

0.454 kg

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10
Q

K to R

A

1.8 R

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11
Q

Linear Interpolation Formula

A

y = y1 + x - x1 / x2 - x1 (y2 - y1)

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12
Q

For saturation states, the values of sf and sg are tabulated as a function of

A

either saturation pressure or saturation temperature

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13
Q

entropy of a two-phase liquid–vapor mixture is calculated using the quality

A

s = (1 - x) sf + xsg
= sf + x (sg - sf)

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14
Q

the quality (x) of the mixture can be determined from the knows specific internal energy

A

x = u - uf / ug - uf

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15
Q

Temperature–Entropy Diagram is also known as

A

T-s Diagram

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16
Q

Enthalpy–Entropy Diagram is also known as

A

h-s diagram or Mollier diagram

17
Q

intended for evaluating properties at superheated vapor states and for two-phase liquid–vapor mixtures

A

h-s diagram or Mollier diagram

18
Q

is an expression of the second law that is particularly effective for thermodynamic analysis

A

entropy balance

19
Q

Entropy Balance for CLOSED Systems

A

(change in the amount of entropy contained within the system during some time interval)
=
(net amount of entropy transferred in across the system boundary during the time interval)
+
(amount of entropy produced within the system during the time interval)

20
Q

(Equation) Entropy transfer

A

it is associated with heat transfer to or from the system during the process

21
Q

(Equation) Entropy transfer: it can be interpreted

A

entropy transfer accompanying heat transfer.

22
Q

(Equation) Entropy transfer

A

The direction of entropy transfer is the same as the direction of the heat transfer, and the same sign convention applies as for heat transfer:

23
Q

Positive value in entropy means

A

entropy is transferred into the system

24
Q

Negative value in entropy means

A

entropy is transferred out the system

25
Q

When there is NO HEAT TRANSFER

A

there is NO ENTROPY TRANSFER.

25
Q

The term σ is positive when

A

internal irreversibilities are present during the process and vanishes when no internal irreversibilities are present

26
Q

entropy is produced (or generated) within the system by

A

by the action of irreversibilities.

27
Q

Entropy production is a property?

A

Entropy production is not a property

28
Q

The second law requires that

A

entropy production be positive, or zero, in value:

29
Q

σ > 0

A

irreversibilities present within the system

30
Q

σ = 0

A

no irreversibilities present within the system

31
Q

The value of the entropy production (σ)

A

CANNOT BE NEGATIVE

32
Q

In contrast, the CHANGE IN ENTROPY (Δ S) of the system may be positive, negative, or zero:

A

. > 0
S2 - S1 = 0
< 0

33
Q

To evaluate the entropy transfer term of the
entropy balance requires

A

information regarding both the heat transfer and the temperature on the boundary where the heat transfer occurs.

34
Q
A