Topic 2 Flashcards
Energy and the First Law of Thermodynamics
Kinetic energy is
Scalar Quantity
What is an extensive property?
An extensive property is one that depends on the amount of matter in a system or the size of the system
Why is kinetic energy an extensive property?
it changes in proportion to the amount of matter in a system
What is the difference between a scalar and a vector quantity?
A scalar quantity has only magnitude, but no direction. Vector quantity has both magnitude and direction
Why is potential energy also considered an extensive property?
Because it depends on the amount of matter in the system—in other words, it scales with the size or quantity of the system.
Work is equal to
Force (distance)
Conversation of Energy
states that the total work of all forces acting on the body from the surroundings, with the exception of the gravitational force, equals the sum of the changes in the kinetic and potential energies of the body.
Thermodynamic definition of work
“Work is done by a system on its surroundings if the sole effect
on everything external to the system could have been the
raising of a weight.
W > 0
positive (+)
W < 0:
negative (-)
work done BY the system
positive (+)
work done ON the system
negative (-)
The rate of energy transfer by work
Power
is one in which the departure from thermodynamic equilibrium is at most infinitesimal.
quasiequilibrium process (or quasistatic) process
a change that a gas undergoes under general conditions
Polytropic Process
When n = 0 in a polytropic process
process is an isobaric (constant-pressure) process
When n = +- infinity in a polytropic process
process is an isometric (constant-volume) process
For ideal gas n = 1 in a polytropic process
isothermal (constant-temperature) process
Internal energy is what property
extensive property of the system
amount of energy transferred across the boundary of a system in a heat interaction with the system’s surroundings.
Heat
Q > 0
positive (+)
Q < 0
negative (-)