topic 6 Flashcards

1
Q

for a chemical reaction to occur particles must : (2)

A
  1. collide in the correct orientation
  2. with enough energy for a reaction to take place called the activation energy
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2
Q

what is the rate of reaction

A

the speed at which the reaction takes place

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3
Q

ways to speed up chemical reactions

A
  1. lower volume (increase pressure)
  2. increase number of particles
  3. increasing temperature
  4. increasing surface area
  5. using a catalyst
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4
Q

what does increasing concentration mean, and how is it achieved

A

increases number of solute particles per unit volume, achieved by adding more particles

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5
Q

what does increasing the concentration do in terms of particles

A

increases the frequency of collisions and rate of reaction

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6
Q

what does increasing pressure mean, and how is it achieved

A

increases the number of gas particles per unit volume. achieved by adding particles or reducing container volume

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7
Q

what does increasing pressure do in terms of particles

A

increases the frequency of collision and rate of reaction

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8
Q

what does increasing temperature do do particles

A

increases the kinetic energy allowing more particles to collide more frequently and with enough energy to overcome the activation energy,

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9
Q

what does increasing surface area mean

A

means more particles are exposed on the outside, fewer unexposed particles in the middle.

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10
Q

what are catalysts and what do they do to rate of reaction in chemistry

A

are chemicals that speed up the rate of reaction without being used up or changing at the end of the reactions. they do this by allowing the reactant particles to collide more easily making the collisions more successful

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11
Q

what happens to the rate of reaction as reactions take place

A

rate of reaction decreases because as more products are formed, concentration of reactants decrease.

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12
Q

what happens to bonds when making new particles

A

bonds between reactant particles must be broken

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13
Q

about an endothermic reaction
- energy, bonds, temp

A
  • absorbing energy
  • breaking bonds = absorbing energy
  • temperature of surrounding decreases
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14
Q

about an exothermic reaction
- energy, bonds, temp

A
  • involves releasing energy
  • making bonds = releasing energy
  • temperature of surroundings increase
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15
Q

what does it mean in terms of bonds when a overall reaction is exothermic

A

energy absorbed to break bonds < energy released to make bonds

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16
Q

what does it mean in terms of bonds when a overall reaction is
endothermic

A

energy absorbed to break bonds > energy released to make bonds

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17
Q

what is enthalpy , and units

A

the change in energy between reactants and products
kj/mol or kj mol -1

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18
Q

enthalpy equation

A

total energy of bonds broken - total energy of bonds made

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19
Q

what is a negative and positive enthalpy

A

positive - endothermic
negative - exothermic

20
Q

a reversible reaction can only occur if ..

A

the product or reactant is not limiting or limited by a limiting factor

21
Q

definition of equilibrium

A
  • rate of forward and reverse reaction is equal
  • the concentration of the reactant(s) and product(s) remain constant
  • requires a closed system where no matter can escape or be introduced
22
Q

what is Le Chatelier’s principle

A

any change to an equilibrium will eventually return to equilibrium

23
Q

what does increasing temp favour and what does decreasing temp favour

A

increase favours endothermic
decrease favours exothermic

24
Q

what does increasing concentration favour and what does decreasing concentration favour

A

increase reactants favours products/ forward reaction
increase products favours reactants / reverse reaction

25
Q

what does increasing pressure favour and what does decreasing pressure favour

A

increase favours side with less moles
decrease favours side with more moles

26
Q

what does adding a catalyst do to equilibrium position do

A

nothing, both forward and reverse reaction are being sped up equally

27
Q

what is the haber process used for

A

used to manufacture ammonia to produce nitrogen based fertilizers

28
Q

haber process symbol equaion

A

N2 (g) + 3H2 (g) -> 2NH3 (g)

29
Q

enthalpy of

A
30
Q

haber process, endo or exo, enthalpy value

A

-92 kj mol -1 , exothermic

31
Q

raw materials in haber process

A

nitrogen from air, hydrogen from natural gas (methane)

32
Q

conditions needed for haber process

A

iron catalyst , high temperature, high pressure

33
Q

what happens at the end of haber process

A

on cooling ammonia is liquified and removed so that it doesnt break down again

34
Q

best temp for haber process and why

A

450 oC , a compromise as it provides best rate of reaction and yield.

35
Q

best pressure for haber process, why

A

200 atm, safer and saves money

36
Q

raw materials in the contact process

A

sulfur , air , and water

37
Q

conditions needed for contact process

A

vanadium oxide (V2O5) catalyst, 450 oC, 2 atm

38
Q

symbol equation for the conversion of sulfur dioxide to sulfur trioxide in the contact process

A

2SO2 (g) + O2 -> 2SO3 (g)

39
Q

steps in contact process (3)

A

1 sulfur is burned in air to produce sulfur dioxide
2. sulfur dioxide reacts with air with the presence of a vanadium oxide catalyst to form sulfur trioxide
3. sulfur trioxide mixed with dilute sulfuric acid to produce oleum,
oleum mixed with water to produce sulfuric acid.

40
Q

why is the specific temp used in the contact process

A

catalyst doesn’t work below 400 oC, high temp decreases yield but low temp gives low rate of reaction

41
Q

enthalpy of main contact process reaction

A
  • 196 kj mol -1
42
Q

why is a moderate pressure used in the contact process

A

position of equilibrium already favours the right (bc lower moles) so high pressure is too expensive and not needed.

43
Q

sources of sulfur

A

volcanoes , metal ores, fossil fuels

44
Q

uses of sulfuric acid

A

fertilisers , manufacture of chemicals, processing metal, batteries

45
Q

properties of sulfuric acid

A

strong acid, corrosive, good electrolyte , dehydrating agent.