Topic 4 - Atomic Structure Flashcards
Which group of historic people were the first to think about atoms?
The greeks
What did Democritus think about matter? When? (2)
- Thought all matter was made up of identical lumps called ‘atomos’.
- 5th century BC
What did John Dalton think/do regarding the understanding of atoms? When? (3)
- He agreed with Democritus that matter is made up of tiny spheres that couldn’t be broken up.
- But thought each element was made up of different types of atoms.
- 1804
What did JJ Thomson discover? When? (2)
- Discovered particles called electrons that could be removed from atoms.
- Around 1905
What did JJ Thomson’s discovery mean for John Dalton’s theory? What did Thompson suggest instead? (2)
- Dalton’s theory was now proved incorrect.
- Thomson suggested that atoms were spheres of positive charge with tiny negative electrons stuck in them - ‘plum pudding model’.
What was Rutherford’s experiment? How did it work? (3)
- Alpha Particles Scattering Experiment.
- Fired beam of alpha particles at thin gold foil.
- A circular detector screen surrounds the gold foil and the alpha source, and is used to detect alpha particles deflected by an angle.
What was the expected outcome of the alpha particles scattering experiment?
Expected that the positively charged alpha particles would go straight through or be slightly deflected by electrons if plum pudding model was true.
What was the actual outcome of the alpha particle scattering experiment? (3)
- Most particles went straight through foil.
- Some deflected back more than expected and some came completely out.
- Showed that atoms must have small, positively charged nuclei at centre.
Why did the alpha particle scattering experiment show that atoms must have small, positively charged nuclei at their centre? (3)
- Most of atom = empty space as most alpha particles passed straight through the foil.
- Nucleus must have large positive charge as some positively charged alpha particles were repelled and deflected by a big angle.
- Nucleus must be small as very few alpha particles were deflected back.
How did Niels Bohr adapt the initial nuclear model, which had been derived from the alpha particle scattering experiment? Was it accepted? Why? (3)
- He concluded that electrons orbiting the nucleus can only do so at certain distances.
- These distances are called energy levels.
- Bohr’s theoretical calculations were found to agree with experimental data, so the model was accepted.
How did evidence from further experiments change Niels Bohr’s nuclear model?
Evidence changed the model to think of the positively charged nucleus as a group of particles (protons) which all had the same positive charge that added up to the overall charge of the nucleus.
What did James Chadwick do after the idea of the nucleus was accepted? When? (2)
- He proved the existence of the neutron, which explained the imbalance between atomic and mass numbers.
- 1932 - about 20 years after the idea of the nucleus was accepted.
What 3 types of particle does the atom contain, according to the nuclear model?
- Electrons => negatively charged
- Protons => positively charged
- Neutrons => neutral/no charge
Where is the nucleus? What is the mass of the nucleus? What does it contain? The size? (4)
- At centre of atom.
- Tiny but makes up most of the mass of the atom.
- Contains protons and neutrons - giving it an overall positive charge.
- Radius of nucleus is about 10,000 times smaller than the radius of the atom.
What gives the atom its overall size?
The negative electrons which move round the outside of the nucleus really fast.
What is the radius of an atom?
About 1 x 10(-10) m
What is the relative mass and charge of the proton?
- 1
- +1
What is the relative mass and charge of the neutron?
- 1
- 0
What is the relative mass and charge of the electron?
- 1/2000
- -1
Do atoms have an overall charge? Why? (2)
- No overall charge.
- The charge of an electron is equal and opposite to the charge of a proton meaning the number of protons always equals the number of electrons in a neutral atom.
Can electrons move within or leave energy levels of an atom? How?
- Electrons can move within or sometimes leave the energy levels of an atom.
- If they gain energy by absorbing EM radiation they move to a higher energy level, further from the nucleus.
- If they release EM radiation, they move to a lower energy level that is closer to the nucleus.
What is the atomic number?
The number of protons in the nucleus of an atom.
What is the mass number?
The number of protons plus the number of neutrons in the nucleus of an atom.
What is an ion? (2)
- Atoms are neutral, but if some electrons are added or removed, the atom becomes a charged particle called an ion.
- The ions still have the same number of protons and neutrons as usual, but a different number of electrons.
What is ionisation?
If an atom has had electrons added or removed. and has become an ion, it is said to have been ionised. This process is called ionisation.
What are isotopes? (3)
- Isotopes are different forms of the same element.
- Isotopes have atoms with the same number of protons but a different number of neutrons.
- This means they have the same atomic number (same charge on nucleus), but different mass numbers.
Do all elements have different isotopes? What quality do unstable isotopes have? (2)
- All elements have different isotopes, but there are usually only one or two stable ones.
- The unstable isotopes are radioactive, meaning they decay into other elements and give out radiation.
What is radioactive decay?
Unstable isotopes tend to decay into other elements and give out radiation as they try to become more stable. This process is called radioactive decay.
Is the process of radioactive decay random? What does this mean? (3)
- The process is completely random.
- This means that if you have a load of unstable nuclei, you can’t say when any one of them is going to decay, and neither can you do anything at all to make a decay happen.
*It’s completely unaffected by physical conditions like temperature, or by any sort of chemical bonding, etc.
What do radioactive substance emit? What is this? What does the ionising power of a radiation source tell you? (3)
- Radioactive substances emit ionising radiation.
- Ionising radiation is radiation that knocks electrons off atoms, creating positive ions.
- The ionising power of a radiation source tells you how easily it can do this.
What do radioactive substances release as they decay? (2)
- One or more types of ionising radiation.
- Neutrons, as they try to rebalance their atomic and mass numbers.
What types of ionising radiation am I required to know about? (3)
- Alpha
- Beta
- Gamma
What is an alpha particle?
It is two neutrons and two protons - the same as a helium nucleus.
What is alpha radiation/ decay? (definition)
When an alpha particle is emitted from the nucleus. This means an alpha particle (two neutrons and two protons) is lost from the unstable nucleus.
How does alpha radiation work? How does it affect the atomic and mass numbers? (process) (3)
- When an atom decays by emitting an alpha particle, two protons and two neutrons are lost from the nucleus.
- As protons have a relative charge of +1, alpha emission decreases the charge on the nucleus and the atomic number by 2.
- The mass number decreases by 4, as protons and neutrons each have a relative mass of 1.
What are 3 main characteristics of alpha particles? What does this mean? (3)
- Alpha particles are relatively big, heavy and slow-moving.
- This means they don’t penetrate very far into materials and are stopped quickly.
- They only travel a few centimetres in air and are absorbed by a piece of paper.
What does the size of the alpha particles mean?
Because of their size, they are strongly ionising - they bash into a lot of atoms and knock electrons off them before they slow down, which creates a lot of ions.
How is alpha radiation used in smoke detectors? (3)
- It ionises air particles, causing a current to flow.
- If there is smoke in the air, the smoke binds to the ions, reducing the number available to carry a current.
- The current falls and the alarm sounds.
In summary, what part(s) of the nucleus does alpha decay change?
- The mass
- The charge
What is a beta particle?
A beta particle is a fast-moving electron released by a nucleus. It has virtually no mass and a relative charge of -1.
What is beta decay? (process) (2)
- When a nucleus decays by beta decay, a neutron turns into a proton in the nucleus, releasing a beta particle.
- This increases the charge on the nucleus (and the atomic number) by 1 but leaves the mass number unchanged.
What are 6 key facts/ characteristics of beta particles?
- Move quite fast
- Quite small
- Moderately ionising
- Penetrate moderately far into materials before colliding
- Have a range in air of a few metres
- Can be absorbed by a sheet of aluminium (around 5 mm thick)
How are beta emitters used to test the thickness of thin sheets of metal?
Beta emitters are used to test the thickness of thin sheets of metal, as the particles are not immediately absorbed by the material like alpha radiation would be, and do not penetrate as far as gamma rays.
In summary, what part(s) of the nucleus does beta decay change?
Only the charge of the nucleus.
What are gamma rays? (2)
- Gamma rays are very short wavelength electromagnetic waves released by the nucleus.
- They have no mass, and no charge.