Topic 3 - chemical changes Flashcards
Which ions make aqueous solutions acidic?
Hydrogen
Which ions make aqueous solutions alkaline?
Hydroxide
What is the pH scale?
It ranges from pH 0 to pH 14 and measures the acidity or alkalinity of a solution
What is the pH of a neutral solution?
7
What is the pH range for acids?
Less the pH 7
What is the range of pH for alkaline?
More than pH 7
What can be used to measure pH?
Universal indicator
pH probe
What colour is phenolphthalein in acid and alkali?
Acid - pink
Alkali - colourless
What colour is methyl orange ina an acid and an alkali?
Acid - red
Alkali - yellow
What colour is blue lit as paper in an acid and an alkali?
Acid - turns red
Alkali - stays blue
What colour is red litmus paper in an acid and an alkali?
Acid - stays red
Alkali - turns blue
Suggest a problem with using universal indicator to test the pH of a solution
It is quite subjecting
It won’t provide an exact value
What is the concentration of hydrogen ions like in a strong acid?
High
What is the concentration of hydroxide ions in strong alkali?
High
If pH decreases by one unit, what happens to the concentration hydrogen ions?
The hydrogen ion concentration increases by a factor of 10
What is a neutralisation reaction?
A reaction between an acid and a base
What is the ionic equation for a neutralisation reaction?
H + Oh -> H2O
What do the terms concentrated and dilute mean when talking about acid?
Concentrated acids have more moles of acid per unit volume of water than dilute acids
An acid only partially dissociates in what er p, what can be said about the strength of the acid?
It is a weak acid
What is a base?
Any substance that react with an acid to form salt and water only
Are alkalis insoluble bases?
No, they are soluble
What are the products when an acid reacts with a metal?
Salt and hydrogen
What are the products when an acid reacts with a metal oxide?
Salt and water
What are the products when an acid reacts with a metal hydroxide?
Salt and water
What are the products when an acid reacts with a metal carbonate?
Salt, water and carbon dioxide
Why are metal oxides normally bases rather than alkalis?
They are normally insoluble
Alkalis are soluble
What is the name of the salt formed from magnesium and sulphuric acid?
Magnesium sulphate
What is the name of the salt formed from zinc and nitric acid?
Zinc nitrate
What is the name of the salt formed from calcium carbonate and hydrochloric acid?
Calcium chloride
Describe the chemical test for hydrogen
Insert a lit splint into a test tube of gas
A ‘squeaky pop’ will be heard if hydrogen is present
Describe the chemical test for carbon dioxide
Bubble the gas through limewater
Limewater turns cloudy is carbon dioxide is present
When a soluble salt is prepared from an acid and an insoluble reactant, why is excess of the insoluble reactant added?
To ensure all the acid reacts
When a soluble salt is prepared from an acid and an insoluble reactant, how and why is excess reactant removed?
By filtration
What method must be used to prepare a salt from an acid and a soluble reactant?
Titration
Name the method that could be used to prepare a sample of soluble copper sulphate from insoluble copper oxide and sulphuric acid?
Filtration
What 3 steps are required when producing a pure dry salt from an acid and alkali?
Complete a titrations. To find the volume of acid that reacts exactly with a set volume of alkali
Use the results from the titration to mix the acid and alkali in the correct proportions
Evaporate the water from the solution, leaving pure dry salt crystals
Most common chlorides are soluble. What are the two exceptions?
Silver chloride and lead chloride
Are all nitrates soluble?
Yes
Are all common sodium, potassium and ammonium salts soluble?
Yes
Most common sulphate are soluble. What are the three exceptions?
Lead sulphate, calcium sulphate and barium sulphate
Most common carbonates and hydroxides are insoluble. What are the three exceptions?
The carbonate/ hydroxides of sodium and ammonium
What salt is produced when lead reacts with sulphuric acid?
Lead sulphate
How could you prepare a pure, dry sample of an insoluble salt?
Mix the two solutions required to form the salt
Filter the mixture using filter paper
The residue of the filter paper is the insoluble salt
Wash the salt with distilled water and leave to dry
What is an electrolyte?
An ionic compound in its molten or aqueous state
Why can an electrolyte carry charge?
An ionic compound in its molten or aqueous state has Mobil earth ions which can carry charge
What is electrolysis?
A process which used electrical energy to decompose electrolytes
What is the cathode and anode?
Cathode - negative electrode
Anode - positive electrode
Where do charged ions in the electrolyte move to during electrolysis?
Cations move towards the cathode
Anions move towards the anode
What happens at the anode during electrolysis?
The anions lose electrons to form their elements
What happens at the cathode during electrolysis?
Cations gain electrons to form their elements
Name the processes that occur at each electrode during electrolysis
Anode - oxidation
Cathode - reduction
What is formed at each electrode in electrolysis?
Anode : non-metal
Negative : metal or hydrogen
How can you predict whether a metal or hydrogen will form at the negative electrode?
If hydrogen is above the metal in the reactivity series then the metal will form
If the metal is more reactive than hydrogen then hydrogen will form
What is formed at each electrode during the electrolysis of copper chloride solution?
Anode: chlorine
Cathode: copper
What is formed at each electrode during the electrolysis of sodium sulphate solution?
Anode: oxygen
Cathode: Hydrogen
What is formed at each electrode during the electrolysis of molten lead bromide?
Anode: bromine
Cathode: hydrogen
What will be formed at each electrode during the electrolysis of molten zinc chloride?
Anode: chlorine
Cathode: zinc
What is formed at each electrode during the electrolysis of sodium chloride solution?
Anode: chlorine
cathode: hydrogen
What I’d formed at each electrode during the electrolysis of water acidified with sulphuric acid?
Anode: oxygen
Cathode: Hydrogen
What are the half equations for the reactions occurring at the cathode and anode during the electrolysis of copper chloride?
Anode: 2Cl- -> Cl2 + 2e-
Cathode: Cu2+ + 2e- -> Cu
What does education mean in terms of electrons?
Loss of electrons
What does reduction mean in terms of electrons?
Gain of electrons
How can electrolysis of copper sulphate be used to purify copper?
Place 2 copper electrodes into copper sulphate solution
The anode should be impure copper and cathode should be pure
Connect to a power supple
The copper in the impure is pulled towards the cathode to form pure copper
Impurities form as sludge below the anode
Cu2+ ions from copper sulphate remain in solution