Topic 2: Atomic Structure Flashcards

1
Q

what is an element?

A

a substance that cannot be broken down into simpler substances by a chemical reaction

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2
Q

Daltons Model of an Atom

A
  • all matter is composed of atoms
  • atoms cannot be created or destroyed
  • atoms of the same element are alike
  • atoms of different elements are different
  • atoms combine to form molecules
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3
Q

what is a compound?

A

a substance made by chemically combining two or more elements. It has different properties than its constituent elements

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4
Q

Rutherford’s model of an Atom

A
  • fired alpha particles at a piece of gold foil; some bounced back
    = atoms are mainly empty space and contain a positive nucleus
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5
Q

Proton

A

+1, in nucleus

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6
Q

Electron

A

-1, outside of nucleus (space outside)

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7
Q

Neutron

A

0, in nucleus

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8
Q

Mass Number (Ar)

A

number of protons plus number of neutrons in an atom

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9
Q

Isotopes

A

atoms of the same element with different mass numbers due to number of neutrons it contains (same electrons and protons however)

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10
Q

Relative average mass formula

A

total mass/number of atoms

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11
Q

positive ion

A

when an element loses an electron (cation)

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12
Q

negative ion

A

when an element gains an electron

anion

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13
Q

Relative Atomic Mass

A

weight mean of all naturally occuring isotopes of an element relative to carbon-12

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14
Q

decreasing wave frequencies/energy

A
Y-Rays
X-Rays
UV Radiation
Visible light
R Radiation 
Microwaves
Radio waves
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15
Q

Continious spectrum

A

contains radiation of all wavelengths within a given range

e.g. visible light

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16
Q

Line spectrum

A

discrete lines of different wavelengths and frequencies

e.g. emmision or absorbtion spectra

17
Q

Explain emmision spectrum of hydrogen atom

A

• The emission spectrum of hydrogen atom consists of different series of lines in different regions of the
electromagnetic spectrum.
• The lines in an emission spectrum are produced by excited electrons falling from higher to lower energy
levels: ΔEatom = hν = hc/λ.
• As the energy levels of the hydrogen atom converge at higher energy as they are further from the nucleus,
the lines in the spectrum also converge at higher energy/frequency.

  • 2–>1 is the UV series
  • anything to 2 is the visible light series (palmer)
18
Q

Formula/relation between frequency and wavelength

A

• Frequency (ν) and wavelength (λ) are related by: c (speed of light) = ν λ.
• The energy of a photon (Ephoton) is related to the frequency (ν) of the radiation by Planck’s equation:
Ephoton = hν (the equation is given in section 1 of the IB data booklet)
h is Planck’s constant (see section 2 of the IB data booklet)

19
Q

frequency

A

the number of waves that pass a certain point

20
Q

IR Radiation

A
  • long wavelength; short frequency; low energy
21
Q

UV radiation

A
  • short wavelength, high frequency, high energy
22
Q

how is a line spectrum produced

A

when white light is passed through hydrogen gas

23
Q

how is an emmision spectra produced

A

by providing hydrogen gas with high voltage

24
Q

first ionization energy

A

minimum energy needed to remove one mole of electrons from one mole of gaseous atoms in their ground state

25
Q

main energy levels of an atom and their energies?

A
  • higher energy states= exicted electrons
  • falling to ground state from high energy level has high energy

N= 1 (ground state)
N=2
N=3
N= infinity

26
Q

how are lines the emission spectra produced

A

The lines in an emission spectrum are produced by excited electrons falling from higher to lower energy
levels: ΔEatom = hν = hc/λ.

27
Q

Heisenbergs Uncertainty principle

A
  • We cannot know where an electron of an atom is at a given time, so we use ‘probable diagrams’
28
Q

Shrodigers model of the hydrogen atom

A
  • atomic orbitals

- wave equation describes properties/behaviour of an electron

29
Q

atomic orbital

A
  • region around nucleus where there is a 90% probably of finding an electron
  • different levels
  • higher energy; more likely to find an electron further way from nucleus
30
Q

Orbitals

A

Orbitals are regions in space in which an electron
may be found in an atom. Each orbital can hold two
electrons of opposite spin.

31
Q

orbital shapes

A
s orbitals are spherical and 
p orbitals are dumb-bell shaped. 
There
are three p orbitals orientated along the x, y and z
axis.
32
Q

Pauli exclusion principle

A

states that only electrons with opposite spin can occupy the same orbital.

33
Q

Orbital diagrams

A
  • used to describe the number of electrons in each orbital.
  • Each orbital is represented by a box and each electron by a single-headed arrow which represents the direction of its spin.
34
Q

energy levels

A

Each main energy level can hold a maximum of 2n^2
electrons.
• Each main energy level contains n sub-levels and n2
orbitals.

35
Q

Aufbau principle

A

states that orbitals with lower energy are filled before

those with higher energy.

36
Q

aufbau order

A

1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4f, 5d, 6p, 7s …