Topic 2: Atmospheric Water Flashcards
Controls on Evaporation
- Needs energy to break bonds (Scales with available radiative and sensible heat)
- Need humidity gradient to drive moisture flux from high to low (Scales with change in q, i.e. qs-qa)
- Need a way to remove moisture so the air above the surface does not get saturated (Scales with wind speed, v)
Shortwave radiation
- Incoming solar radiaton
- Some sensible heat, breaks bonds
Longwave radiation
- Absorbed at surface
- Re-radiated back
Net Radiation at the surface
Q*=Qs(in) -Qs(out) + Ql(in)-Ql(out)
Qe
- Latent Heat
- Energy transfer involved in phase changes
- Consumed during evaporation
- Released during condensation
Albedo (alpha) estimate
Q=Qs(in)(1-alpha) + Ql(in)-Ql(out)
Terrestrial Budget
- Energy from the sun that is not scattered or absorbed by the atmosphere
- Absorbed by Earth & Re-radiated as long wave radiation
Albedo
Reflective quality of a surface (clouds, cloud type, surface). Dictates amount of energy absorbed by Earth overall.
Qh
- Sensible Heat
- Energy (heat) flows from warm to cold
- via conduction (molecular transfer)
- via advection/convection (movement of the medium, e.g. water)
Advection/convection
Movement of the medium
e.g. water
Conduction
molecular transfer
Qg
- Heat exchange w/ substrate (ground)
- Sometimes not included in surface energy balance
Surface Energy Balance
Net Energy Qn
Qn=Q*+Qh+Qe+Qg=0
Controls on Evaporation
- Temperature
- Energy
- Wind (circulation)
- How much water is on the ground available to be evaporated
- Need a humidity (vapour pressure) gradient to drive moisture flux from high to low (Scales with change in q i.e. qs-qa)
Modelling evaporation/sublimation
From water/snow/ice): Evaporation Rate (E)= Qe (Latent Heat)/ Density of water *Lv(latent heat of evaporation
- Equation still holds for soils/sediments/vegetation but rates are limited by the available water (hence, potential evaporation)
When are Evaporation rates high?
- Evap rates are high when there is lots of available energy (Q*,Qh)
- When the atmosphere is dry
- and when it is windy
Methods to measure both evaporation & transpiration
- Evaporation pan (change in water height daily)
- Lysimeter (Change in weight of a soil or snow sample)
- Water Balance Equation
- Energy Balance (theoretical calculation)
- Hydrological model (e.g. Penman-Monteith)
Evaporation Pan
- Method for measuring evapotranspiration
- start daily with full pan
- refill using graduated cylinder to record how much is filled back in during the day
- Provides evap rate if water is available but isn’t representative of what is happening b/c standing water/soil water may not be available for evaporation at the time in reality
Lysimeter
- Method to measure evapotranspiration
- Add rain or actively add water
- let it percolate
- collect percolated water
Water Balance Equation
Evapotranspiration = Qin - Qout
- basically water in - water out
- works well for a small controlled basin
- Can determine losses (animals, plants, groundwater)
- May need to know about storage & precipitation
- Evapotranspiration then = Qin - Qout +Precip + Change in Storage
- Groundwater can create water balance with more out than in
Hydrological Model
The concept of potential evapotranspiration (Theoretical calculation)
- Penman-Monteith is common equation
Means of describing Humidity (with units)
- Vapour pressure, ev (Pa or mbar)
- Mixing ratio, wv (g water vapour/kg air)
- Specific humidity, qv (g water vapour/kg air)
- Absolute humidity rho v (g water vapour/m^3)
- Relative humidity, RH (%)
Vapour Pressure
- Partial pressure contribution of water to the total atmospheric pressure
- Measured in Pa or mbar
- Measures effect of water molecules in atmosphere
Relative Humidity
- How close an air parcel is to saturation
- Measured with a %
- % = Actual (ev, vapour pressure)/ Potential (es, saturation)
- Not the best method
Why is Relative Humidity not the best method for reporting/measuring humidity?
- % is based on the capacity of the atmosphere to hold water vapour
- But, cooler air has less capacity to hold water than warmer air (Potential for saturation is different)
- Therefore, same amount of water vapour in the tropics would be less RH than that amount in the Arctic
- % at one location has different volume than another location
At what temperature does vapour pressure double?
Every 11 degrees celsius vapour pressure will double
Dalton’s Law
Total pressure of a mixture of gases = sum of pressure constituents
- vapour pressure is the pressure exerted by water vapour that contributes to this Law
What is the standard atmospheric pressure exerted by air?
101.325 kPa or 1013.25mb or 1 atm (Not 101.335 KPa like it was on the class notes)
Actual Vapour Pressure
Pressure resulting from the water molecules
Saturation Vapour Pressure
Partial pressure of the water molecules when the air is saturated