Topic 1 - Year 1 - Biological Molecules - Carbohydrates Flashcards

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1
Q

Which type of reaction joins biological monomers in order to create biological polymers?

A

Condensation reactions join monomers to create biological polymers which are larger more complex molecules. In the condensation reaction two things happen

  1. A chemical bond is made
  2. A water molecule is produced
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2
Q

Which type of reaction breaks biological polymers down into their biological monomers?

A

Biological polymers are usually broken down by hydrolysis reactions , hydrolysis use molecules of water to break chemical bonds.

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3
Q

What does the term ‘sugars’ refer to?

A

The term sugars refer to monosaccharides and disaccharides.

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4
Q

Which elements do carbohydrates contain?

A

Hydrogen
Carbon
Oxygen

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5
Q

Name 3 Monosaccharides

A

Glucose
Fructose
Galactose

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6
Q

There are two different isomers of glucose what are the names of these two isomers?

A

Alpha Glucose

Beta Glucose

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7
Q

Explain the orientation of the H and OH groups on the first carbon in the hexose sugars Alpha Glucose and Beta Glucose

A

Alpha Glucose – the H group is ontop and the OH group is on the bottom

Beta Glucose – the OH group is ontop and the OH group is on the bottom

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8
Q

What is a Monosaccharide?

A

A monosaccaride is a monomer for a polysaccharide which is a carbohydrate hence a monosaccharide is a monomer of carbohydrate

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9
Q

What is created when two monosaccharides are joined in a condensation reaction?

A

A disacchaaride

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10
Q

If a disaccharide is hydrolysed what happens?

A

The chemical bond that holds the disaccharide together is broken by a water molecules and the disaccharide becomes two separate monosaccharides

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11
Q

Which disaccharide is produced when two monosaccharides of glucose join in a condensation reaction?

A

Maltose

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12
Q

Which disaccharide is formed if monosaccharides glucose and fructose join by condensation reaction?

A

Sucrose

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13
Q

Which disaccharide is formed if monosaccharides glucose and galactose join by condensation reaction?

A

Lactose

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14
Q

What is a reducing sugar ?

A

A reducing sugar is a sugar that readily looses electrons to another substance. reducing sugars reduce other substances by giving them electrons (reduction is gain)

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15
Q

How do you test for a reducing sugar ?

A

To test for a reducing sugar you use the Benedict’s test, Benedicts test is conducted by:

1) first the sample being tested must be put into solution
2) Benedicts reagent is then added in an excess to the solution an excess is added so that all the sugar reacts
3) the sample is then placed in a water bath and boiled
4) a positive test result will show a colour change and a precipitate will form
5) the Benedicts test has a semi-quatative nature the closer the colour change to brick red the more reducing sugar that was found in the sample , colour changes from blue to something like green may suggest only small amounts of reducing sugar were present.

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16
Q

How do you test for non-reducing sugar ?

A

To test for non-reducing sugars you must also use the Benedictus test however you must complete some additional steps:

1) first the sample being tested must be put into solution
2) too this solution hydrochloric acid must be added , the solution containing the sample must be heated with this hydrochloric acid in a water bath
3) this mixture must then be mixed with sodium hydrogen carbonate to neutralise the acid.
4) Benedicts reagent is then added in an excess to the solution an excess is added so that all the sugar reacts
5) the sample is then placed in a water bath and boiled
6) a positive test result will show a colour change and a precipitate will form
7) the Benedicts test has a semi-quatative nature the closer the colour change to brick red the more reducing sugar that was found in the sample , colour changes from blue to something like green may suggest only small amounts of reducing sugar were present.

17
Q

What is a Polysaccharide?

A

A polysaccharide is a large chain of monosaccharides that are held together by glycosidic bonds which form in condensation reactions. Polysaccharides are carbohydrates.

18
Q

Name 3 polysaccharides

A

Starch
Cellulose
Glycogen

19
Q

What is the monomer of Starch

A

alpha glucose

20
Q

Explain the structure of Starch

A

Starch is a polysaccharide , the monosaccharide that builds the polymer is alpha glucose (glucose with the h on the first carbon in the ring orientated on top) . the monomers are organised in two ways , straight chains and branches , to form the straight chains (amylose) alpha glucose molecules form 1,4 glycosidic bonds. As starch has a branched structure branches must also be formed (amylopectin) , these branches are created when when alpha glucose molecules for 1,6 glycosidic bonds. Starch has a coiled structure hence is a great storage molecule as it is compact so can store a lot of energy in a small space. The branched nature of starch also means its easily hydrolysed.

21
Q

Explain the purpose of Starch

A

starch is a storage molecule in plants , plants get energy from glucose and store their excess glucose as starch and then hydrolyse this starch if at a later point they require energy.

22
Q

Where is the polysaccharide starch found?

A

Plants

23
Q

Starch is insoluble in water , why is this important?

A

starch is insoluble in water hence it docent affect the water potential of cells. this means that water doesn’t move into the cell by osmosis and cause them to swell. the insolubility of starch is therefore a good thing as it makes it an ideal storage molecule.

24
Q

What is the monomer of glycogen?

A

Alpha glucose

25
Q

Explain the structure of Glycogen

A

The monomer of glycogen is alpha glucose , the chains of alpha glucose which are bonded by glycosidic bonds are branched they are more branched than you would find in starch . as the chains are branched you find both 1,4 and 1,6 glycosidic bonds. As glycogen is heavily branched it can be quickly hydrolysed meaning energy in the form of glucose can be taken from it quickly.

26
Q

Explain the function of Glycogen

A

Glycogen is a storage molecule it is found in animal cells , animals store their excess glucose as glycogen.

27
Q

Where is Glycogen found?

A

glycogen is found in animals , primarily in the muscles and the liver.

28
Q

Glycogen is insoluble why is this important?

A

Glycogen is insoluble hence it does not change the water potential in cells this is important as it means water does not enter the cell and cause it to become hemolysed as this could cause death . Therefore the insolubility of glycogen allow it to be an ideal storage molecule

29
Q

Where is the polysaccharide cellulose found?

A

Cellulose is found in plant cell walls.

30
Q

Explain the structure of cellulose

A

Cellulose is made up by monomers of beta glucose. The monosaccharides of beta glucose are joined in 1,4 glycosidic bonds. In order to align the 1 and 4 groups on the beta glucose molecules the monosaccharide must continually alienate in orientation. there are no 1,6 glycosidic bonds in cellulose as the polysaccharide is made up of LONG STRAIGHT CHAINS of beta glucose. These many long straight chains are linked together by hydrogen bonds to form strong fibres called microfibrils. These strong fibres create a cross hatch structure by weaving together p ultimately providing structural support in the cell wall.

31
Q

Explain the function of Cellulose

A

cellulose keeps plant walls stable and keeps them intact by preventing them from bursting

32
Q

How would you test for starch?

A

Firstly you would put your sample in solution , you would then add iodine to this solution , if there is starch present there will be a colour change from brown-yellow too blue-black.