Topic 1 - Key Concepts In Chemistry Flashcards
What are the 3 ideas in John Daltons theory about the atom?
- Atoms cannot be created, divided or destroyed
- Atoms of same element are exactly the same/atoms of different elements are different
- Atoms join with other atoms to make new substances
What discovery caused the original Dalton model of an atom to change?
Discovery of subatomic particles
Describe structure of atom
Small central nucleus made up of protons and neutrons
Electrons orbit the nucleus in shells
Whats the radius of nucleus? How large is it compared to radius atom?
Radius of nucleus is 1x10⁻¹⁴m
This is 1/10,000 of atomic radius
What are the relative masses of protons, neutrons and electrons?
Proton 1
Neutron 1
Electron 1/1836
What are the relative charges of protons, neutrons and electrons?
Proton +1
Neutron 0
Electron -1
Why do atoms contain equal numbers of protons and electrons
Atoms are stable with no overall charge
Protons are postively charges and electrons are negatively charged. For charges to balance, no of protons and electrons must be equal.
Where is the mass of an atom concentrated
In nucleus
What does atomic number of an atom represent
Number of protons
What does mass number of an atom mean
Mass number is number of protons and neutrons found in nucleus of atom
Atoms of same element have same number of ________ in nucleus and this is unique to that element
Protons
Whats an isotope
Isotopes are atoms with same number of protons but different number of neutrons.
Isotopes of an element have the same atomic number but different mass numbers.
Boron has atomic number 5 and mass number 11. How many protons, neutrons and electrons does Boron have?
5 protons
5 electrons
6 neutrons
Why is relative atomic mass not always a whole number
Different isotopes of same element have different mass numbers. Relative atomic mass is an average of the masses of all these isotopes.
What 2 values would be requires to calculate the relative atomic mass of chlorine?
Mass numbers and relative abundances of all the isotopes of chlorine
How did Mendeleev arrange the elements in his periodic table?
- Elements arranged with increasing atomic masses
- Elements with similar properties put into groups
- Switched position of some elements
- Gaps left for undiscovered elements
How was Mendeleev able to predict the properties of new elements?
He left gaps in his periodic table
Used properties of elements next to gaps to predict properties of undiscovered elements
Mendeleev’s table lacked some amount of accuracy in the way he ordered his elements. Why was this?
Isotopes were poorly understood at the time
Protons and neutrons had not yet been discovered
How are elements arranged in the modern periodic table?
In order of increasing atomic number
Elements in the same group (column) have similar _______ ________
Chemical properties
Why do elements in the same column have similar chemical properties?
Same no of outer shell electrons
No of outer shell electrons determines how atom reacts
What does the period (row) number tell you about all the elements in that period?
Elements in the same period have the same number of electron shells
What does group (column) number tell you about all the elements in that group
All elements in same group have same number of outer shell electrons
On which side pf periodic table are metals positioned?
Left side
What determines whether an element is a metal or non metal?
Atomic structure of the elements
Whats the max number pf electrons allowed in each of first three shells
1st shell - 2
2nd + 3rd shell - 8
When are atoms most stable
When they have full electron shells
The atomic number of Na is 11.
Whats the electronic configuration of Na?
2, 8, 1
How is electron configuration of an element related to its position in the periodic table?
Diagram: no of rings is period, no of electrons in outer ring is group, total no of electrons is atomic number
Number: (eg sodium 2.8.1) sodium has three shells as there are 3 numbers, last number is no of outer shell electrons/group, sum of digits is atomic number
Whats an ionic bond?
A bond between a metal and non metal involving transfer of electrons
In terms of electrons, describe what happens to the metal and non metal when an ionic bond forms
Metal atom loses electrons to become a positively charged ion (cation)
Non metal gains electrons to become a negatively charged ion (anion)
Whats an ion
An ion is an atom or group of atoms with a positive or negative charge
If an ion is positively charged, has it lost of gained electrons?
Lost. There are fewer negatively charged electrons to cancel out the charge of the positive protons so overall charge becomes positive.
Na⁺ has atomic no 11 and mass no 23. How many protons, neutrons and electrons are in this ion?
11 protons
10 electrons
12 neutrons
O²⁻ has atomic no 8 and mass no 16. How many protons, neutrons and electrons are in this ion?
8 protons
10 electrons
8 neutrons
Why do elements in groups 1,2,6 and 7 readily form ions?
So they become more stable and achieve the electron structure of the noble gases (group 8)