Topic 1 - Key Concepts In Chemistry Flashcards

1
Q

What are the 3 ideas in John Daltons theory about the atom?

A
  1. Atoms cannot be created, divided or destroyed
  2. Atoms of same element are exactly the same/atoms of different elements are different
  3. Atoms join with other atoms to make new substances
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2
Q

What discovery caused the original Dalton model of an atom to change?

A

Discovery of subatomic particles

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3
Q

Describe structure of atom

A

Small central nucleus made up of protons and neutrons

Electrons orbit the nucleus in shells

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4
Q

Whats the radius of nucleus? How large is it compared to radius atom?

A

Radius of nucleus is 1x10⁻¹⁴m

This is 1/10,000 of atomic radius

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5
Q

What are the relative masses of protons, neutrons and electrons?

A

Proton 1
Neutron 1
Electron 1/1836

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6
Q

What are the relative charges of protons, neutrons and electrons?

A

Proton +1
Neutron 0
Electron -1

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7
Q

Why do atoms contain equal numbers of protons and electrons

A

Atoms are stable with no overall charge
Protons are postively charges and electrons are negatively charged. For charges to balance, no of protons and electrons must be equal.

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8
Q

Where is the mass of an atom concentrated

A

In nucleus

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9
Q

What does atomic number of an atom represent

A

Number of protons

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10
Q

What does mass number of an atom mean

A

Mass number is number of protons and neutrons found in nucleus of atom

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11
Q

Atoms of same element have same number of ________ in nucleus and this is unique to that element

A

Protons

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12
Q

Whats an isotope

A

Isotopes are atoms with same number of protons but different number of neutrons.
Isotopes of an element have the same atomic number but different mass numbers.

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13
Q

Boron has atomic number 5 and mass number 11. How many protons, neutrons and electrons does Boron have?

A

5 protons
5 electrons
6 neutrons

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14
Q

Why is relative atomic mass not always a whole number

A

Different isotopes of same element have different mass numbers. Relative atomic mass is an average of the masses of all these isotopes.

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15
Q

What 2 values would be requires to calculate the relative atomic mass of chlorine?

A

Mass numbers and relative abundances of all the isotopes of chlorine

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16
Q

How did Mendeleev arrange the elements in his periodic table?

A
  • Elements arranged with increasing atomic masses
  • Elements with similar properties put into groups
  • Switched position of some elements
  • Gaps left for undiscovered elements
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17
Q

How was Mendeleev able to predict the properties of new elements?

A

He left gaps in his periodic table

Used properties of elements next to gaps to predict properties of undiscovered elements

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18
Q

Mendeleev’s table lacked some amount of accuracy in the way he ordered his elements. Why was this?

A

Isotopes were poorly understood at the time

Protons and neutrons had not yet been discovered

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19
Q

How are elements arranged in the modern periodic table?

A

In order of increasing atomic number

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20
Q

Elements in the same group (column) have similar _______ ________

A

Chemical properties

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21
Q

Why do elements in the same column have similar chemical properties?

A

Same no of outer shell electrons

No of outer shell electrons determines how atom reacts

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22
Q

What does the period (row) number tell you about all the elements in that period?

A

Elements in the same period have the same number of electron shells

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23
Q

What does group (column) number tell you about all the elements in that group

A

All elements in same group have same number of outer shell electrons

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24
Q

On which side pf periodic table are metals positioned?

A

Left side

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25
Q

What determines whether an element is a metal or non metal?

A

Atomic structure of the elements

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26
Q

Whats the max number pf electrons allowed in each of first three shells

A

1st shell - 2

2nd + 3rd shell - 8

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27
Q

When are atoms most stable

A

When they have full electron shells

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28
Q

The atomic number of Na is 11.

Whats the electronic configuration of Na?

A

2, 8, 1

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29
Q

How is electron configuration of an element related to its position in the periodic table?

A

Diagram: no of rings is period, no of electrons in outer ring is group, total no of electrons is atomic number
Number: (eg sodium 2.8.1) sodium has three shells as there are 3 numbers, last number is no of outer shell electrons/group, sum of digits is atomic number

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30
Q

Whats an ionic bond?

A

A bond between a metal and non metal involving transfer of electrons

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31
Q

In terms of electrons, describe what happens to the metal and non metal when an ionic bond forms

A

Metal atom loses electrons to become a positively charged ion (cation)
Non metal gains electrons to become a negatively charged ion (anion)

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32
Q

Whats an ion

A

An ion is an atom or group of atoms with a positive or negative charge

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33
Q

If an ion is positively charged, has it lost of gained electrons?

A

Lost. There are fewer negatively charged electrons to cancel out the charge of the positive protons so overall charge becomes positive.

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34
Q

Na⁺ has atomic no 11 and mass no 23. How many protons, neutrons and electrons are in this ion?

A

11 protons
10 electrons
12 neutrons

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35
Q

O²⁻ has atomic no 8 and mass no 16. How many protons, neutrons and electrons are in this ion?

A

8 protons
10 electrons
8 neutrons

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36
Q

Why do elements in groups 1,2,6 and 7 readily form ions?

A

So they become more stable and achieve the electron structure of the noble gases (group 8)

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37
Q

What type of ions do elements in group 1 and 2 form?

A

Cations (positive)
Group 1 metals form 1+ ions
Group 2 metals form 2+ ions

38
Q

What type of ions do elements from groups 6 and 7 form?

A

Non metals so form anions (negative)
Group 6 forms 2- ions
Group 7 forms 1- ions

39
Q

What does it mean if an ionic compound ends in -ide?

A

Compound contains 2 elements

40
Q

What does it mean if an ionic compound ends in -ate?

A

The compound contains at least 3 elements, one of which is oxygen

41
Q

Describe the structure of an ionic compound

A

Lattice structure
Regular arrangement of ions
Ions held together by strong electrostatic forces between ions with opposite charges

42
Q

Whats the chemical formula of sodium oxide, formed from Na⁺ and O²⁻ ?

A

Na₂O

Charges must balance so 2 sodium ions are required

43
Q

Whats the chemical formula of magnesium hydroxide, formed from Mg²⁺ and OH⁻ ?

A

Mg(OH)₂

Charges must balance so 2 hydroxide ions are required

44
Q

What is a covalent bond?

A

A bond formed when an electron pair is shared between 2 atoms

45
Q

What forms as a result of covalent bonding?

A

A molecule

46
Q

True or false? ‘Covalent bonds are weak’

A

FALSE

Covalent bonds are strong

47
Q

Which is smaller, an atom or a molecule?

A

An atom

Simple molecules consist of atoms joined by strong covalent bonds within the molecule

48
Q

Why do ionic compounds have high melting points?

A

Strong electrostatic attraction between the positive and negative ions requires a lot of energy to overcome

49
Q

When do ionic compounds conduct electricity? Why?

A

When molten or aqueous (dissolved in water) because the ions are charged and free to move. When solid, the ions are fixed in an ionic lattice so cant move.

50
Q

Why do simple molecular compounds have low melting and boiling points?

A

They have weak intermolecular forces (forces between molecules) which only require a little energy to overcome

51
Q

Do simple molecular compounds conduct electricity? Why? Why not?

A

No because there are no charged particles

52
Q

Do giant covalent structures have a high melting point? Explain your answer.

A

Yes because they have lots of strong covalent bonds which require a lot of energy to break

53
Q

How do metals conduct electricity and heat

A

The positive ions are fixed in a sea of delocalised electrons. These electrons are free to move and carry charge/energy.

54
Q

True or false? ‘Metals are insoluble in water’

A

TRUE

55
Q

Name two giant covalent structures formed from carbon atoms

A

Diamond

Graphite

56
Q

Describe the structure of graphite

A
  • Each carbon atom bonded to 3 other carbon atoms
  • Layers of hexagonal rings of carbon atoms
  • Weak intermolecular forces between layers
  • One delocalised electron per carbon atom
57
Q

Describe and explain the properties of graphite

A

Soft/slippery because of weak intermolecular forces between layers - allow to slide over each other
Conducts electricity because theres one delocalised electron per carbon atom. These electrons are mobile charges

58
Q

Describe structure of diamond

A

All carbon atoms are covalently bonded to 4 other carbon atoms
No delocalised electrons

59
Q

Describe properties of diamond

A

Very hard
Very high melting pt
Doesnt conduct electricity as are no charged particles

60
Q

What are the uses of graphite? Why?

A

Electrodes because graphite conducts electricity and has high melting pt
Lubricant because its slippery

61
Q

Why is diamond used in cutting tools

A

Very hard

62
Q

Whats a fullerene?

A

A molecule made of carbon, shaped like a closed tube or hollow ball

63
Q

Name 2 fullerenes

A

Graphene

C₆₀ (buckminsterfullerene)

64
Q

What are the properties of the fullerene C₆₀ ?

A

Slippery due to weak intermolecular forces
Low melting pt
Spherical
Strong covalent bonds between carbon atoms in a molecule
Large surface area

65
Q

What are the properties of graphene?

A

High melting pt due to covalent bonding between carbon atoms

Conducts electricity because it has delocalised electrons

66
Q

Why is graphene useful in electronics

A

Is extremely strong and has delocalised electrons - are free to move and carry charge
One one atom thick as it is a single layer of graphite

67
Q

What is a polymer? Name one

A

Long chain molecules formed from many monomers

Polyethene

68
Q

What bond is formed between carbon atoms in polymer molecules?

A

Covalent bonds

69
Q

What are the properties of metals?

A
High melting pt
High density
Good conductors of electricity
Malleable and ductile
Generally shiny
70
Q

Explain why metals are malleable

A

Atoms are arranged in uniform rows which can slide over one another

71
Q

Explain why metals can conduct electricity

A

Electrons in metal are charges that can move

72
Q

What are the properties of non metals

A

Low boiling pt
Poor conductors of electricity
Brittle when solid

73
Q

List the limitations of the following models when representing ionic compounds: dot and cross, 2D and 3D diagrams

A

Dot and cross- no lattice structure or ionic bonds
2D- only shows one layer, doesnt show formation of ions
3D- shows spaces between ions, doesnt show charges

74
Q

List the limitations of the following models when representing covalent molecules: dot and cross and ball and stick

A

Dot and cross- doesnt show relative sizes of atoms or intermolecular forces
Ball and stick- bonds shown as sticks rather than forces, doesnt show how covalent bonds form

75
Q

How do you calculate the relative formula mass of a compound?

A

Add together all the relative atomic masses of the atoms in the compound

76
Q

Whats the empirical formula? What 2 values could be used to calculate the empirical formula of a simple compound?

A

The smallest whole number ratio of the atoms of each element in a compound
Reacting masses or percentage composition can be used to calculate the empirical formula

77
Q

Whats the empirical formula for Fe₂O₄ ?

A

FeO₂

78
Q

Whats the molecular formula?

A

Actual number of atoms of each element in a compound

79
Q

Describe an experiment to work out the empirical formula of magnesium oxide

A
  • weigh sample of magnesium
  • heat sample in crucible
  • weigh mass of magnesium oxide at end
  • calculate mass of oxygen
  • calculate moles of magnesium and oxygen using the experimental mass and relative atomic mass
  • work out whole number ratio to number of moles of magnesium to oxygen
80
Q

What is the law of conservation of mass

A

No matter is lost or gained during a chemical reaction

81
Q

If a reaction is carried out in a closed system, what can you say about the total mass od the reaction throughout the experiment?

A

Mass stays constant

82
Q

If a reaction is carried out in an open flask and a gas is produced, what can you say about the total mass of the reaction throughout the experiment?

A

Mass decreases as gas escapes

83
Q

52g of calcium reacts with oxygen to form 79g of calcium oxide. Using the law of conservation of mass, what mass of oxygen is needed?

A

79-52=27

Mass of oxygen = 27g

84
Q

What equation links mass, moles and relative atomic mass?

A

Mass (g) = moles x relative atomic mass (Mr)

85
Q

How can you calculate concentration in g/dm³ ?

A

Concentration (g/dm³) = mass (g) / volume (dm³)

86
Q

What is the avogadro constant?

A

Number of atoms, molecules or ions in one mole of a given substance
Value of constant is 6.02 x 10²³

87
Q

Whats the mass of 20 moles of calcium carbonate, CaCO₃

A

Mass (g) = moles x relative atomic mass (Mr)
Mr = 100
20 x 100 = 2000g

88
Q

What formula links the avogadro constant, moles and no of particles?

A

No of particles = avogadro constant x moles

89
Q

How many atoms are in 3 moles of copper?

A

No of atoms = avogadro constant x moles

  1. 02 x 10²³ x 3
  2. 81 x 10²⁴
90
Q

Whats a limiting reagent in a chemical reaction?

A

The chemical thats used up first in a reaction, preventing the formation of more product.
Typically, an excess of one of reactants is used to ensure that the other reactant is completely used up.