Things to remember for chem Flashcards

1
Q

Carbohydrate definition

A

Polymers of simple sugars. The functional group features of carbohydrates/sugars are polyhydroxyaldehydes or polyhydroxyketones or compounds formed by linking up polyhydroxyaldheydes or
polyhydroxyketones i.e., carbohydrates are polymers of simple sugars.

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2
Q

Blood sugar

A

D-Glucose , aldohexose

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3
Q

D or L

A

For any carbohydrate, the D or L designation is based on the configuration of the chiral carbon farthest from the carbonyl group. D-sugars have a hydroxyl group at the bottom most chiral carbon, on the right when the molecule is drawn in the Fischer Projection if the -OH is on the left, then it is an L-sugar

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4
Q

epimers

A

diastereoisomers that differ at only
one stereogenic centre

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5
Q

Simple classification of amino acids

A

Amino acids can be classified very simply into 3 groups - neutral, acidic, basic,
depending on the acidity or basicity of the side chain. Learn this classification. Neutral amino acids have no acidic nor basic functionality in the R side-chain.
Acidic amino acids have an additional carboxylic acid function in the R side-chain
Basic amino acids have a basic amino group in the R side-chain.

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6
Q

Zwitter-ion

A

We represent amino acids as dipolar ions known as zwitterions.
(German zwitter = hybrid or double ion).
Zwitterions arise by internal proton transfer from the acidic carboxyl-group to the
basic amino-group i.e., an acid-base reaction occurs within the molecule.
This charged form is a zwitterion.
It is a a dipolar ion with no net
charge.

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7
Q

The Isoelectric Point (pI)

A

the pH at which an amino acid has no net charge i.e., the amino acid exists as a zwitterion.

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8
Q
A
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