Thermodynamics Flashcards

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1
Q

What is Thermodynamics?

A

Thermodynamics: A study of energy transfer and the relationship between properties of substances.
Revolves around Thermal Motion, Thermal Energy and Temperature.

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2
Q

What is Thermal motion?

A

Thermal motion: Particles and atoms constant movement are influenced by changes in temperature in a proportional matter .

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3
Q

What is Thermal Energy?

A

Thermal Energy: The sum of all kinetic energy (rotational, vibrational) and translational energy of particles. It is used to describe the power of the thermal motion.

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4
Q

What is Temperature (T)?

A

Temperature (T): A physical quantity describing the internal thermal state of an object. The degree of thermal energy is the temperature.

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5
Q

Change in Temperature → Change in _______ _____ → Change in Thermal Energy

A

Change in Temperature → Change in Thermal Motion → Change in Thermal Energy

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6
Q

Temperature Scales - Kelvin

A

Kelvin (=Absolute, Fahrenheit) scale (K): Fixed points are 0K (absolute zero, no values below this point) and 100K (human body temperature).
(SI Unit)

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7
Q

Temperature Scales - Celsius

A

Celsius scale (℃): Fixed points are 0℃ (melting point of ice) and 100℃ (boiling point of H2O)

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8
Q

Conversion Formula between Celsius and kelvin:

A

𝑡/℃=𝑇/𝐾−273.15

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9
Q

Define Heat (Q):

A

Heat (Q):The process of energy transfer between two interacting objects of different thermal energies. The object with higher temperature will transfer energy in form of heat to the other object.

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10
Q

What is the SI unit of Heat (Q)?

A

Heat (Q) - SI unit: J

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11
Q

Define Heat capacity (C):

A

The ratio between heat transfer and change in temperature (∆𝑇).

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12
Q

Formula for Heat Capacity (C):

A

𝐶= 𝑄/∆𝑇

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13
Q

Unit for Heat Capacity (C):

A

Unit:J/K

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14
Q

Define Specific Heat capacity (Cs):

A

The heat capacity of a specific body. It depends on the body size and material.

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15
Q

Formula for Specific Heat Capacity (Cs):

A

C𝑠= 𝐶/𝑚

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16
Q

Unit for Specific Heat Capacity (C):

A

Unit:J/kg∙K

17
Q

What is Thermal expansion?

A

Thermal expansion: Increase in thermal motion and energy of a body, may result in thermal expansion. This can increase the length and volume of a body. Usually as the temperature increase, bodies expand. Vise versa, bodies shrink.

18
Q

States of matter: The body (material) can exist in _(how many?) different states of matter

A

States of matter: The body (material) can exist in 3 different states of matter
(There are actually 5 but this is not our topic)

19
Q

Define the 3 different States of Matter by Volume and Shape.

A

Solid: Well defined volume and shape of the body
Liquid: Defined volume, but shape depends on the container
Gas: No definite volume or shape. The body takes the volume and shape of its container

20
Q

What is a Phase transition?

A

Phase transition: The change of a body from one state to another.

21
Q

What are the different Phase Transitions?

A

Melting↔Freezing
Evaporation↔Condensation
Sublimation

22
Q

What is Specific Latent Heat?

A

Specific latent heat (L): During a phase transitioning, the released/absorbed heat (Q) divided by the mass (m) of the body, is called the specific latent heat.

23
Q

Specific latent heat (L) - Unit:

A

Specific latent heat (L) -Unit: J/kg

24
Q

What is the formula for Specific latent heat (L)?

A

𝐿= 𝑄/𝑚

25
Q

What is Specific heat of of fusion (Lf)?

A

Specific heat of of fusion (Lf): In case of melting, the specific amount of heat needed for 1kg body to move from a solid to liquid state.

26
Q

What is Specific heat of of vaporization (Lv)?

A

Specific heat of vaporization (Lv): In case of boiling, the specific amount of heat needed for 1kg body to move from a liquid to gas state

27
Q

How can we define amount of substance (From chemistry)?Units?

A

Amount of substance (n): 1 mole of a body contains 6.02*1023 mol^-1 number of particles. Unit: mole

28
Q

What is Avogadro’s Constant (Na)

A

NA = 6.02 ∙ 1023 mol^-1

29
Q

number of particles (N) - Definition and Formula (Chemistry)

A

The number of particles (N) equals The relationship between the amount of substance (n) and Avogadro’s Number (Na)
Formula - N=n∙𝑁a

30
Q

What is an Ideal gas?

A

Ideal gas: A gas consisting of random moving point particles, which have perfect elastic collisions. They only move by translation, thus the thermal energy is proportional to the kinetic translational energy.

31
Q

Formula for the Ideal Gas law

A

pV=nRT
T = temperature (K)
R (universal gas constant) = 8.314 J/(mol*K)

32
Q

What is an Isobaric Process?

A

Isobaric process: Pressure p stays constant

33
Q

What is an Isothermal process?

A

Isothermal process: Temperature T stays constant

34
Q

What is an Isochoric process?

A

Isochoric process: Volume V stays constant

35
Q

1st law of Thermodynamics - Formula

A

1st law of Thermodynamics : ∆𝑈=𝑄 −𝑊
∆U = Internal energy
Q = Heat (J)
W = Work (J)

36
Q

2nd law of Thermodynamics - Formula

A

2nd law of Thermodynamics:

∆𝑆𝑡𝑜𝑡𝑎𝑙=∆𝑆𝑠𝑦𝑠𝑡𝑒𝑚+∆𝑆𝑠𝑢𝑟𝑟𝑜𝑛𝑑𝑖𝑛𝑔 >0

37
Q

3rd law of Thermodynamics - Definition

A

As the temperature approaches absolute 0 (0K), the entropy of a system goes towards a constant value.