Thermodynamics Flashcards
What is Thermodynamics?
Thermodynamics: A study of energy transfer and the relationship between properties of substances.
Revolves around Thermal Motion, Thermal Energy and Temperature.
What is Thermal motion?
Thermal motion: Particles and atoms constant movement are influenced by changes in temperature in a proportional matter .
What is Thermal Energy?
Thermal Energy: The sum of all kinetic energy (rotational, vibrational) and translational energy of particles. It is used to describe the power of the thermal motion.
What is Temperature (T)?
Temperature (T): A physical quantity describing the internal thermal state of an object. The degree of thermal energy is the temperature.
Change in Temperature → Change in _______ _____ → Change in Thermal Energy
Change in Temperature → Change in Thermal Motion → Change in Thermal Energy
Temperature Scales - Kelvin
Kelvin (=Absolute, Fahrenheit) scale (K): Fixed points are 0K (absolute zero, no values below this point) and 100K (human body temperature).
(SI Unit)
Temperature Scales - Celsius
Celsius scale (℃): Fixed points are 0℃ (melting point of ice) and 100℃ (boiling point of H2O)
Conversion Formula between Celsius and kelvin:
𝑡/℃=𝑇/𝐾−273.15
Define Heat (Q):
Heat (Q):The process of energy transfer between two interacting objects of different thermal energies. The object with higher temperature will transfer energy in form of heat to the other object.
What is the SI unit of Heat (Q)?
Heat (Q) - SI unit: J
Define Heat capacity (C):
The ratio between heat transfer and change in temperature (∆𝑇).
Formula for Heat Capacity (C):
𝐶= 𝑄/∆𝑇
Unit for Heat Capacity (C):
Unit:J/K
Define Specific Heat capacity (Cs):
The heat capacity of a specific body. It depends on the body size and material.
Formula for Specific Heat Capacity (Cs):
C𝑠= 𝐶/𝑚
Unit for Specific Heat Capacity (C):
Unit:J/kg∙K
What is Thermal expansion?
Thermal expansion: Increase in thermal motion and energy of a body, may result in thermal expansion. This can increase the length and volume of a body. Usually as the temperature increase, bodies expand. Vise versa, bodies shrink.
States of matter: The body (material) can exist in _(how many?) different states of matter
States of matter: The body (material) can exist in 3 different states of matter
(There are actually 5 but this is not our topic)
Define the 3 different States of Matter by Volume and Shape.
Solid: Well defined volume and shape of the body
Liquid: Defined volume, but shape depends on the container
Gas: No definite volume or shape. The body takes the volume and shape of its container
What is a Phase transition?
Phase transition: The change of a body from one state to another.
What are the different Phase Transitions?
Melting↔Freezing
Evaporation↔Condensation
Sublimation
What is Specific Latent Heat?
Specific latent heat (L): During a phase transitioning, the released/absorbed heat (Q) divided by the mass (m) of the body, is called the specific latent heat.
Specific latent heat (L) - Unit:
Specific latent heat (L) -Unit: J/kg
What is the formula for Specific latent heat (L)?
𝐿= 𝑄/𝑚
What is Specific heat of of fusion (Lf)?
Specific heat of of fusion (Lf): In case of melting, the specific amount of heat needed for 1kg body to move from a solid to liquid state.
What is Specific heat of of vaporization (Lv)?
Specific heat of vaporization (Lv): In case of boiling, the specific amount of heat needed for 1kg body to move from a liquid to gas state
How can we define amount of substance (From chemistry)?Units?
Amount of substance (n): 1 mole of a body contains 6.02*1023 mol^-1 number of particles. Unit: mole
What is Avogadro’s Constant (Na)
NA = 6.02 ∙ 1023 mol^-1
number of particles (N) - Definition and Formula (Chemistry)
The number of particles (N) equals The relationship between the amount of substance (n) and Avogadro’s Number (Na)
Formula - N=n∙𝑁a
What is an Ideal gas?
Ideal gas: A gas consisting of random moving point particles, which have perfect elastic collisions. They only move by translation, thus the thermal energy is proportional to the kinetic translational energy.
Formula for the Ideal Gas law
pV=nRT
T = temperature (K)
R (universal gas constant) = 8.314 J/(mol*K)
What is an Isobaric Process?
Isobaric process: Pressure p stays constant
What is an Isothermal process?
Isothermal process: Temperature T stays constant
What is an Isochoric process?
Isochoric process: Volume V stays constant
1st law of Thermodynamics - Formula
1st law of Thermodynamics : ∆𝑈=𝑄 −𝑊
∆U = Internal energy
Q = Heat (J)
W = Work (J)
2nd law of Thermodynamics - Formula
2nd law of Thermodynamics:
∆𝑆𝑡𝑜𝑡𝑎𝑙=∆𝑆𝑠𝑦𝑠𝑡𝑒𝑚+∆𝑆𝑠𝑢𝑟𝑟𝑜𝑛𝑑𝑖𝑛𝑔 >0
3rd law of Thermodynamics - Definition
As the temperature approaches absolute 0 (0K), the entropy of a system goes towards a constant value.