Thermodynamics Flashcards

1
Q

What is enthalpy

A

The heat content of a system at constant pressure

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2
Q

What is temperature

A

A measure of the average kinetic energy of random motion of molecules, atoms or ions in a substance

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3
Q

What is heat

A

A measure of the amount of energy transferred from an object of high temperature to an objective of low temperature, the total kinetic energy

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4
Q

What is endothermic

A

System gains heat from the surroundings

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5
Q

What is exothermic

A

System releases heat to the surroundings

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6
Q

What is H in endothermic reactions

A

+

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7
Q

What is H is exothermic reactions

A

-

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8
Q

What is a state function

A

A property that depends on only the difference between the initial and final states rather than the way they were achieved, i.e. Change in H

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9
Q

What is an open system

A

A system that permits the transfer of mass, work or energy between the system and surroundings

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10
Q

What is a closed system

A

A system where energy can be transferred between the system and surroundings, but matter cannot

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11
Q

What is an isolated system

A

A system where there is no transfer of energy or matter between the system and surroundings

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12
Q

What is a system

A

The object under inspection

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13
Q

What is the surroundings

A

Everything in the universe besides the system

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14
Q

What is Kinetic Energy

A

Energy of motion, phases

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15
Q

What is potential energy

A

Energy of position, phase changes

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16
Q

What is the first law of thermodynamics

A

The law of conservation of energy,- energy cannot be created nor destroyed, it may only be transferred into another form

17
Q

What is the second law of thermodynamics

A

If a process is spontaneous in one direction, it cannot be spontaneous in the reverse direction

18
Q

What is heat capacity

A

The amount of heat required to raise the temperature of an object by 1°C

19
Q

What is specific heat

A

The amount of heat required to raise the temperature of 1 g of an object by 1°C

20
Q

Is deposition, condensation, and freezing endo or exo

A

Exothermic

21
Q

If sublimation, melting, and boiling endo or exo

A

Endothermic

22
Q

Why is it good that water has a pretty high specific heat

A

The higher the specific heat, it takes more energy and heat transfer to have a significant change in temperature

23
Q

Would a substance with a very low specific heat require a lot, or a small amount of energy to produce a large change in temperature

A

Only a lil bit

24
Q

What is a catalyst

A

A substance added to a rxn to speed it up

25
Q

What values on a potential energy graph changes when a catalyst is added

A

Activation energy for the forward and reverse reactions, and the potential energy of the activated complex