Thermodynamics Flashcards

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1
Q

absolute zero

A

lowest possible temperature kinetic energy = 0

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2
Q

How to convert from Celsius to Kelvin?

A

+273

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3
Q

thermometer

A

device that has volume that changes in a predictable way as temperature changes

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4
Q

What does a thermometer measure?

A

temperature of body it is in contact with

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5
Q

thermal interaction

A

energy transferred until two bodies have same temperature

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6
Q

thermal equilibrium

A

two bodies have same temperature

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7
Q

heat

A

energy that is transferred from one body to another as a result of a difference in termperature

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8
Q

internal energy

A

total random kinetic energy of particles + total inter-particle potential energy of particles

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9
Q

How can internal energy of a system change?

A

as result of heat added or taken out as result of work performed

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10
Q

specific heat capacity

A

energy required to increase temperature of a unit mass of a body be one kelvin

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11
Q

specific latent heat

A

amount of energy required to change the phase of a unit mass at constant temperature

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12
Q

Why is specific latent heat larger for vaporization than for melting?

A

increase in separation of molecules much larger when vaporizing more energy required to achieve greater separation

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13
Q

method of mixtures

A

measures specific heat capacity of a solid solid put into container of hot water reaches constant temperature temperature recorded solid transferred to calorimeter of known specific heat capacity and initial temperature final temperature of water recorded after thermal equilibrium reached

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14
Q

flaw with method of mixtures

A

likely that solid loses heat to surrounding air during transfer temperature of solid less than expected specific heat capacity appears larger

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15
Q

mole

A

contains as many particles as are atoms in 12g of carbon-12

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16
Q

Avogadro’s constant

A

number of particles in mole 6 x 10^23

17
Q

atomic mass unit

A

1/12 mass of one atom of carbon-12

18
Q

molar mass

A

sum of atomic masses of atoms

19
Q

pressure

A

normal force applied per unit area

20
Q

How do you calculate pressure at an angle?

A

P = Fcos/A

21
Q

ideal gas characteristics

A
  1. point particles
  2. negligible volume
  3. no forces between molecules except when collide
  4. duration of collision negligible compared to time between collisions
  5. collisions are elastic
  6. molecules have range of speeds and move randomly
22
Q

When can a real gas be approximated by an ideal gas?

A

when density low

23
Q

pressure-volume law

A

P proportional to 1/V PV = constant

24
Q

What is pressure-volume law also called?

A

Boyle’s law

25
Q

How do you confirm the pV=constant relationship is constant?

A

take three points form graph and show product is same

26
Q

volume-temperature law

A

V proportional to T V/T = constant

27
Q

What is volume-temperature law also called?

A

Charles’ law

28
Q

pressure-temperature law

A

P proportional to T P/T = constant

29
Q

What is pressure-temperature law also called?

A

Gay-Lussac’s law Amontons’ law

30
Q

equation of state of an ideal gas

A

pV = nRT

31
Q

What is the Boltzmann equation?

A

Ek = 3/2kT

32
Q

Boltzmann constant

A

R/NA