Thermodynamics Flashcards

0
Q

Extensive properties

A

Change is seen as amount of sample changes

Ex. Delta h delta s delta g and delta e

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1
Q

State functions

A

An aspect of a chemical system

Pressure temp volume and number of atoms/mols

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2
Q

Quantities are made intensive properties when we define

A

The temp, pressure, mass and physical state of the substance

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3
Q

Standard state of a system

A

1 ATM, 25 degrees Celsius, 1 mole of compound

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4
Q

Delta H^o
Delta S^o
Delta G^o
The ^o means that

A

The system is at standard state and they are intensive properties

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5
Q

In a exothermic reaction delta h is

A

Negitive

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6
Q

Kinetic energy KE is

A

The energy that matter possesses because of motion

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7
Q

KE=

A

.5mv^2

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8
Q

Potential energy

A

Stored energy that may be released under the appropriate conditions

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9
Q

Specific heat of water

A

4.184J/g degrees celcius

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10
Q

Specific heat

A

The amount of energy required to raise the temp of a substance 1 degree Celsius

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11
Q

Dulong and Petit law

A

Specific heat X molar mass = 25J/mol*degrees Celsius

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12
Q

Specific heat is a ________ physical property of all elements and can be used to _________

A

Intensive

Identify substances

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13
Q
Heat energy (q) = 
(In terms of specific heat)
A

(Specific heat)(mass)(Delta T)

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14
Q

q is expressed in (unit)

A

Joules

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15
Q

First law of thermodynamics states

A

Energy is always conserved

16
Q

Delta E =

A
q + w
(Heat energy + work)
or
PEfinal - PEinitial
(Potential energy)
17
Q

q is positive in

A

Endothermic reactions

18
Q

w is positive when

A

Work Is done on the system

19
Q

w is negative when

A

Work is done by the system

20
Q

Work is equal to

In terms of pressure

A

-P* Delta V

21
Q

If volume increases in a system

A

Work is done by the system and w is negitive

22
Q

When volume decreases

A

Work is done on the system and w is positive

23
Q

Work is defined as

A

Force applied to an object as it moves a certain distance