Thermodynamics Flashcards

1
Q

What is temperature?

A

A measurement of the average kinetic energy of the particles in a system

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2
Q

When an object warms up what happens to the particles?

A

They move faster

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3
Q

What happens if you had two objects at different temperature?

A

Heat will flow to the colder until their temperatures are identical and thermal equilibrium is reached

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4
Q

What is a thermometer?

A

A temperature measuring instrument

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5
Q

What are the three main types of thermometers?

A

-bulb thermometer
-bimetallic thermometer
-thermistor

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6
Q

What are thermocouples used for?

A

Measurement of high temperature

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7
Q

Why is mercury used in thermometers?

A

They have a linear rate of expansion with rising temperature

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8
Q

In a bulb thermometer what happens when temperature rises?

A

The fluid expands and moves up the tube

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9
Q

Why is water not used in thermometers?

A

Because it would freeze or boil

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10
Q

How does a bimetallic thermometer work?

A

Two different metals are bonded together and when the temperatures rises or falls the bonded metal will bend in a certain direction

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11
Q

A thermistor is a combination of two words, what are these words?

A

Thermal and resistor

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12
Q

How does a thermistor work?

A

A wire that changes its electrical resistance with change in temperature

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13
Q

What is the most commonly used sensor to measure temperature?

A

A thermistor

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14
Q

What temperature range is used in the metric system?

A

Celsius or centigrade

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15
Q

Where is Fahrenheit used?

A

USA and some Caribbean countries

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16
Q

In Fahrenheit what is the freezing point of water?

A

32˚F

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17
Q

In Fahrenheit what is the boiling point of water?

A

212˚F

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18
Q

What is the only temperature that is the same in Celsius and Fahrenheit?

A

-40˚

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19
Q

When is kelvin used as the base unit for temperature?

A

In the SI units

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20
Q

What is the lowest possible temperature?

A

Absolute zero

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21
Q

What would happen to ordinary gases like air if they reached absolute zero?

A

They’d become rock solid

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22
Q

Is it possible to get to absolute zero?

A

No but we can get to a fraction of ˚C from it

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23
Q

What is the equation to work out kelvin?

A

K = C + 273.15

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24
Q

What is heat?

A

A measurement of energy transferred from one substance to another

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25
What is the units for heat energy?
joules or calories
26
When the unit calories is written down it can come in two forms, lower c and upper C, what does this mean?
Lower c is one thousandths of a upper C
27
Does heat transfer from a lower temperature to a higher?
No unless work is done
28
What would happen if absolute zero is reached?
All molecular movement would stop
29
What is specific heat capacity?
The amount of energy that is needed to raise the temperature of 1 kg of that substance by 1Kelvin
30
If you added heat to two different substances would they increase at the same rate?
No as they have different specific heat capacity
31
What is the equation for specific heat of a substance?
Heat energy added / (mass x change in temperature)
32
What is heat capacity?
The ratio of the amount of heat energy transferred to an object to the resulting increase in its temperature
33
What is another way to describe heat capacity?
Thermal mass
34
What is the heat capacity equation?
Heat energy added / change in temperature
35
What is heat transfer?
The flow of heat due to temperature differences
36
What are the three methods by which heat is transferred?
-convection -conduction -radiation
37
In relation to heat transfer what is conduction?
The process by which heat is directly transferred through the material
38
What is the only heat transfer method in solids?
Conduction
39
In relation to heat transfer what is convection?
Heat transfer from one part of a fluid to another
40
What is thermal radiation?
Energy that comes from a source and travels through air or a vacuum
41
In relation to heat transfer why is radiation different to conduction and convection?
Because the substances don’t have to be in contact with eachother
42
When a material is heated up and it expands what happens to the molecules for this to happen?
They vibrate about their positions and space between them increases
43
What is linear expansion?
It’s the comparison between length change to the original and the change in temperature
44
What type of solids does area expansion affect?
Two dimensional solids
45
What type of solids get affected by volumetric expansion?
Three dimensional solids
46
From the three basic states of substances, what order do they expand the most?
1st: gases 2nd: liquid 3rd: solids
47
Why cant the expression for the linear thermal expansion of solids be used on liquids and gases?
Because they have no fixed shape
48
What is the first law of thermodynamics?
Energy can neither be created nor destroyed but can only be transformed from one to another
49
What is the second law of thermodynamics?
The total energy output (as produced by a machine) is equal to the amount of heat supplied
50
What is a heat receiver?
The place where heat energy is lost
51
What is another way a heat receiver is described?
A heat sink
52
What is a thermodynamic cycle?
Where the. Working fluid of the system undergoes a series of processes and finally returns to its initial state i.e a refrigerator
53
What are the two types o thermodynamic cycles?
Open and closed
54
What are the five basic elements of a thermodynamic cycle?
-working substance -heat source -heat receiver -pump -engine
55
In thermodynamic cycles what is a working substance?
A medium that receives, stores and transports the energy
56
In thermodynamic cycles what is a heat source?
Supplies thermal energy to the working fluid
57
In thermodynamic cycles what is a heat receiver?
It absorbs the heat (or thermal energy) from the working substance
58
In thermodynamic cycles what is a pump?
Moves the working substance from low pressure to high pressure
59
In thermodynamic cycles what is a engine?
It converts the thermal energy to work in mechanical energy
60
What is the factor in a thermodynamic open cycle?
An opening in the system allows the fluid to be regularly replaced i.e aircraft air conditioning
61
What is the main factor in a thermodynamic closed cycle?
The working substance never leaves the cycle
62
What are the three main characteristics that affect gases?
-temperature -pressure -density
63
When one of the main characteristics that affects gases what happens to the other 2?
They will also change
64
When a gas compresses or expands, what happens to the temperature?
It will change
65
What is boules law?
The direct relationship between pressure and the volume of a gas
66
What is an isothermal process?
The pressure exerted by a gas varies inversely with the volume of the gas (temperature remains constant)
67
What is Charles law?
Describes the direct relationship between the temperature and the volume of a gas
68
What is an isobaric process?
The volume of a given mass of an ideal gas increases or decreases by the factor as its temperature increases or decreases (constant pressure)
69
What is gay-lussac’s law?
Describes the direct relationship between the pressure an the temperature of a gas
70
What is a isochoric process?
The pressure of gas varies directly with the temperature (constant volume)
71
What is combined gas law?
It puts all three gas laws together to show that pressure, temperature, and volume are interrelated
72
How do you calculate work in a thermodynamic process?
Work = pressure x change in volume
73
What is an adiabatic process?
Where no heat is transferred to or from the system
74
Why is an adiabatic process an idealisation?
Because it is impossible to get absolute thermal insulation
75
What is an engine cycle in thermal dynamics?
Any thermodynamic process constituting a cycle for the conversion of heat into work
76
What is meant when a system is said to have undergone a process?
One of the properties of the system change (temperature,volume, etc)
77
What is a reversible process?
Is a process when the system can be restored to the initial state from the final state without causing any changes in the surroundings
78
In practice why does a reversible process never occurs?
Because you will always affect the surroundings as you can’t achieve thermodynamic equilibrium
79
What is a irreversible process?
A process that cannot be completely reversed without causing any changes in the surroundings
80
Why is a irreversible process also called the natural process?
Because all the processes occurring in nature are irreversible processes
81
What is an internal combustion engine?
A heat engine in which the combustion of a fuel occurs with an oxidiser in a combustion chamber
82
What are the two types of theoretical and practical cycles for the internal combustion engine?
-reciprocating piston engines -gas turbine engines
83
What is the difference between a reciprocating piston engine (car engine) and a gas turbine engine (plane engine)?
The piston engine use non-flow processes that convert heat energy into mechanical energy however a gas turbine engine use flow processes to convert heat energy into mechanical energy
84
What happens with pressure and volume in a gas turbine engine?
Combustion occurs at a constant pressure with an increase in volume
85
What happens with pressure and volume in a piston engine?
Combustion occurs at a constant volume with an increase in pressure
86
In both piston and gas turbine engines what are the four stages?
Induction , compression, combustion, and exhaust
87
What is the Otto cycle?
An idealised thermodynamic cycle describing the processes in a spark ignition piston engine
88
What is the Brayton cycle?
A thermodynamic cycle describing the process in a constant-pressure heat engine
89
What are the three main components to a brayton-type engine?
A gas compressor, a mixing chamber, and an expander
90
What does a heat pump do?
Transfers thermal energy from a cold place to a warm place (opposite to natural flow of heat)
91
What is refrigeration?
The removal and relocation of heat
92
Cooling can be achieved by what three processes?
-conduction -convection -radiation
93
What are the two main processes used in the design of refrigeration equipment?
Conduction and convection
94
What principle is used for an aircraft refrigeration system?
That a liquid can be made to vaporise at any temperature by altering the pressure acting on it
95
What is latent heat?
The amount of heat that is absorbed or released when a body undergoes a constant temperature process
96
Why is latent heat said to be latent?
There is a change of heat but no change of temperature
97
When is there a change in heat energy but no change in temperature of a substance?
When that substance is changing its state i.e ice to water or water to steam
98
What is latent heat Of fusion?
The heat added causing a change of state from solid to a liquid
99
What is latent heat of evaporation?
The heat added causing a change of state from liquid to a vapour
100
What are the two types of curves when considering the changes of states?
A cooling curve and a heating curve
101
In relation to cooling curves and heating curves what is fusion?
The phase transition from a solid to a liquid
102
In relation to cooling and heating curves what is solidification?
A phase change of matter that results in the production of a solid
103
Why is solidification an exothermic process?
Because heat is released during the change
104
What is thermal energy?
The kinetic energy possessed by an object due to the movement of particles within it
105
The faster the particles move within an object or system results in?
A higher temperature
106
What is the heat of combustion?
The energy released as heat when a substance undergoes complete combustion with oxygen