Thermodynamics Flashcards
Lattice Enthalpy
Enthalpy change when 1 mole of an ionic compound is formed from its gaseous ions under standard conditions
Enthalpy of atomisation
Enthalpy change when 1 mole of gaseous atoms are formed under standard conditions.
Electron affinity
Energy change when one mole of gaseous atoms gain an electron
Enthalpy of hydration
Enthalpy change that accompanies dissolving of gaseous ions in water to form one mole of aqueous ions
Enthalpy of solution
Enthalpy change that accompanies when one mole of a solid ionic lattice dissolves
Entropy
Measure of disorder in a system.
Units of entropy
J/K/mol
ΔS =
S(products) - S(reactants)
Why is Gibbs free energy used?
Calculate if a reaction is spontaneous or not at a given temperature
ΔG =
ΔH - TΔS
To find what temperature a reaction is spontaneous
T = ΔH / ΔS
On a graph
y = mx + c
y = ΔG | m = -ΔS | x = T | c(y-intercept) = ΔH