Thermodynamics Flashcards
when two bodies have equality of temperature with a
third body, they in turn have equality of temperature with each
other.
Zeroth Law
Also known as the Conservation of Energy principle,
states that energy can neither be created nor destroyed, it can only change form
First law of thermodynamics
Deals with the quality of energy (energy
degradation). There are two classical statements of this law:
It is impossible to construct a device that will
operate in a cycle and produce no effect other than the raising of a
weight and the exchange of heat with a single reservoir.
: It is impossible to construct a device that operates
in a cycle and produces no effect other than the transfer of heat from a
cooler-body to a hot
Second law of thermodynamics
It is impossible to construct a device that will
operate in a cycle and produce no effect other than the raising of a
weight and the exchange of heat with a single reservoir.
Kelvin Planck Statement
It is impossible to construct a device that operates
in a cycle and produces no effect other than the transfer of heat from a
cooler-body to a hot
• Clausius statement
states that the entropy of a perfect crystal is zero at
the absolute zero of temperature.
Third law of thermodynamics
the
science that deals with the study of energy and
entropy;
Thermodynamics
it
deals
with
the
properties
of
matter/substance related to heat and work;
Thermodynamics
it deals
with processes and cycles on the transformation of
energy of all kinds, from one form to another.
Thermodynamics
deals with processes of cooling; it deals
with the processes and cycles of different methods of
refrigeration;
Refrigeration
condition of a substance as
described by certain observable macroscopic
parameter called Properties
State of Substance
quantity of matter that is homogeneous
throughout(solid, liquid, gas)
Phase-
Solid to Liquid
Melting
Liquid to Solid
Solidification (Freezing)
Liquid to Gas
Evaporation
Gas to liquid
Condensation
Solid to Gas
Sublimation
Gas to Solid
Deposition
Simply the change of state
Process
constant temperature.
Isothermal
constant pressure
Isobaric
constant volume
Isometric/isovolumetric
constant entropy
Isentropic
constant enthalpy
Isenthalpic
PV^n = C
Polytropic
a series of processes one after the other such
that the initial and final states are the same.
Cycle
Measures of the degree of hotness or coldness of a body
Temperature
If the temperature of a given quantity of gas is held
constant, the volume of the gas varies inversely
with the absolute pressure during a change of
state.
Boyle’s Law
Specific gravity is always _____ to rate of density
Equal
If the pressure on a particular quantity of gas is
held constant, then, with any change of state, the
volume
will
vary
directly
as
the
absolute
temperature.
Charle’s Law