Thermodynamics 1 Flashcards

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1
Q

Thermodynamics

A

Thermodynamics is a branch of physics which deals with the processes involving heat work our internal energy thermodynamics deals with the macroscopic properties and does not go into the detail structure.

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2
Q

System and surrounding

A

If we consider one mole of gas in enclosed inside a cylinder fitted with a piston the gas is a system which has a clear boundary sometimes the system does not have a clear boundary anything outside the system is called the surrounding

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3
Q

Types of system

A

open system, isolated system and close system

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4
Q

open system

A

it is a system where the exchange of martyr and energy with the surroundings take place

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5
Q

closed system

A

it is a system where the exchange of only energy and not matter with the surrounding takes place

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6
Q

isolated system

A

It is a system which is not influence in any way by its surroundings

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7
Q

What are thermodynamic variables

A

Thermal state of a simple homogeneous body is defined by its temperature T pressure P and volume V these quantities are called thermodynamic variables

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8
Q

Thermodynamic process

A

A particular set of such values specify a particular state of the system. The process by which the system goes from one thermodynamic state to another is called thermodynamic processes

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9
Q

Extensive variable

A

Extensive variables indicate the size of the system.
Eg: - Volume, mass, internal energy, etc…

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10
Q

Intensive variable

A

Intensive variable do not indicate the size of the system.
Eg: - Pressure, temperature, density, etc…

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11
Q

Thermal equilibrium

A

Ford assistant to be in thermal equilibrium, there should be no temperature difference between the different parts of the system or between the system and the surroundings. Dual system in thermal equilibrium with each other are in the same temperature.

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12
Q

Zeroth Law of thermodynamics

A

If two systems A and B are separately in a thermal equilibrium with a 3rd system C, then systems A and B are in thermal equilibrium with each other.

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13
Q

first law of thermodynamics

A

This is the law of conservation of energy first up Delta Q is a quantity of energy is supplied to a system, delta U be the increase in the internal energy, in addition to the same work done by it, the total work
delta W = P delta V
delta Q = delta U + delta W
= delta U + P delta V

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14
Q

Isothermal process

A

Then a system suffers a physical change under the condition that its temperature remains constant throughout the process it is called an isothermal process.
delta Q = delta U + delta W
delta U = 0
delta Q = delta W

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15
Q

Adiabatic process

A

Then the system undergoes a physical change under the condition that no heat enters or leaves the system, the change is said to be adiabatic.
delta Q = 0
delta U = - delta W

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16
Q

Entropy

A

Physical quantity remains constant during an adiabatic change is called entropy

17
Q

Relationship between the slope of Adiabatic and isothermal curve

A

The slope of adiabatic is gamma times Slope of isothermal.

18
Q

Second law of thermodynamics

A

It is mainly concerned with the direction of heat transfer

19
Q

Kelvin statement

A

It is impossible to get a continuous supply of work from body by calling it to a temperature lower than the lowest of its surrounding.