Thermodynamics 1 Flashcards
Thermodynamics
Thermodynamics is a branch of physics which deals with the processes involving heat work our internal energy thermodynamics deals with the macroscopic properties and does not go into the detail structure.
System and surrounding
If we consider one mole of gas in enclosed inside a cylinder fitted with a piston the gas is a system which has a clear boundary sometimes the system does not have a clear boundary anything outside the system is called the surrounding
Types of system
open system, isolated system and close system
open system
it is a system where the exchange of martyr and energy with the surroundings take place
closed system
it is a system where the exchange of only energy and not matter with the surrounding takes place
isolated system
It is a system which is not influence in any way by its surroundings
What are thermodynamic variables
Thermal state of a simple homogeneous body is defined by its temperature T pressure P and volume V these quantities are called thermodynamic variables
Thermodynamic process
A particular set of such values specify a particular state of the system. The process by which the system goes from one thermodynamic state to another is called thermodynamic processes
Extensive variable
Extensive variables indicate the size of the system.
Eg: - Volume, mass, internal energy, etc…
Intensive variable
Intensive variable do not indicate the size of the system.
Eg: - Pressure, temperature, density, etc…
Thermal equilibrium
Ford assistant to be in thermal equilibrium, there should be no temperature difference between the different parts of the system or between the system and the surroundings. Dual system in thermal equilibrium with each other are in the same temperature.
Zeroth Law of thermodynamics
If two systems A and B are separately in a thermal equilibrium with a 3rd system C, then systems A and B are in thermal equilibrium with each other.
first law of thermodynamics
This is the law of conservation of energy first up Delta Q is a quantity of energy is supplied to a system, delta U be the increase in the internal energy, in addition to the same work done by it, the total work
delta W = P delta V
delta Q = delta U + delta W
= delta U + P delta V
Isothermal process
Then a system suffers a physical change under the condition that its temperature remains constant throughout the process it is called an isothermal process.
delta Q = delta U + delta W
delta U = 0
delta Q = delta W
Adiabatic process
Then the system undergoes a physical change under the condition that no heat enters or leaves the system, the change is said to be adiabatic.
delta Q = 0
delta U = - delta W