Thermodymanics Flashcards
State the second law of thermodynamics dynamics?
The entropy of a reaction system and its surroundings, increases for a spontaneous process
State 3rd law of thermodynamics
The entropy of a perfect crystal is at 0K (zero)
entropy increases when
Increase in temperature
When a substance melts, boils or dissolves
Type of entropy in a solid
Low
Type of entropy in a gas
High
When heat energy is produced, what happens to the entropy of the surroundings
Increases
What happens to the entropy of the surroundings when heat energy is absorbed?
Decreases
What does ΔG mean
Change in free energy
What does ΔS mean
Change in entropy
What does ΔH mean
Change in enthalpy
In Gibbs free energy, what makes the reaction feasible?
If the free energy between reactants and products is negative
What happens to the equilibrium position if ΔG°<0
The forward reaction is favoured
What happens to the equilibrium position if ΔG°>0
The reverse reaction is favoured
How do we know if a reaction is at equilibrium
ΔG°=0