Past Papers Flashcards

1
Q

What many elements bind to a octahedral complex ion

A

6

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2
Q

How many bonds does a bidentate ligand has

A

2

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3
Q

What technique does purify and identify a compound

A

Distillation

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4
Q

The absorption of radiation in the radio frequency region causes H nuclei to adopt a high frequency state aligned against a strong magnetic field.
Explain how this leads to peaks in an NMR spectrum corresponding to the different H environments

A

Hydrogen nuclei flip with magnetic field
Different wavelengths
OR
Different energy gaps between high and low states

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5
Q

State a reason why different bonds absorb different wave numbers of infrared radiation

A

Different strengths of bonds

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6
Q

State what is meant by a weak acid

A

Partially disassociated into ions in an aqueous solution

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7
Q

The sodium salt of Heuke acid formed a new reaction mixture during the first step is treated with dilute hydrochloric acid. A white precipitate of puke acid is formed.

Explain why adding hydrogen ions in the salt of the weak acid results in the formation of undisassociated weak acid molecules

A

Hydrogen ions react with the conjugate base

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8
Q

What causes d orbital splitting in octahedral complex 

A

Repulsion from Electrons

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9
Q

State the aufbau principal

A

Electrons fill orbitals in order of increasing energy

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10
Q

State one difference between bonding molecular orbital and an anti-bonding molecular orbital 

A

Anti-bonding high energy or anti-bonding unfilled and bonding filled 

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11
Q

Explain why cis and trans isomerism can exist in some compounds with carbon to carbon double bonds 

A

Lack of rotation at the double bond
Two different groups attached to each carbon atom

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12
Q

Describe fully how weighing by difference Work

A

Weigh the empty container
weigh the container with the sample 

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13
Q

State what is meant by nucleophilic

A

Negatively charged ions or neutral molecules that are electron rich

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14
Q

What is meant by an antagonist?

A

Binds to receptor and prevents the response

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15
Q

Sate second law of thermodynamics

A

The entropy of a reaction system and its surroundings increases for a spontaneous process

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16
Q

Explain how a pi bond is formed

A

Orbitals overlap side on

17
Q

Colour arises in some aromatic compounds due to absorption of visible light .

Explain why the conjugated system in benzene result in absorption of ultraviolet light and not visible light.

A

The energy gap is too large between the from HOMO to LUMO since the conjugated system is small

18
Q

The concentration of cobalt ions in a cobalt chloride solution can be determined by complexometric titration

Suggest a suitable complexometric reagent that could be used in this titration

A

EDTA

19
Q

What solvent is used in a haloalkane to alkene

A

Ethanol

20
Q

Explain why the pH of a buffer solution remains approximately constant when small volume of water is added

A

Ratio of acid and salt unchanged/ the salt and acid re diluted by the same quantity

21
Q

Describe an experiment procedure that could be carried out to determine which of the two solutions has the larger buffer capacity

A

Same volume of each buffer

Measure pH after same volume of alkali added

22
Q

Define the term drug

A

Substance which alters the biochemical body processes

23
Q

The impure precipitate of benzoic acid is produced by acidifying the alkaline sodium benzoate

Explain fully why an aqueous solution of sodium benzoate is alkaline

A

Ions from the salt react with H+ ions from water, this results in excess OH- ions from water equilibrium

24
Q

What is the definition of a bronsted Lowrydefination for a base

A

Proton acceptor

25
Q

Explain fully why a solution of complex ion Zn(H2O)6^2+ is colourless

A

Full 3d subshell
No absorption of visible light

26
Q

Explain the effect infrared radiation has on the bonds within molecules and how this allows different functional groups to be identified

A

Vibrate
Different bonds/functional groups absorb different wave number/wavelength/frequency/energy