Synthesis Flashcards

1
Q

What is the process of reactant bonds breaking and product bonds forming?

A

Bond fission

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What are the two types of bond fission?

A

Heterolytic and homolytic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Describe homolytic fission

A

Results in formation of 2 neutral radicals

Occurs when each atom retains one electron from sigma covalent bond and bond breaks evenly

Normally occurs non-polar covalent bonds broken

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Describe Heterolytic fission

A

Results in formation of 2 opposite charged ions

Occurs when one atom retains both electrons from the sigma covalent bond and bond breaks unevenly

Normally occurs when polar covalent bonds are broken

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What makes homolytic reactions unsuitable for organic synthesis?

A

Forms complex mixtures of products

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What makes Heterolytic fission better suited for organic synthesis?

A

Far Fewer products

How well did you know this?
1
Not at all
2
3
4
5
Perfectly