Thermochemsitry Flashcards

1
Q

Work

A

Energy used to cause an object to move

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2
Q

Heat

A

Energy used to increase an objects temperature

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3
Q

System

A

Part of the universe we are looking at

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4
Q

Surroundings

A

Everything else

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5
Q

State function

A

Property of a system that only depends on the systems initial and final state

(Final - initial)

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6
Q

Heat (j) joule

A

Unit of energy 1J=1kg-msquared over s squared

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7
Q

Delta t (tfinal - tinitial) is a

A

State function

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8
Q

Q=mcdeltat

If q>0 the reaction is

A

Endothermic

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9
Q

Q=mcdeltat

If q

A

Exothermic

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10
Q

First law of of thermodynamics

A

Energy is conserved

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11
Q

Energy can be ____ or _______

A

Heat or work

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12
Q

Change in energy =

A

Heat + work

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13
Q

Enthalpy (h)

A

The heat content and flow of a system due to chemical changes

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14
Q

The change in enthalpy that accompanies a chemical reaction is known as

A

Enthalpy of reaction or
Heat of reaction

Delta h rxn

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15
Q

Calorimetry is

A

The measure of heat flow q=mcdeltat

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16
Q

Q=mcdeltat

A

M= mass(grams)
C=specific heat capacity (j/g x degrees Celsius)
Delta t= change in temperature

17
Q

Specific heat capacity

A

The amount of heat required to raise 1g of substance 1degree c
(J/g degree Celsius)

18
Q

Molar heat capacity

A

The amount of heat required to raise 1 mol of substance 1 degree celsius (j/mols degree Celsius )

19
Q

Heat capacity

A

Amount of heat required to raise an amount of substance 1 degree Celsius (j/degree Celsius)

20
Q

Hess’s law (of heat summation)

A

If a reaction occurs in steps, delta h is equal to the sum of the steps

21
Q

Standard enthalpy of formation of a compound

A

Enthalpy for the reaction that forms one mile of the compound from its constituent elements

22
Q

Work formula

A

P * delta v

23
Q

Which reactions are more thermodynamicly favored?

A

Ectothermic

24
Q

Enthalpy of reaction =

A

Sum of heat of products-sum of heat of reactants

25
Q

Elements in their standard states have a delta h of formation of

A

0

26
Q

Energy

A

Capacity to do work and transfer heat