Test 3 Equilibrium Flashcards

1
Q

Collision theory

A

A reaction will occur if the reactants reactants collide with enough energy

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2
Q

Activation energy

A

Minimum amount of energy needed for a reaction

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3
Q

Anything that enhances collisions will __________ the rate of reaction

A

Increase

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4
Q

Many gasses in a closed container are

A

Reversible

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5
Q

Increasing concentration __________ rate of reaction

A

Increases

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6
Q

Lowering temperature ___________ rate of reaction

A

Decreases

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7
Q

Decreasing particle size __________ rate of reaction

A

Increases

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8
Q

Catalysts __________ rate of reaction

A

Increase

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9
Q

Anything that _____ __________ will increase rate of reaction

A

Enhances collisions

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10
Q

Chemical equilibrium

A

Is reached when the rates of the foward and reverse reaction are equal

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11
Q

Lechatelier’s principal

A

If a stress is applied to a system at equilibrium, the system changes to relieve the stress and return to equilibrium

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12
Q

Stresses include a change in

A

Concentration
Temperature
Pressure

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13
Q

Increasing the pressure of an equation would shift the equilibrium towards the side with the _______ moles

A

Least

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14
Q

Increasing pressure has no effect on an

A

Aqueous solution

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15
Q

Equilibrium position of a reaction

A

Is given by the relative concentrations of reactants and products at equilibrium

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16
Q

Instead of using % for equilibrium position, equilibrium contracts are used (_____)

A

K eq

17
Q

Equilibrium constant equation

A

K eq = [C]^c [D]^d
___________
[A]^a [B]^b

[ ] = mol/liter or M

18
Q

K eq > 1

A

Products are favored at equilibrium

19
Q

K eq

A

Reactants are favored at equilibrium

20
Q

Solubility product constant

A

K sp

21
Q

Soluable

A

Describes ionic compounds (salts) that dissolve in water

22
Q

Insoluable

A

Describes ionic compounds (salts) that don’t dissolve in water

23
Q

The solubility product constant (K sp) quantifies

A

The extent to which salt dissolves

24
Q

Don’t include _____ in equilibrium expression

A

Solids

25
Q

Smaller k sp =

A

Lower solubility (less ions dissolved in solution)

26
Q

Common ion

A

Ion present in both salts

27
Q

Precipitate

A

A solid product that “comes out” of solution when two aqeous reactants are mixed

28
Q

Q ( reaction quotient )

A

Used in place of k sp at non equilibrium conditions

29
Q

Q > K sp

A

Precipitate will form

30
Q

Q

A

No precipitate will form

31
Q

Q = K sp

A

System is at equilibrium

32
Q

Rate of chemical change

A

Amount of reactant changing per unit time (how fast reactants become products)

33
Q

Equilibrium which processes occur continuously with no net charge

A

Dynamic equilibrium

34
Q

Chemical equilibrium

A

Dynamic with foward and reverse reactions occurring at the same rate

35
Q

Equilibria involving species in more than one phase

A

Heterogenous equilibrium