thermal properties and temperature Flashcards

You may prefer our related Brainscape-certified flashcards:
1
Q

What is Thermal Expansion?

and why it happens

Note: When this happens,what remains the same and what doesn’t

A

When (most) materials are heated, they expand.

This expansion happens because the molecules start to move around (or vibrate) faster, which causes them to knock into each other and push each other apart.

it is the space taken up by the molecules that increases. The molecules themselves remain the same size.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Thermal Expansion in Solids, Liquids & Gase

A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q
A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

The thermal expansion of materials can have some useful applications:

A

The expansion of a liquid in a thermometer can be used to measure temperature.

A bimetallic strip, consisting of two metals that expand at different rates, can be made to bend at a given temperature, forming a temperature-activated switch.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

The thermal expansion of materials can have undesirable consequences:

A

Consequences:

The expansion of solid materials can cause them to buckle if they get too hot.

This could include:

Metal railway tracks.

Road surfaces.

Bridges.

Things that are prone to buckling in this way often have gaps built into them, providing some room for them to expand into.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q
A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

When a substance is heated, some of its physical properties can change.

If these properties change in a well-defined way, by measuring the property you can

A

The volume (and density) of the substance.

The electrical resistance of the substance.

determine the temperature.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

When a substance is heated, some of its physical properties can change.

If these properties change in a well-defined way, by measuring the property you can determine the temperature.

how?

A

In order to build a thermometer based on one of these properties, you need to start by measuring the property at some well-defined fixed points.

A fixed point is a temperature at which some easily identifiable change occurs, such as the melting of ice (at 0 °c) or the boiling of pure water (at 100 °c).

These fixed points allow you to know the temperature without having to measure it directly.

Usually two fixed points are used:

The lower fixed point: the melting temperature of ice.

The upper fixed point: the boiling temperature of pure water.

Once a property (such as electrical resistance) has been measured at these two fixed points, the values of that property at other temperatures can be worked out.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Measuring some property at two fixed points allows you to then work out the temperature for other values of that propertydraw gragp

A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

about the way in which the property changes with temperature: linear

A

That it does so at a steady rate.

Properties that change in this way are said to be linear, and linearity is a very useful property for something to have as it makes it easy to work out the relationship between that thing and the temperature.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Sensitivity

A

– if the thing you are measuring changes significantly when the temperature changes, it makes it easier to detect small changes in temperature: Your thermometer is more sensitive.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Range

A

What are the lowest and highest temperatures the thermometer can measure? If a liquid-thermometer is too short, there may not be enough room for the liquid to expand into.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q
A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

descirbe liquid-in-glass thermometer

A

a thin glass capillary tube containing a liquid that expands with temperature.

At one end of the tube is a glass bulb, containing a larger volume of the liquid which expands when heated, moving into the narrower tube.

A scale along the side of the tube allows the temperature to be measured based on the length of liquid within the tube.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q
A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q
A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

The liquids used in liquid-in-glass thermometers are chosen for their thermal expansion properties:

A

thermal expansion properties:

They expand linearly with temperature.

They expand significantly, giving them greater sensitivity.

They have low freezing points and high boiling points, allowing them to be used over a greater range of temperatures.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

The use of a large glass bulb coupled to a very narrow tube also results in…as

A

greater sensitivity

a small change in volume results in the liquid moving a significant distance along the tube.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

describe A thermocouple

A

two different types of wire attached together.

When the joint between the two wires is heated, a potential difference (voltage) is created between the two wires.

The greater the temperature, the greater the potential difference.

Thermocouples are not as sensitive as liquid-in-glass thermometers, but because the metals have high melting points, they can be used to measure very high temperatures.

Thermocouples are also very responsive to rapidly changing temperatures.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q
A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q
A
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

When a substance is heated, its…increases.

A

internal energy increases.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
23
Q

As a substance’s internal energy increases, so will

A

its temperature.

24
Q

The higher the temperature of a substance the more …it possesses

A

the more internal energy it possesses.

25
Q

The molecules within a substance possess two forms of energy

Together, these two forms of energy make up the

The temperature of the material is related to…of the molecules.

A

Kinetic energy (due to their random motion/vibration).

Potential energy (due to the bonds between the molecules).

internal (thermal) energy of the substance.

to the average kinetic energy

26
Q
A
27
Q

What is Thermal Capacity?

A

The thermal capacity of an object is the amount of heat energy required to raise the temperature of that object by 1 °c.

28
Q

The greater the thermal capacity of an object, the more

A

heat energy it takes to raise its temperature.

29
Q

The thermal capacity is also equal to

A

the amount of heat energy an object will give out when it cools by 1 °c.

30
Q

The energy, E, required to raise the temperature of an object by an amount T is given by the equation:

A

E = thermal capacity × T

31
Q

The thermal capacity of an object is related to the specific heat capacity by the equation:

A
32
Q
A
33
Q

What is Specific Heat Capacity?

A

The specific heat capacity of a substance is the amount of thermal energy required to raise the temperature of 1kg of that substance by 1 °C.

34
Q

Specific heat capacity has units of

A

joules per kilogram per degree Celsius (J/kg °C).

35
Q

(Note: Different substances have different

A

specific heat capacities)

36
Q

From the definition of specific heat capacity, it follows that if you have more than 1 kg of a material, you will need more
Likewise, if you want to raise its temperature by more than 1 °C, you will also need to

A

thermal energy.

add more thermal energy.

37
Q

The amount of thermal energy needed is given by the equation:

A
38
Q
A
39
Q

describe an experiment to determine the specific heat capacity of a substance.
A method for carrying out such an experiment is given below.

The following apparatus will be needed:

A

A block of the substance (preferably 1kg in mass) or in the case of a fluid, a beaker containing a known mass of the fluid.

A thermometer.

An appropriate heater (e.g. an immersion heater).

A power source.

A joule meter or a voltmeter, ammeter and stopclock (I will assume we have the latter).

40
Q

describe an experiment to determine the specific heat capacity of a substance.
A method for carrying out such an experiment is given below.

In this experiment you need to use the following equation to determine the specific heat capacity of the substance:

A
41
Q

describe an experiment to determine the specific heat capacity of a substance.
A method for carrying out such an experiment is given below.

procedure

A

Start by assembling the apparatus and measure the initial temperature of the substance.

Turn on the power supply and start the stop-clock.

Whilst the power supply is on take several periodic measurements of the voltage and current, and calculate an average of these values.

After 5 minutes (300 seconds) switch off the power supply, stop the stop-clock and leave the apparatus for a few more minutes.

Monitor the thermometer and make a note of the highest temperature reached.

Calculate the rise in temperature.

The heat supplied to the substance can be calculated using the equation

energy = current × voltage × time

(Note: The time must be in seconds)

These values, along with the mass of the substance, can now be substituted into the top equation to find the specific heat capacity of the substance.

The biggest problem with the above experiment is that not all of the heat supplied by the heater will go into the substance – some will go into the surroundings and the substance will also lose heat whilst it is being heated.

This means that the value for the heat added will be too great which means that the calculated specific heat capacity will also be too great.

42
Q
A
43
Q

A change of state refers

A

to a substance changing its state between solid, liquid or gas.

44
Q

Usually, when a substance is heated its temperature

However, whilst a substance changes its state

This happens because

When a substance turns from gas to liquid (condensation) or from liquid to solid (solidification) the opposite happens:

A

increases.

the temperature of that material remains constant, even though energy is still being added.

the energy is being used to break the bonds between the molecules instead of increasing the kinetic energy of the molecules (and hence the temperature).

The temperature remains constant whilst the bonds reform (giving out energy in the process).

45
Q

he melting point and boiling point of a substance is the

A

temperature at which that substance changes state.

46
Q
A
47
Q

Boiling and Evaporation both refer to a change in state from liquid to gas, however:

difference

A

however:

Boiling occurs at a fixed temperature and happens throughout the liquid.

Evaporation can occur at any temperature and happens from the surface of the liquid.

48
Q

Latent Heat is

is

A

the energy required to change the state of a substance to break the bonds holding molecules togethe

49
Q

Latent Heat of Fusion is

A

the energy required to turn a solid into a liquid.

50
Q

Latent Heat of Vaporisation is

A

the energy required to turn a liquid into a gas.

51
Q

The Specific Latent Heat, L, of a substance is

A

the energy required to change the state of 1 kg of that substance.

52
Q

For an object of mass m, the total energy required to change its state is given by the equation:

A
53
Q

A method for determining the specific latent heat for steam is given below.

In this experiment you need to use the following equation:

A
54
Q

A method for determining the specific latent heat for steam is given below.

The following apparatus will be needed:

A

A vacuum flask containing pure water

A top pan balance

An appropriate heater (e.g. an immersion heater).

A power source.

A joule meter or a voltmeter, ammeter and stop-clock (I will assume we have the latter).

55
Q

a method for determining the specific latent heat for steam is given below.

procedure

A

Start by measuring (and recording) the mass of the vacuum flask along with the water.

Next place the heater into the water and connect it to the power supply.

Turn on the power supply and wait until the water starts to boil.

Once the water is boiling start the stop-clock and take several measurements of the potential difference (on the voltmeter) and current (on the ammeter), and calculate an average of these values.

After 5 minutes (300 seconds) switch off the power supply and stop the stop-clock.

Now measure the mass of the vacuum flask and water once more, and calculate how much the mass has decreased by. This will give the mass of water that has changed state (which you will use in determining your result).

The heat supplied to the material can be calculated using the equation:

energy = current × voltage × time

(Note: The time must be in seconds)

These values, along with the change in mass, can now be substituted into the top equation to find the specific latent heat for steam.

A similar experiment can be carried out for ice (in a beaker this time), but the ice must be measured separately from the beaker otherwise you’ll be measuring the mass of the water as well.

It is also important to ensure that the temperature of the ice is 0 °c at the start of the experiment. This will be the case if the ice has started to melt.