Thermal Physics Flashcards

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1
Q

Define Specific Heat Capapcity

A

The energy needed to raise the temperature of a unit mass of the substance by 1 Kelvin without a change of state

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2
Q

What is the internal energy of a body

A

Sum of all the kinetic and potential energies of all its particles
The energy of its molecules due to their positions and movements

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3
Q

What happens on a molecular level when energy is transferred to a solid

A

Molecules vibrating about fixed points gain kinetic energy so their temperature increases to their melting/boiling point.
Then they stop gaining K.E and gain potential energy and break/weaken the bonds between them

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4
Q

How to know if a substance is pure

A

It will melt at its melting point and boil at its boiling point

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5
Q

Compare the density of a substance in the three states of matter, explain why

A

Density of a gas is much less than for a liquid/solid

Dist. between molecules of gas is much larger

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6
Q

Why can’t solids flow

A

Atoms have strong enough bonds and not enough kinetic energy to break/weaken these strong bonds so they can flow

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7
Q

Define Latent Heat of Fusion

A

The energy required to change the state of 1kg of a substance from solid to liquid without a change of temperature

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8
Q

Explain on a molecular level how a substance melts

A

When a solid is heated at its melting point, it gains enough potential energy to weaken the bonds between molecules and become a liquid.
There is no temperature increase as all the energy is being transferred to the P.E store

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9
Q

Define Latent Heat of Vaporisation

A

The energy required to change the state of 1kg of a substance from a liquid to gas without a change of temperature

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10
Q

What is Brownian Motion

A

The random motion of larger particles in a fluid caused by collisions with surrounding particles

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11
Q

How may one see brownian motion

A

Looking at smoke particles under a microscope

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12
Q

Use M.K.T to explain Boyle’s Law

A

Increasing the volume of a gas allows molecules to move more freely with less frequent collisions

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13
Q

Use M.K.T to explain Charles’s Law

A

Increasing the temperature of a gas increases the Av. K.E of molecules
One must increase the volume in order to keep the frequency of the collisions the same since molecules are traveling faster

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14
Q

Use M.K.T to explain the Pressure Law

A

Increasing the temp. of a gas increases its average K.E
Since they are moving faster, but in the same confined space, they collide more frequently and faster.
Rate of change of momentum for collisions with walls increases
Hence Pressure will increase

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15
Q

Name the 5 assumptions of M.K.T

A

No intermolecular forces act on molecules
Duration of collisions is negligible in comparison to time between collisions
Motion of molecules is random and are perfectly elastic collisions
Motion of molecules follow Newton’s Laws
Molecules move in straight lines

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16
Q

What is the derivation for the Kinetic Theory Model Equation

A

Assume there is 1 particle moving in a cube length l in the x-plane, it has a perfectly elastic collision with the wall with a speed of u. By conservation of momentum:
mu-(-mu)=2mu
Time taken for the molecule to collide again with the wall is
t=dist/speed so t=2l/u
We can find the impulse
F=Change in momentum/Time
F=2mu/(2l/u)
F=mu^2/l
As we know P=F/A and the area of the wall is l^2 so
P=(mu^2/l)/l^2
P=mu^2/l^3
The volume of the cube is l^3
P=mu^2/V
Now we should consider the total no. of particles in the cube, the total pressure is the sum of all the pressures. N is the no. of particles. We will use the root mean squared speed for the av. spd.
P=Nmu(rms)/V
However, this will be assuming the particles are all traveling in the same plane. In reality, they are traveling in different planes, but the average speed in each plane will be the same, so we divide the arms speed by 3
P=Nmc(rms)/3V
pV=Nmc(rms)/3

17
Q

What is Boyle’s Law

A

Pressure is proportional to 1/V

pV = const.

18
Q

What is Charles’ Law

A

V/Absolute Temp = Const.

V is Proportional to T

19
Q

What is the Pressure Law

A

P/Abs. T = const.

P is proportional to T

20
Q

In the Ideal Gas Equation, what is n

A

The number of moles

21
Q

In the ideal gas equation, what is N

A

The number of molecules

22
Q

How to calculate work done on a gas

A

p x Change in V
Area under a Pressure/Volume Graph
Work is done on a gas to change its volume when pressure is constant

23
Q

If a gas at pressure Q and temperature U in a container is released into an atmosphere with pressure P and temperature T, what will be the pressure and temperature of the gas remaining when it is at equilibrium with the surroundings

A

Pressure P
Temperature T
The characteristics of the atmosphere become the same inside the container when they are at equilibrium

24
Q

What is the unit for mean square speed

A

m^2s^-2

25
Q

What happens as 2 gases approach/reach thermal equilibrium

A

Hot gas cools, cold gas heats
Till they are the same temperature
Warmer gas particles transfer energy to cooler gas particles

26
Q

Define Thermal Equilibrium

A

no net flow of thermal energy between two or more bodies

bodies at same temperature