Engineering Physics 2 Flashcards
Equation showing the relationship between P,T and V
P1V1/T1 = P2V2/T2
PV/T = Const.
What is a property of an ideal gas interms of its energy
Energy of the molecules is entirely kinetic and depends only on the temperature
No forces acting between the molecules, no work done against these forces
Define a system
A fixed mass of some substance, enclosed by a boundary, outside of which are the surroundings
What is the internal energy (U) of a gas
The sum of the total kinetic energy of its constituent particles and (unless it is an ideal gas) the total potential energy of the particles.
What is the first law of thermodynamics
Q = ΔU + W
ΔU=Q-W
Q = Energy transferred to the system by heating
W = always negative
U = Internal Energy
Change in internal energy = Energy transferred to the system by heating - Work done by the system
What is W in the first law of Thermodynamics
Work done by the system
eg. energy transferred out by compression
Value is negative if energy is transferred out
Define a non flow process
A process during which the fluid does not move in or out of the system during the process
What is an isothermal process
So what is its restriction
A process through which a system stays at the same temperature
So Change in U = 0
A non-flow process
What is the first law of thermodynamics for an isothermal process
Why
Q=W
No change in temperature, so average kinetic energy of particles is constant
So total kinetic energy and therefore internal energy is constant, change in U = 0
What is the ideal gas equation for an isothermal process
pV=Const.
Boyles Law
n and T are constant
Use the first law of thermodynamics to explain how an isothermal change can happen
If a gas expands and does external work W, an amount of heat Q has to be supplied to the gas in order to maintain its temperature constant, and vice versa.
How does pV change as the temperature that the isothermal process takes place at changes
Graph gets further from the origin
Equation for work done on a gas during compression
W=pAΔs
Δs = distance moved by the piston
p = pressure
A = Area
What is the first law of thermodynamics for a constant pressure process
How do you use the equation for a compression
Q = ΔU + pΔV
For a compression
ΔV is negative as volume is decreasing
pΔV =W is negative as work is being done on the gas
What is the first law of thermodynamics for a constant volume process, explain it
ΔU = Q
When the volume is constant, no work has been done on/by the gas
So all thermal energy transferred to the gas will be transferred to the internal energy