thermal dynamics Flashcards

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1
Q

Specific heat capacity

Key:

  • Often referred to as thermal capacity
  • Different masses have different heat capacities
  • 1 kg = 1 JOULES
  • Q = mcΔT
A

When heated, some materials increased in temperature more quickly than others. The property of the material that describes this phenomenon is called the specific heat capacity and is defined as the amount of energy required to increase the temperature of 1 kg of the substance by 1 °C (or K).

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2
Q

Are Liquids and gasses good insulators or conductors?

Key
- far apart

A

liquids and gasses are usually poor conductors (Insulators) of heat. In gasses and liquids, the particles are far apart, making energy transfer by collision very inefficient.

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3
Q

Describe the key process that moves thermal energy around the Earth’s mantle?

A

Convection currents in the molten rock move hotter less dense rock outwards and cooler denser rockfalls.

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4
Q

What is temperature?

Key:

  • Average kinetic energy
  • Measurement
A

A temperature is a number that is related to the average kinetic energy of the molecules of a substance. Temperature is the measurement.

Kow the difference between temperature and heat;
Heat is the total amount of energy possessed by all the molecules in an object.

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5
Q

What is Celius?

Key:
- Scale

A

Celsius is a temperature scale. 0 degrees - 100 degrees. freezing point - boiling point.

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6
Q

What is kelvin?

Key:
- Scale

A

Kelvin is a temperature scale. - 273 kelvin - +273 Kelvin.

Absolute zero to evaporation

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7
Q

Conversion between Celcius and Kelvin

A

From Celcius to Kelvin = +273 Kelvin

From Kelvin to Celcius = -273 kelvin

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8
Q

What is heat?

  • Motion of molecules
A

Heat energy is the result of the movement of tiny particles called atoms, molecules, or ions in solids, liquids, and gases. The motion of atoms and molecules creates a form of energy called heat or thermal energy which is present in all matter

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9
Q

Explain why faster atoms and molecules give off a hotter temperature.

Key:
- Kinetic energy

A

The faster a particle moves, the more kinetic energy it has. Kinetic energy is related to heat. The motion of atoms and molecules creates a form of energy called heat, The faster the particles in a substance move, the hotter it is.

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10
Q

What is the Kinetic theory of matter?

Key:

  • Atoms and Molecules
  • Viberate
  • Space
A

Kinetic theory of matter: All matter is made up of atoms and molecules that are constantly moving. When heat is added to a substance, the molecules and atoms vibrate faster. As atoms vibrate faster, the space between atoms increases. ( Thermal expansion)

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11
Q

how do particles in solids interact?

Key:

  • Viberate
  • Potential energy
  • Regular shape
A

Particles in solids are not moving but vibrating.
A lot of potential energy is stored in a strong force that holds the energy together. Solids are tightly packed, usually in a regular pattern.

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12
Q

How do particles in liquids interact?

Key:

  • Kinetic energy
  • Space
  • Dense
A

The particles in a liquid have more kinetic energy than the particles in the corresponding solid. Because they are moving faster, the particles in the liquid occupy more space, and the liquid is less dense than the corresponding solid.

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13
Q

How do particles in gasses interact?

Key:
- No regular arrangement

A

Particles in a gas are well separated with no regular arrangement. Molecules are rasing.

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14
Q

What is absolute zero?

  • lowest
  • No heat energy
  • Minimal vibrational
A

Absolute zero is the lowest possible temperature where nothing could be colder and no heat energy remains in a substance. Absolute zero is the point at which the fundamental particles of nature have minimal vibrational motion.

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15
Q

What is the zeroth Law?

Key:

  • Equilibrium
  • Second
  • Size
A

Two bodies in contact will come to thermal equilibrium. The law defines temperature as a property independent of material. In that sense, the temperature does not depend on the size of the material (the number of molecules). However, smaller substances will reach their heat capacity faster.

It is the second law of thermodynamics.

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16
Q

What is the First Law?

Key:

  • Delta U = Q - W
  • Work
A

Based on the law of conservation of energy.
Delta U = Q - W
- The internal energy of a substance can increase if worked.
- The First Law of Thermodynamics states that energy is conserved and cannot be created or destroyed. If there is an energy change in a system, all the energy must be accounted for.

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17
Q

What is thermal Equilibrium?

Key:

  • Two substances
  • Same temperature
A

The condition under which two substances in physical contact with each other exchange no heat energy. Two substances in thermal equilibrium are said to be at the same temperature.

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18
Q

What is Internal energy?

Key:

  • Random
  • Microscope
A

Internal energy is defined as the energy associated with the random, disordered motion of molecules.
It refers to the invisible microscopic energy on the atomic and molecular scale

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19
Q

What is a thermometer?

Key:
- Thermo (heat) and meter (measuring device).

A

A thermometer is a tool that measures temperature — how hot or cold something is. Made up of thermo (heat) and meter (measuring device).

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20
Q

What is Thermal Expansion?

Key:

  • Viberate
  • Kinetic energy
  • Average separation
A

Thermal expansion is the tendency of matter to change its shape, area, and volume in response to a change in temperature. When a substance is heated, the kinetic energy of its molecules increases. When the temperature is increased, the kinetic energy of atoms increases and the atoms vibrate and move, resulting in a greater average separation of atoms and thus thermal expansion

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21
Q

What is a Thermal Gradient?

Key:

  • High to low
  • Conservation temperature
A

A temperature gradient is a physical quantity that describes in which direction and at what rate the temperature changes the most rapidly around a particular location.

  • Thermal energy flows from a High level to a lower level.
  • The heat comes from a higher source.
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22
Q

What is Conduction?

Key:

  • Solids are better conductors
  • Metals make good conductors
  • Vibration and collisions
  • Transfer of energy without a change in the matter.
A

Conduction is the transfer of heat through a substance as a result of collisions between neighboring vibrating particles. This transfer of kinetic energy from particle to particle continues until thermal equilibrium is reached.
-In solids, the particles are more tightly bound and closer together than in liquids and gases.
Thus, kinetic energy can be transferred more quickly.

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23
Q

What is Convection?

Key:
- As it rises, it pulls cooler fluid down to replace it.

A

Moving particles transfer thermal energy through a fluid by forming convection currents. Convection currents move thermal energy through many fluids.
- As water’s temperature increases in the presence of a heat source, it will become less dense and rise. As it moves up and away from the heat source, it cools and becomes denser and sinks.

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24
Q

How can we Reduce convection currents?

Key:
- Remember that convection is not always negative as it distributes thermal energy

A
  • Prevention of fluid movement – smaller rooms
  • Trapping fluids – layers trapping air (insulation)

Air is a poor conductor and by trapping it between the panes, convection currents cannot be set up. Heat loss through walls can be reduced using cavity wall insulation.

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25
Q

What is Radiation?

Key:
- Radiation is a form of energy transport consisting of electromagnetic waves traveling at the speed of light.

A

Electromagnetic waves emitted by all objects. Radiation is a method of heat transfer that does not rely upon any contact between the heat source and the heated object.

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26
Q

Black body emitters

A

An object is considered a perfect black body when it absorbs all of the incoming light and does not reflect any. It appears perfectly black at room temperature.
It is an ideal emitter: at every frequency, it emits as much or more thermal radiative energy as any other body at the same temperature.

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27
Q

Explain the process of evaporation

Key:
-Evaporation is the process by which water changes from a liquid to a gas or vapor.

A

The molecules move and vibrate so quickly that they escape into the atmosphere as molecules of water vapor.

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28
Q

What is Latent Heat?

Key:
- Without change…

A

The heats required to convert a solid into a liquid or vapor, or a liquid into a vapor, without change of temperature.

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29
Q

Q = mcΔT explains this formula

Clue:
150 mL of water is heated from 10°C to 50°C. What amount of energy is required for this
temperature change to occur?

A

The quantity of energy, Q, transferred to or from a substance in order to change its temperature is directly proportional to three factors:
• The mass of the substance (m)
• The change in temperature (ΔT) in K
• The specific heat capacity of the substance (c). ( Can be found on a table)
Thus,
Q = mcΔT

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30
Q

ΔT = Q/MC explain this formula and how it is used.

clue:
A cup holds 250 mL of water at 20 ̊C. 10.5 kJ of heat energy is transferred to the water. What temperature does the water reach after the heat is transferred?

A
• The mass of the substance (m)
• The change in temperature (ΔT)  in K 
• The specific heat capacity of the substance (c).  ( Can be found on a table)
Thus,
 Temperature = 
ΔT = Q/MC
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31
Q

How much more energy is emitted by the substance at the current temperature compared to the initial temperature.

How can we calculate the thepreture ratio?
Key:
The ratio of power (hot to cold) = Ratio of temperatures to the power of 4

A

Step 1
Change the temperature to Kelvin.

Step 2
Calculate the ratio.

   P hot       (Thot)^4
----------= -----------  
 P cold      (Tcold)^4
32
Q

Q = ML explain this formula and how it is used.

A

Energy = Mass of substance in kg multiplied by the specific latent heat of fusion or fission of the substance.
Q = ML
convert mass into kg

Latent heat is the energy released or absorbed, by a body during a constant-temperature process, for example, a phase change of water from liquid to gas.

33
Q

What is the Electromagnetic spectrum?

A

The range of wavelengths or frequencies over which electromagnetic radiation extends.

34
Q

What are the Electromagnetic spectrum Regions?

A

The EM spectrum is generally divided into seven regions, in order of decreasing wavelength and increasing energy and frequency. The common designations are: radio waves, microwaves, infrared (IR), visible light, ultraviolet (UV), X-rays and gamma rays

35
Q

Explain Wien’s Law

Key:

  • displacement law
  • peak at different
A
  • Wien’s displacement law states that the black-body radiation curve for different temperatures will peak at different wavelengths that are inversely proportional to the temperature.
36
Q

What is the kinetic theory of matter?

Key:

  • Rapid motion
  • Space
  • atoms
  • Random motion
  • Not lost or gained
  • Eventually, stop moving
  • Large gas particles
A

The kinetic theory of matter assumes that:
• all matter is made up of particles in constant, random, and rapid motion
• there is space between the particles.
• All matter is made up of many very small particles (atoms or molecules).
• The particles are in constant random motion.
• No kinetic energy is lost or gained overall during collisions between particles.
• The distances between particles in a gas are large compared with the size of the particles.
The particles would eventually stop moving when they reach the coldest possible temperature is called absolute zero. This is 0 Kelvin or −2730 C.

37
Q

What is Heat transfer?

Key:
- High to low

A

During heating and cooling, energy is always transferred from a region of high temperature to a region of lower temperature. Heat transfer changes the internal energy of both systems involved.

38
Q

What distinguishes the different types of electromagnetic radiation from each other?

Key:
These properties, in turn, determine their ability to be transmitted through transparent or opaque objects, their heating effect and their effect on living tissue

A
  • Their wavelength (the distance the wave takes to repeat itself)
  • Their frequency (the number of wavelengths passing every second)
  • The amount of energy they transfer.
39
Q

Why do Hot objects emit electromagnetic radiation

Key:

  • Motion of electrons
  • Random range of speed
  • Frequency
A

At any temperature above absolute zero, atoms are moving and colliding into each other. The motion of the atoms and their collisions with other atoms affect the motion of the electrons. The electrons produce electromagnetic radiation.

  • The higher the temperature of the object, the higher the frequency and the shorter the wavelength of the radiation emitted.
40
Q

Explain Stefan Boltzmann EQUATION

Key:
Power ∝ T ^4.
- As the temperature rises, the kinetic energy rises

A
  • He found that the power was proportional to absolute temperature to the power of 4, that is, Power ∝ T ^4.
    1. T Multiple = T final/ T initial
    2. power the temperature Multiple by 4

For example.
1. 2000/500 = 4

2.Power ∝ T ^4.
therefore 4^4 = 256

The rate of transmission is increased by 256 times.

41
Q

Often media articles suggest that Global Warming is something that can either
be believed in or not. List 3 pieces of evidence that this effect is occurring.

A

Co2 levels in the atmosphere are rising dramatically since the industrial evolution

  • Average global temperature has risen by 1c - it is now around 15c
  • sea levels are rising
  • Also can cite, IR emission measurements from Earth and comparisons of
    received and emitted thermal energy
42
Q

What is the cause of Global Warming?

key:
- Human impact on the earth

A
  • Less ice, therefore, less UV reflection
  • Seal level rises
  • When fossil fuels are burned, they release large amounts of carbon dioxide, a greenhouse gas, into the air. Greenhouse gases trap heat in our atmosphere, causing global warming.
  • Land clearing, removing trees due to Intensive farming
  • increased population
43
Q

Sea breeze

Key:
- A sea breeze is caused by convection currents from temperature differences between the land and sea.

A

During hot summer days, radiant energy from the Sun heats the land and sea. The land reaches a higher temperature sooner than the water. The air near the ground becomes hot, it expands, becoming less dense than the cooler, denser air over the sea. Rising warm air due to convection causes what is known as a sea breeze.

44
Q

Land breeze

Key:
- Land breeze convection current blowing cool air from the Land.

A

At night, the roles reverse. The air over the ocean is now warmer than the air over the land. The land has a lower heat capacity than seawater. During night time, the temperature of the land drops faster than the sea. Hot air (lower density) above the sea rises. Cooler air from the land blows towards the sea and hence produces land breeze.

45
Q

Explain Latent heat of fusion Formula

Clue:
How many kJ of energy are required to melt exactly 100 g of ice initially at −4.00 ̊
C? Assume no loss of energy to the surroundings.

A

(mass of the body) x (specific latent heat) The equation is. Q= mL. convert mass to Kelvin

  • Latent heat describing the energy for the phase change between a liquid and a solid to occur without a change in temperature.
46
Q

Explain Latent heat of Fission Formula

Clue:
How much heat energy must be transferred away from 100 g of steam at 100 ̊C to
change it completely to a liquid? 0.1kg

A

Two common forms of latent heat are latent heat of fusion (melting) and latent heat of vaporization (boiling).

Process, for example, a phase change of water from liquid to gas.

This is written as
(mass of the body) x (specific latent heat) The equation is. Q= mL.

47
Q

λmax

Key:
Lambda max

A

This wavelength is called the maximum wavelength or λmax.

Lambda max refers to the wavelength along the absorption spectrum where a substance has its strongest photon absorption.

48
Q

Δ U = Q - W Explain this formula

Key:
- The first law of thermodynamics

A

Change in thermal energy = positive change in internal energy on the system - work is done by the system.

49
Q

Δ U = Q + W Explain this formula

Clue:
A hot block of iron does 50 kJ of work on a cold floor. The block of iron also transfers 20 kJ of heat energy to the air. Calculate the change in energy (in kJ) of the iron block.

A

Change in thermal energy = Positive change in internal energy on the system + work done on the system

50
Q

Δ U = - Q - W Explain this formula

A

Change in thermal energy = negative change in internal energy by the system- work is done by the system.

51
Q

W=Q-ΔU Explain this formula

Clue:
A scientist very carefully does mechanical work on a container of liquid sodium. The liquid sodium loses 300 J of energy to its surroundings but gains 250 J of energy overall. How much work did the scientist do?

A

Work was done on the system = positive change in internal energy on the system - thermal energy.

52
Q

At night you can stand outside and still be very warm. What is the source of the thermal energy that you are receiving?

A

Potentially a little from the ground but primarily from the air around you. Infrared radiation emitted from the atmospheric gasses around you,

53
Q

What is the real reason for the seal level rising?

Key:
- Melting of floating ice does not change sea levels

A

The two major causes of global sea-level rise are thermal expansion caused by warming of the ocean (since water expands as it warms).

  • Melting of floating ice does not change sea levels
54
Q

Explain the heat transfer when the refrigerator door is left open?

Key:
- Heat travels from a higher level to lower level

A

If you leave the door open, heat is merely recycled from the room into the refrigerator, then back into the room. The temperature will start to rise inside the refrigerator. - Convection current

  • Heat travels from a higher level to lower level
55
Q

What is Primordial heat?

A

Primordial heat is the internal heat energy left over from the formation of Earth

56
Q

Draft excluders are often fitted to the bottom of doors but not the top, even though
there can be gaps just as large in both locations. Why are these only fitted to the base
of doors?

Key:
Little thing at the bottom of the door blocking the air

A

Convection currents in a room result in warmer (less dense) air rising.
The air beyond the door on the ground will be cooler (denser) and will flow into the room to replace the warm air. This is not the case above the door.

57
Q

How do you calculate the temperature

Key:
λmax

A

The value of this constant is 2.90 × 10−3 mK (meter–degree Kelvin).

constant divided by λmax = T

READ MORE ON PDF FILE

58
Q

How to calculate λmax

A

Constant divided by T =λmax

  1. CONVERT TO NANOMETERE

READ MORE ON PDF FILE

59
Q

Whats are the factors affecting thermal conduction?

Key:
The rate at which heat is transferred is measured in joules per second (J s−1), or watts (W).

A

The rate at which heat will be transferred through a system depends on the:
• Nature of the material.
• Temperature difference between the two objects
• Thickness of the material
• Surface area.

60
Q

Q/T = kAΔT / L Explain this thermal conduction formula

A

The letter Q represents the amount of heat transferred in a time t, k is the thermal conductivity constant for the material, A is the cross-sectional area of the material transferring heat, ΔT, is the difference in temperature between one side of the material and the other, and L is the thickness of the material.

61
Q

Wait, I thought “coldness” was entering my body!

A

People usually think of the sensation of cold as “coldness entering the body”, but feeling cold is better thought of as “heat energy leaving the body”. The system loses heat when work is done by the system.
The system gains heat when work is done on the system.

62
Q

What is the cause of temperature rise?

A

When the amount of Infra-red radiation radiated is less than the amount absorbed. System gain’s heat but exposes it at a lower rate.

63
Q

Examples of greenhouse gasses

A

H2O - Water vapors
CO2 - carbon dioxide
Acts like a blanket.

64
Q

How do water vapor and carbon dioxide act as a blanket?

A

H2O and CO2 have three atoms in each molecule which is more flexible than N2 and O2 which have 2 atoms in each molecule. The molecule which has three atoms can bend. Atoms with two molecules cannot bend. Other molecules with more than 2 atoms can absorb infrared radiation in the same way (methane)

65
Q

Enhanced greenhouse gases

Key:

  • human activity
  • wavelengths that CO2 absorbs
A

Enhanced greenhouse gases is when those natural effects become altered by human activity. Such as the burning of fossil fuels (coal, oil, and natural gas), agriculture and land clearing, are increasing the concentrations of greenhouse gases in the atmosphere.
Increased carbon dioxide concentration in the atmosphere means that more of the wavelengths that CO2 absorbs will be re-emitted back to Earth, increasing the temperature of the Earth. This increase is sometimes called the enhanced greenhouse effect.

66
Q

Process of the greenhouse effect

Key:
The result of this is that heat stays in the close to the earth’s surface for more than it otherwise would, therefore keeping it warmer.

A

The atmosphere lets the solar thermal radiation partially made up of visible light and infra-red radiation pass through the earths atmosphere as wavelengths. The earth’s surface than absorbs thermal radiation and spreads this energy through the process of conduction. When the surface has reached its specific heat capacity it re-emitted the energy as infra-red radiation back into the earth’s atmosphere. The infrared given off by the earth is partially absorbed by greenhouse gasses like CO2 AND H2O in the atmosphere. Three atoms in a molecule can stretch and bend actink like a blanket. The greenhouse gases vibrate the energy and shoot the infra-red radiation back in any direction because of its structure.

67
Q

Are greenhouse gases good?

A

Without the insulation from greenhouse gasses trapping the infra-red radiation, the earth would have been too cold to stand.

68
Q

How does the earth heat up?

A

48% of the radiation reaches the earth. 25% of the 340w goes back into the atmosphere vis evaporation

69
Q

How do fossil fuels affect climate change?
Key:
- Fossil fuels are hydrocarbons, primarily coal, fuel oil or natural gas, formed from the remains of dead plants and animals.

A

When fossil fuels are burned, they release carbon dioxide and other greenhouse gases, which in turn trap heat in our atmosphere, making them the primary contributors to global warming and climate change
• When these fossil fuels are burnt, the carbon, which has relatively little carbon-13, is released back into the atmosphere.

70
Q

The earth’s energy budget

A

Accounting of the incoming energy from the sun, where it goes in the atmosphere and at the surface, and how the outgoing energy leaves.

71
Q

Positive feedback Climate change
Key:
- The risk of positive feedback is the tipping point beyond the system can become stable.
-Another example of positive feedback in the Earth’s climate is the physical quantity ‘albedo’.

A

Brings change to the system, usually dramatic changes
1 process causes another process to occur which increases the frequency of the first process.
- Evaporation: Increasing sea temperatures lead to more evaporation of water, a greenhouse gas, which increases the temperature of the air and sea.

72
Q

Negative feedback climate change

- Cools down

A

Negative feedback brings stability to the system.

Thermal radiation: Increasing surface temperature emits more infra-red radiation, which cools the Earth.

73
Q

Albedo effect
Key:
-Radiation that is reflected

A

Albedo is a measure of the proportion of incoming radiation that is reflected without being absorbed. It is usually expressed as a number between 0 and 1, with 1 being a perfect reflector and 0 a perfect absorber.

74
Q

Less Albedo effect
Key:
- Increased air temperature leads to more sea ice melting

A

Increased air temperature leads to more sea ice melting, which means that more of the incoming radiation hits water rather than ice and is absorbed. This increased energy absorption then heats up the atmosphere, which leads to more sea ice melting, and so the feedback loop continues. The sea begins to expand due to the thermal energy absorbed which raises the sea level.

75
Q

What is the average global surface air temperature?

A

The average global surface air temperature since the last ice age has been about
+15 °C.