Thermal Flashcards

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1
Q

What is heat?

A

The total kinetic energy within a system.

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2
Q

What is temperature?

A

The average kinetic energy of a particle within a system.

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3
Q

What is specific heat capacity?

A

The amount of energy needed to raise 1kg of a substance of 1 degree Celsius.

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4
Q

What is specific latent heat?

A

The amount of energy to change state of 1kg of a substance

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5
Q

What is brownian motion?

A

Movement of gas is random with random velocities.

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6
Q

What is proven by brownian motion?

A

atoms/observed particles are very small and their motion is random.

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7
Q

What are the gas laws?

A

Pressure law - Pressure is directly proportional to temperature (K)

Boyle’s Law - Pressure is directly proportional to 1/Volume, Temperature is constant.

Charles’s Law - Volume is directly proportional to temperature (K)

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8
Q

What is an isothermal process?

A

A process where temperature is constant.

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9
Q

What are the properties of ideal gasses?

A
  • Particles occupy negligible volume compared to the volume of gas.
  • Molecules are identical in mass and speed.
  • Molecules collide with each other and the walls in a perfectly elastic matter in zero time.
  • Molecules exert no force on each other except during collisions.
  • There are enough molecules so that statistics can be applied.
  • They are moving randomly and rapidly.
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10
Q

What is internal energy?

A

Sum of potential and kinetic energy.

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11
Q

How does a gas exert pressure on the walls of the container?

A
  • Lots of molecules collide with the walls.
  • Molecules change momentum
  • Newton’s second law - resultant force is the rate of change of momentum therefore a force is exerted on the wall.
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12
Q

How to derive the relationship between absolute temperature and mean kinetic temperature?

A

PV = 1/3*Nmc^2
3PV = Nmc^2
KE = 1/2Mc^2
M = Nm
N = number of moles
m = Molar mass

2KE = Nmc^2
3PV = 2KE
3/2PV = KE
PV = KT for for one mol of gas
KE = 3/2
kT
1/2mc^2 = 3/2kT

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13
Q

Kinetic Theory for solids

A
  • Strong forces of attraction
  • Particles tightly packed
  • Vibrate about fixed positions
  • High density
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14
Q

Kinetic Theory for liquids

A
  • Medium forces of attraction
  • Particles close
  • Particles slide past each other
  • Medium density
  • Translational kinetic energy
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15
Q

Kinetic Theory for gas

A
  • Almost no attractive forces
  • Particles far apart (unless compressed)
  • Free to move around quickly, randomly
  • Low density, compressible
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16
Q

What is N?

A

Number of particles

17
Q

What is n?

A

Number of moles.

18
Q

What is the equation for the mass of an element?

A

M*n = m (in grams)

M = molar mass
n = number of mols

19
Q

How do I calculate the energy supplied for an object to change state into liquid then into gas?

A

E = mc/\T + mL(fusion) + mc/\T + mL(vapourisation)

20
Q

What happens to the maxwell-boltzmann curve when temperature is increased to an ideal gas?

A

Gases with higher temperatures have more particles with higher speeds. Therefore, peak of curve drops but curve is much less steep slope.

21
Q

What is a boltzmann distribution curve?

A

Number of molecules against energy.