Thermal Flashcards
What is heat?
The total kinetic energy within a system.
What is temperature?
The average kinetic energy of a particle within a system.
What is specific heat capacity?
The amount of energy needed to raise 1kg of a substance of 1 degree Celsius.
What is specific latent heat?
The amount of energy to change state of 1kg of a substance
What is brownian motion?
Movement of gas is random with random velocities.
What is proven by brownian motion?
atoms/observed particles are very small and their motion is random.
What are the gas laws?
Pressure law - Pressure is directly proportional to temperature (K)
Boyle’s Law - Pressure is directly proportional to 1/Volume, Temperature is constant.
Charles’s Law - Volume is directly proportional to temperature (K)
What is an isothermal process?
A process where temperature is constant.
What are the properties of ideal gasses?
- Particles occupy negligible volume compared to the volume of gas.
- Molecules are identical in mass and speed.
- Molecules collide with each other and the walls in a perfectly elastic matter in zero time.
- Molecules exert no force on each other except during collisions.
- There are enough molecules so that statistics can be applied.
- They are moving randomly and rapidly.
What is internal energy?
Sum of potential and kinetic energy.
How does a gas exert pressure on the walls of the container?
- Lots of molecules collide with the walls.
- Molecules change momentum
- Newton’s second law - resultant force is the rate of change of momentum therefore a force is exerted on the wall.
How to derive the relationship between absolute temperature and mean kinetic temperature?
PV = 1/3*Nmc^2
3PV = Nmc^2
KE = 1/2Mc^2
M = Nm
N = number of moles
m = Molar mass
2KE = Nmc^2
3PV = 2KE
3/2PV = KE
PV = KT for for one mol of gas
KE = 3/2kT
1/2mc^2 = 3/2kT
Kinetic Theory for solids
- Strong forces of attraction
- Particles tightly packed
- Vibrate about fixed positions
- High density
Kinetic Theory for liquids
- Medium forces of attraction
- Particles close
- Particles slide past each other
- Medium density
- Translational kinetic energy
Kinetic Theory for gas
- Almost no attractive forces
- Particles far apart (unless compressed)
- Free to move around quickly, randomly
- Low density, compressible