the periodic table 1.6 Flashcards

(26 cards)

1
Q

what increases going down group 2

A

-atomic radius
-sheilding (outer electron held less tightly)
- reactivity increases

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2
Q

what are the flame tests for group 2

A

mg- none
ca- orange/brick red
sr - crimson red
ba- green

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3
Q

what are the group 1 flame tests

A

li- red
na- yellow (orangy)
k- lilac

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4
Q

group 2 reactions with water

A

Be - no reaction
mg- steam required
ca- reacts moderately (hydroxide forms)
sr - reacts rapidly (hydroxide forms)
ba- reacts vigorously, (hydroxide formed)

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5
Q

whats the equation when group 2 reacts in water

A

M + 2H2O —>M(OH)2 + H2

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6
Q

describe the solubility of group 2 sulphates

A

decreases down a group
MgSO4 - soluble
CaSO4 - slightly soluble
SrSO4 - insoluble
BaSO4 - insoluble

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7
Q

whats the equation for group 2 sulphates

A

M(aq) 2+ + SO4(aq) 2- ——> MSO4(s)

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8
Q

describe the solubility for group 2 hydroxides

A

increases down a group
mg(OH)2-insoluble
Ca(OH)2 - slightly soluble
Sr(OH)2- soluble
Ba(OH)2 - soluble

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9
Q

equations for group 2 hydroxides

A

M(aq)2+ + 2OH-(aq) —> M(OH)2 (s)

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10
Q

describe solubility in group 2 carbonates

A

all slightly soluble but gets extremely less soluble ass you go down the group

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11
Q

equations for group 2 carbonates

A

M(aq)2+ + CO3(aq)2- —> MCO3 (s)

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12
Q

whats the trend in thermal stability in group 2 hydroxides and carbonates

A

increases down the groups

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13
Q

whats the equation for the decomposition of both group 2 hydroxide and carbonate

A

MCO3—–> MO+ CO2
M(OH)2 —->MO + H2O

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14
Q

what happens going down group 7

A
  • molecule radius increases(greater van der waals forces)
    -melting/boiling point increase (due to greater van der waals)
  • electronegativity decreases due to atomic radius increasing
  • reactivity decreases
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15
Q

what observations can be made when halogens (group 7) react with sodium

A

bright orange flame. sodium ignites and white solid halide

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16
Q

whats the equation for the reaction of halogen and sodium

A

2Na + X2 —–> 2NaX

17
Q

what happens to the halogens when we react them with iron

A

cl- burns and glows brightly
Br - iron wool gloes less
I- slight glow

18
Q

whats the equation of when potassium halide reacts with silver nitrate

A

KX(aq) + AgNO3(aq) —> KNO3(aq) + AgX(s)

19
Q

what are the colour of precipitates when the halides react with silver nitrate

A

cl - white
br - cream
i- yellow

20
Q

how do we confirm the identity

A

using dilute ammonia at first and then concentrated

21
Q

what happens to the halides as we confirm their identity with ammonia

A

cl dissolves in dilute ammonia
Br only dissolves in concentrated ammonia
i is insoluble in both

22
Q

what happens when Cl- reacts with Br2 or I2

A

no reaction in both

23
Q

what happens when Br- reacts with cl2 and i2

A

Cl2 - yellow solution
I2 - no reaction

24
Q

what happens when i- reacts with Cl2 or Br2

A

Cl2- brown solution
Br 2 - brown solution

25
whats the equation for the halogen displacement
Cl2 + 2KBr -----> 2KCl + Br2
26
explain how the halogen oxidises the halide
halogen gains electron when it oxidises halide ion the smaller the halogen easier it is to gain electron therefore oxidisation ability decreases down a group