the periodic table 1.6 Flashcards

1
Q

what increases going down group 2

A

-atomic radius
-sheilding (outer electron held less tightly)
- reactivity increases

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2
Q

what are the flame tests for group 2

A

mg- none
ca- orange/brick red
sr - crimson red
ba- green

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3
Q

what are the group 1 flame tests

A

li- red
na- yellow (orangy)
k- lilac

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4
Q

group 2 reactions with water

A

Be - no reaction
mg- steam required
ca- reacts moderately (hydroxide forms)
sr - reacts rapidly (hydroxide forms)
ba- reacts vigorously, (hydroxide formed)

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5
Q

whats the equation when group 2 reacts in water

A

M + 2H2O —>M(OH)2 + H2

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6
Q

describe the solubility of group 2 sulphates

A

decreases down a group
MgSO4 - soluble
CaSO4 - slightly soluble
SrSO4 - insoluble
BaSO4 - insoluble

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7
Q

whats the equation for group 2 sulphates

A

M(aq) 2+ + SO4(aq) 2- ——> MSO4(s)

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8
Q

describe the solubility for group 2 hydroxides

A

increases down a group
mg(OH)2-insoluble
Ca(OH)2 - slightly soluble
Sr(OH)2- soluble
Ba(OH)2 - soluble

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9
Q

equations for group 2 hydroxides

A

M(aq)2+ + 2OH-(aq) —> M(OH)2 (s)

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10
Q

describe solubility in group 2 carbonates

A

all slightly soluble but gets extremely less soluble ass you go down the group

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11
Q

equations for group 2 carbonates

A

M(aq)2+ + CO3(aq)2- —> MCO3 (s)

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12
Q

whats the trend in thermal stability in group 2 hydroxides and carbonates

A

increases down the groups

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13
Q

whats the equation for the decomposition of both group 2 hydroxide and carbonate

A

MCO3—–> MO+ CO2
M(OH)2 —->MO + H2O

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14
Q

what happens going down group 7

A
  • molecule radius increases(greater van der waals forces)
    -melting/boiling point increase (due to greater van der waals)
  • electronegativity decreases due to atomic radius increasing
  • reactivity decreases
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15
Q

what observations can be made when halogens (group 7) react with sodium

A

bright orange flame. sodium ignites and white solid halide

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16
Q

whats the equation for the reaction of halogen and sodium

A

2Na + X2 —–> 2NaX

17
Q

what happens to the halogens when we react them with iron

A

cl- burns and glows brightly
Br - iron wool gloes less
I- slight glow

18
Q

whats the equation of when halide reacts with silver nitrate

A

KX(aq) + AgNO3(aq) —> KNO3(aq) + AgCl(s)

19
Q

what are the colour of precipitates when the halides react with silver nitrate

A

cl - white
br - cream
i- yellow

20
Q

how do we confirm the identity

A

using dilute ammonia at first and then concentrated

21
Q

what happens to the halides as we confirm their identity

A

cl dissolves in dilute ammonia
Br only dissolves in concentrated ammonia
i is insoluble in both

22
Q

what happens when Cl- reacts with Br2 or I2

A

no reaction in both

23
Q

what happens when Br- reacts with cl2 and i2

A

Cl2 - yellow solution
I2 - no reaction

24
Q

what happens when i- reacts with Cl2 or Br2

A

Cl2- brown solution
Br 2 - brown solution

25
Q

whats the equation for the halogen displacement

A

Cl2 + 2KBr —–> 2KCl + Br2

26
Q

explain how the halogen oxidises the halide

A

halogen gains electron when it oxidises halide ion
the smaller the halogen easier it is to gain electron therefore oxidisation ability decreases down a group