the periodic table 1.6 Flashcards
what increases going down group 2
-atomic radius
-sheilding (outer electron held less tightly)
- reactivity increases
what are the flame tests for group 2
mg- none
ca- orange/brick red
sr - crimson red
ba- green
what are the group 1 flame tests
li- red
na- yellow (orangy)
k- lilac
group 2 reactions with water
Be - no reaction
mg- steam required
ca- reacts moderately (hydroxide forms)
sr - reacts rapidly (hydroxide forms)
ba- reacts vigorously, (hydroxide formed)
whats the equation when group 2 reacts in water
M + 2H2O —>M(OH)2 + H2
describe the solubility of group 2 sulphates
decreases down a group
MgSO4 - soluble
CaSO4 - slightly soluble
SrSO4 - insoluble
BaSO4 - insoluble
whats the equation for group 2 sulphates
M(aq) 2+ + SO4(aq) 2- ——> MSO4(s)
describe the solubility for group 2 hydroxides
increases down a group
mg(OH)2-insoluble
Ca(OH)2 - slightly soluble
Sr(OH)2- soluble
Ba(OH)2 - soluble
equations for group 2 hydroxides
M(aq)2+ + 2OH-(aq) —> M(OH)2 (s)
describe solubility in group 2 carbonates
all slightly soluble but gets extremely less soluble ass you go down the group
equations for group 2 carbonates
M(aq)2+ + CO3(aq)2- —> MCO3 (s)
whats the trend in thermal stability in group 2 hydroxides and carbonates
increases down the groups
whats the equation for the decomposition of both group 2 hydroxide and carbonate
MCO3—–> MO+ CO2
M(OH)2 —->MO + H2O
what happens going down group 7
- molecule radius increases(greater van der waals forces)
-melting/boiling point increase (due to greater van der waals) - electronegativity decreases due to atomic radius increasing
- reactivity decreases
what observations can be made when halogens (group 7) react with sodium
bright orange flame. sodium ignites and white solid halide
whats the equation for the reaction of halogen and sodium
2Na + X2 —–> 2NaX
what happens to the halogens when we react them with iron
cl- burns and glows brightly
Br - iron wool gloes less
I- slight glow
whats the equation of when halide reacts with silver nitrate
KX(aq) + AgNO3(aq) —> KNO3(aq) + AgCl(s)
what are the colour of precipitates when the halides react with silver nitrate
cl - white
br - cream
i- yellow
how do we confirm the identity
using dilute ammonia at first and then concentrated
what happens to the halides as we confirm their identity
cl dissolves in dilute ammonia
Br only dissolves in concentrated ammonia
i is insoluble in both
what happens when Cl- reacts with Br2 or I2
no reaction in both
what happens when Br- reacts with cl2 and i2
Cl2 - yellow solution
I2 - no reaction
what happens when i- reacts with Cl2 or Br2
Cl2- brown solution
Br 2 - brown solution
whats the equation for the halogen displacement
Cl2 + 2KBr —–> 2KCl + Br2
explain how the halogen oxidises the halide
halogen gains electron when it oxidises halide ion
the smaller the halogen easier it is to gain electron therefore oxidisation ability decreases down a group