basic ideas of atoms 1.2 Flashcards
what is the absorption spectrum and how does it happen?
a spectrum of light can contain harsh and discrete lines when an electron passes through to absorb a quantized wavelength
what is the emissions spectrum and how does it happen
the excited state the electron is in after absorbing energy is unstable so releases the same amount of energy absorbed and falls back to ground state.
what is the electrons filling order
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6
what is the symbol for alpha radiation
4 He 2+
2
what is the symbol for beta radiation
0 e
-1
why does successive ionisation energy increase?
The successive ionisation energies of an element increase because As more electrons are removed, the attractive forces increase due to decreasing shielding and an increase in the proton to electron ratio.
what is the definition of first ionisation energy
energy required to remove one mole of electrons from one mole of gaseous atom to form 1+ gaseous ion
whats the equation for the first ionisation for x
x(g) ——> x+(g) + e-
why does first ionisation energy decrease down a group
more shielding and larger nucleus radius so it is easier to remove as the outer electron is held less tightly by the nucleus
why does first ionisation energies generally increase across a period
increase in nuclear charge
why does ionisation energies not increase from period 2-3
easier to remove an electron from group 3 as the electron is being removed from an orbital which is further away from the nucleus (p orbital) therefore held less tightly
why does ionisation energies not increase from period 5-6
easier to remove an electron from group 6 as the electron being removed is paired therefore experiences more electron-electron repulsion from p orbital
whats the definition of half life
the time it takes for the count rate or mass of a radioactive substance to fall o half its original value
whats the definition of an orbital
energy levels split regions of space around the nucleus where there is a high probability of finding 2 electrons
describe the convergence limit
convergence limit becomes closer and closer together as the frequency of radiation increase so they converge to a limit