bonding and structure 1.4/1.5 Flashcards

1
Q

whats the definition of ionic bonding

A

when there is a large change in difference in electronegativity. electrons are completely transferred from one atom to another. electrostatic attraction between the oppositely charge ions

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2
Q

properties of ionic bonding

A

-high melting point (strong electrostatic forces)
- conduct electricity when molten or dissolved (free ions)
-most are soluble in water (polar water can break lattice)

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3
Q

whats the definition of covalent bonding

A

small difference in electronegativity. the atoms are kept together as they share the same electrons

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4
Q

whats the definition of coordinate bond

A

both electrons come from the same atom

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5
Q

structure of graphite

A

brittle hexagonal layers held my van der waals forces. each carbon bonded to 3 others.

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6
Q

properties of graphite

A

-soft and slippery
-conductor (free ion)
-insoluble
high melting/boiling point

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7
Q

structure of diamond

A

tetrahedral, each carbon bonded to 4 others.

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8
Q

properties of diamond

A

-hard due to tetrahedral structure
-poor conductor no free ions
- insoluble
- high melting point/ boiling point

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9
Q

properties of simple covalent structures

A
  • low melting point/ boiling point (weak intermolecular forces)
  • dont conduct (no free ions)
  • soluble in non polar solutes
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10
Q

definition of electronegativity

A

the power of an atom to attract the electrons in a covalent bond

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11
Q

which experiences the most repulsion ( lone pairs and bonding pairs)

A

2 bond pairs 1 loan 1 bond 2 loan pairs
——————————————————–>
increase in repulsion

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12
Q

how does nuclear charge effect electronegativity

A

more protons, stronger attraction between nucleus and bonding pair electrons.
as nuclear charge increases the electronegativity of an element increases

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13
Q

how does atomic radius effect electronegativity

A

if atomic radius increases electronegativity decreases as electrons further away from the nucleus are held less tightly.

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14
Q

how does shielding effect electronegativity

A

an increased number of shells will result in a decreased electronegativity due to the outer electron being further away from the nucleus therefore held less tightly

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15
Q

how do van der waals forces occur

A

happens when atoms electrons move to one side cause repulsion in the next molecules electrons to move to side

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16
Q

factors that effect van der waals

A

-amount of electrons (down group 7 inc)
-number of point of contact

17
Q

how do permanent dipole dipole occur

A

polar molecules come close partially positive side attracts partially negative side

18
Q

factors that effect permanent dipole dipole

A

larger differences in electronegativity—-stronger dipoles

19
Q

how do hydrogen bonds occur

A

when hydrogen bonds with F,O,N

20
Q

factor that effects hydrogen bonding

A

larger the electronegativity the stronger dipoles

21
Q

anomalous properties of water

A
  • ice is less dense than water( ice contains tetrahedral water contains bent)
    -high melting/boiling point- hydrogen bonds
22
Q

whats the definition of metallic bonding

A

electrostatic attraction between positive metal ions and delocalized electrons

23
Q

factors effecting metallic bonding

A
  • larger the charge the stronger electrostatic attraction
24
Q

properties of metals

A

malleable - layers slide
conductor- sea of delocalised electrons
- insoluble - cant for hydrogen binds with water