The Halogens Flashcards

1
Q

what does F2 look like at rtp?

A

almost colourless gas

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2
Q

what does Cl2 look like at rtp?

A

pale green gas

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3
Q

what does Br2 look like at rtp?

A

red-brown liquid which easily vapourises giving brown vapour

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4
Q

what does I2 look like at rtp?

A

grey-black solid which sublimes on heating giving purple vapour

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5
Q

what’s the trend for colour down group 7?

A

colour gets darker

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6
Q

what’s the trend for mp and bp down group 7?

A

increases, they get less volatile and switch from gas to liquid to solid (because intermolecular bonds get stronger)

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7
Q

are halogens oxidising or reducing agents?

A

oxidising agents - have to gain one electron to achieve noble gas configuration

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8
Q

how does oxidising power change up group 7 & why?

A

oxiding power increases up group 7 because as you go up the groups, the halogen has fewer shells so the incoming electron is closer to the +ve nucleus & less shielded so more strongly attracted

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9
Q

why do 2 layers form when organic solvents and water are shaken?

A

organic solvents and water are immiscible (do not mix)

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10
Q

what colour is Cl-?

A

colourless

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11
Q

what colour is Br-?

A

colourless

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12
Q

what colour is I-?

A

colourless

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13
Q

what colour is Cl2 in aqueous solutions?

A

almost colourless

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14
Q

what colour is Br2 in aqueous solutions?

A

orange

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15
Q

what colour is I2 in aqueous solutions?

A

brown

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16
Q

what colour is Cl2 in organic solvents?

A

pale green

17
Q

what colour is Br2 in organic solvents?

A

deeper orange

18
Q

what colour is I2 in organic solvents?

A

purple

19
Q

what happens when you mix a solution containing F- with AgNO3(aq)?

A

no ppt

20
Q

what happens when you mix a solution containing Cl- with AgNO3(aq)?

A

white ppt of AgCl

21
Q

what happens when you mix a solution containing Br- with AgNO3(aq)?

A

cream ppt of AgBr

22
Q

what happens when you mix a solution containing I- with AgNO3(aq)?

A

pale yellow ppt of AgI

23
Q

what happens when silver halides are left in sunlight?

A

they start to go grey/black due to the formation of silver

24
Q

what happens when silver halide ppts are shaken with aqueous ammonia solution?

A

AgCl: ppt dissolves, giving a colourless solution
AgBr: some ppt redissolves
AgI: ppt remains