Textboolk LO1-3 Flashcards

1
Q

Quantization

A

Only certain energies are allowed

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2
Q

Principle quantum number (2)

A

A positive unit less integer
defines the energy of the allowed orbits in the H atom

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3
Q

The energy of the electron in an orbit has a negative value because

A

the electron in the atom has a lower energy than when it is free.

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4
Q

The 0 of energy occurs when

A

n= infinity
That is when the election is infinitely separated from the nucleus

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5
Q

Ground state

A

An atom with its electron in the lowest possible energy levels

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6
Q

The energy of the electron depends on

A

n

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7
Q

The larger the value of n, (radius and energy negativity)

A

The larger the Bohr radius and the less negative the value of the energy

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8
Q

The difference between successive energy levels becomes _________ because

A

smaller as n becomes larger

Energy is dependent on 1/n^2

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9
Q

what needs to happen when an electron goes From n=1 to n=2 electron state

A

Energy is absorbed from the surroundings

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10
Q

A consequence or requirement of quantization (2)

A

A specific and precise amount of energy

No more or no less

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11
Q

When a electron falls down its energy level to a diff one

A

Since only certain energy levels are possible, only photons with particular energies and wavelengths are emitted

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12
Q

principle quantum number (3)

A

any integer from 1-infinity

primary factor in determining the energy of an orbital
defines size of an orbital

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13
Q

In atoms having more than 1 electron, two or more electrons may have the same n value. They are said to be

A

in the same electron shell

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14
Q

orbital example

A

3px

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15
Q

which quantum number or combination is needed to specify a given subshell in an atom?

A

n and l

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16
Q

repulsion counteract the nuclear attraction making electrons

A

easier to remove by helping to push it away

17
Q

shielding reduces the full nuclear charge to

A

an effective nuclear charge

18
Q

the energy difference arises from three factors

A

nuclear attractions, electron repulsion and orbital shape

19
Q

puli exclusion principle

A

requires each electron to have a unique set of four quantum number

20
Q

repulsion shield electrons from the ______ reducing it to an_____

A

the full nuclear charge

effective nuclear charge

21
Q

aufbau principle

A

we start at the beginning of the periodic table and add one proton to the nucleus and one electron to the lowest energy sub level available.

22
Q

order for filling energy sub levels

A

1s, 2s, 2p,3s,3p,4s,3d,4p,5s,4d,5p

23
Q

Hunds rule

A

No electrons are paired in a set of orbitals of equal energy until every orbital in the set has one electron.

24
Q

formula for which orbital filled first

A

n+l

Whichever orbital has the lower n+1 value will fill first

25
Q

formula for maximum electron possible for nth shell

A

2n^2

26
Q

the energy gaps between sub shells of a given shell becomes______ as n _____

A

smaller

increase

27
Q

The electrons included in the noble gas notation are often referred to as

A

core electrons

28
Q

What are the two exceptions for transition metals and draw it out

A
29
Q

Transition metal steps or exceptions for electron configs

A

Make sure that d orbital is half filled (5) or fully filled (10) by promoting electrons from the 4s

30
Q

from Scandium and onwards, the 3d orbital of transition metals actually becomes

A

lower in energy than the 4s, which is why we write 3d before 4s in the configuration.